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Petrochronology of monazite in volcanic rocks of the Hutti deposit in the Eastern Dharwar Craton (India) has been studied to understand the magmatic and hydrothermal events that have affected the area. The volcanic rocks occurring in the Hutti greenstone belt are bimodal in nature and contain both felsic and metabasalt. The felsic volcanic rocks in the area preserve accessory minerals like monazite, allanite, and apatite, whereas the same is absent in metabasalts. Petrographic observation of felsic volcanic rock shows corona growth of allanite and apatite (in addition to huttonite) clustering around monazite grains. This corona texture, termed allanite cluster, occurs parallel to the shear planes (C‐plane) of the felsic volcanic rock and characterizes late‐stage hydrothermal activity in the area. Texturally, monazite in the felsic volcanic rock occurs included within arsenopyrite (<1 μm), and in association with apatite, allanite, and occasionally with huttonite/thorite (~10–40 μm), in which monazite grains preserve geochemical heterogeneity in both intra‐ and inter‐grains. The U–Th–PbTotal dating of monazite associated with the allanite cluster shows two age peaks (both from intra‐ and inter‐grains) at 2658 ± 17 Ma (older) and 2534 ± 38 Ma (younger), in which the older age represents the magmatic/crystallization age of the studied felsic volcanic rock overprinted by a later hydrothermal event in the study area. Based on monazite geochemistry‐geochronology, the present study deduces two texturally constrained events related to the primary crystallization of monazite (~2.65 Ga) and subsequent alteration of the same during a later hydrothermal event (ca. 2.53 Ga) that has affected the felsic volcanic rock in the Hutti gold deposit. [ABSTRACT FROM AUTHOR]

Vast clay deposits of Chitradurga and Sandur greenstone belts of the Dharwar Craton, southern peninsular India, hosting pockets of high‐grade manganese (Mn) ore, provide remarkable clues related to the ore‐forming processes and palaeo‐environmental conditions. In this study these Fe–Mn‐rich clays were investigated through mineralogical and geochemical characteristics to comprehend their palaeo‐weathering and genetic constraints and their role in the supergene accumulation of Mn ore. Their mineralogy is characterized by predominant kaolinite, muscovite, birnessite, haematite, goethite, halloysite along with quartz and traces of ilmenite. Chemical indices of alteration and weathering indicate intense weathering conditions under high palaeo‐precipitation rates in a humid, tropical climate under shallow burial conditions and K‐metasomatism. The presence of authigenic kaolinite and absence of illite reflect on diagenesis up to mesodiagenetic stage. Positive to negative Ce anomalies (Ce/Ce* = 0.67–5.93) of these clays suggest varying oxic‐anoxic conditions during their genesis, whereas conspicuous negative Eu anomalies (Eu/Eu* = 0.61–0.99) are attributed to precursor sediment signatures and hydrothermal imprints of the Mn ore. These kaolinite‐rich clays are suggested to have been formed by in situ chemical alteration, whereas kaolinitization of the Fe–Mn‐rich arenaceous and argillaceous sediments was derived from predominant tonalite and felsic provenance in a shallow marine passive margin setting. Based on the morphologies of birnessite, haematite and goethite in the investigated clays, we propose that these clays have played a key role in the oxidation and deposition of Mn (II) from the migrating aqueous solutions and acted as organo‐polymerization templates for the proliferation of ancient microbial life on the planet Earth. [ABSTRACT FROM AUTHOR]

Due to the inherently fluid‐mobile nature of W, the 182W record of the early Earth may have been obscured by fluid‐induced mobilization of W. To investigate W mobilization in Archean greenstone sequences, we analyzed 182W isotope systematics and major and trace element concentrations in samples from the 3.53 Ga old Onverwacht Group of the Kaapvaal Craton (South Africa) and the >3.51 Ga old Badampahar Group of the Singhbhum Craton (India). Our results for mafic and ultramafic metavolcanic rocks show W/Th ratios significantly higher than primary magmatic values, which suggests fluid‐induced W enrichment. Samples least affected by secondary W enrichment (W/Th < 0.26) show no resolvable W isotope anomalies from modern mantle values in both cratons. Samples from the Kaapvaal Craton with elevated W/Th exhibit deficits in 182W as low as −8.1 ± 4.3 ppm compared to the modern mantle. Covariations of μ182W with W/Th, and Ce/Pb suggest that negative isotope signatures were introduced during secondary fluid‐mediated processes. The enrichment of W is most evident in altered ultramafic rocks comprising serpentine, resulting in additional covariations between MgO, LOI, and W/Th. The W isotope composition of serpentinized komatiites reflects the composition of younger intruding granitoids. We therefore infer the latter as a possible source of W‐rich fluids. The Badampahar Group samples exhibit little W isotope variability. A well‐resolved 182W deficit of −6.2 ± 2.9 ppm was determined in a single komatiite sample, which indicates an unknown fluid source, currently not represented in any other unit of the Singhbhum Craton. Plain Language Summary: The tungsten (W) isotope composition of ancient rocks can be used to trace processes that occurred during Earth's early evolution. However, interactions between rocks and fluids may alter the W concentration and therefore influence the interpretation of W isotope data. To identify the source of such fluids and the processes by which they affect the W isotope composition of rocks, we analyzed ancient rock samples from South Africa and India. The isotope composition of rocks with a low W concentration reflects that of the modern Earth. Therefore, they do not trace the processes that occurred during Earth's early evolution. Samples from South Africa with untypically high W concentrations show a different isotopic composition. The variation in the W isotope signature correlates with other chemical indices that are susceptible to modification by fluid‐related processes. This shows that the W within the rocks is derived from an external fluid source and not from their original magmatic source. Samples with the highest W enrichment have a similar isotope composition as spatially associated intrusive rocks. By inference, the latter likely represent the source of W‐rich fluids. The samples from India show similar enrichment in W, indicating similar fluid‐related processes and W sources at both localities. Key Points: The magmatic sources of metavolcanic rocks from the Onverwacht Group and the Badampahar Group do not exhibit W isotope anomaliesNegative W isotope signatures in the Onverwacht Group are likely derived from fluids sourced from younger intrusive granitoidsFelsic intrusive rocks are a major source of W‐rich fluids in Paleoarchean greenstone units [ABSTRACT FROM AUTHOR]

The north‐dipping Hout River Shear Zone (HRSZ), which marks the boundary between the high‐grade Limpopo Complex in its hanging wall and the low‐grade granite‐greenstone terrane of the Kaapvaal Craton in South Africa in its footwall, is a deep‐crustal shear zone that controlled emplacement of hot Limpopo Complex granulites over and against low‐grade granite‐greenstones during exhumation at ~2.72–2.62 Ga. This major shear zone controlled migration of large volumes of hydrous fluids released during devolatilization of underthrusted greenstones that infiltrated into hot overlying granulites, establishing a retrograde anthophyllite‐in isograd and associated zone of retrograde rehydrated granulite that bounds the Limpopo Complex in the south. Here, we report new petrological data based on mineral equilibrium modelling of amphibolites from the Rhenosterkoppies Greenstone Belt (RGB) located in the immediate footwall of the HRSZ and discuss evidence that these rocks also interacted with high‐temperature fluids that infiltrated along the HRSZ. This study provides an important perspective of the interaction of hot granulites with underthrusted relatively cold greenschist‐facies rocks along the steeply north‐dipping section of the HRSZ, and shows that evidence for such interaction is restricted to a relatively narrow zone in the footwall of the HRSZ termed a hot‐iron‐zone. The peak mineral assemblage of a garnet‐free amphibolite from the RGB (magnesio‐hornblende + plagioclase + quartz + clinopyroxene + titanite + ilmenite) yielded the peak P–T condition of 7–8 kbar and 640–680°C with H2O content of 3.5–3.8 mol%. Clinopyroxene is replaced by actinolite + quartz and epidote + quartz symplectites by a post‐peak hydration event at <5 kbar and <590°C caused by elevated H2O content in the rock (>4.0 mol%), possibly related to fluid infiltration along the HRSZ. Mineral equilibria in a garnet‐bearing amphibolite records a prograde path from 5 to 7 kbar and 540–630°C to the peak conditions at 7.6–8.7 kbar and 620–650°C. A clockwise P–T path suggesting rapid compression and decompression has been inferred for the amphibolites from the RGB, possibly because of pressure increase related to overthrusting of the high‐grade terrane (Southern Marginal Zone of the Limpopo Complex) onto the low‐grade granite‐greenstone terrane, followed by rapid exhumation. The quantity of H2O associated with the amphibolite‐facies metamorphism in the RGB was elevated from the peak stage (M(H2O) = 3.5–3.8 mol%) to the retrograde stage (M(H2O) = 4.0–4.5 mol%) of metamorphism in the RGB, possibly suggesting fluid infiltration not only from internal sources but also from external sources. The results of this study indicate that a H2O‐bearing fluid, which infiltrated along the HRSZ, affected both the footwall and the hanging wall sections of the shear zone, although the effect on the footwall section was limited. [ABSTRACT FROM AUTHOR]

A high‐resolution seismic reflection transect was acquired over a hard‐rock geological setting along an existing roadway in the Larder Lake area of the Superior Craton of Canada for the Metal Earth project in 2017. This profile, as well as other Metal earth transects, primarily aims to enhance the knowledge and to better understand the subsurface geology of the Abitibi Greenstone Belt within the Canadian Shield. The complex geological settings of the study area as well as the tribulations caused by the survey geometry have made the imaging and velocity field estimation more challenging. A recently introduced 2.5D multifocusing stacking method is one potential solution for processing crooked‐line seismic data with a poor signal‐to‐noise ratio. The 2.5D multifocusing approach offers more realistic modelling of the zero‐offset wavefield by explicitly accounting for the midpoint dispersion and cross‐dip effects. The main practical problem of the 2.5D multifocusing implementation is the simultaneous determination of the optimal wavefield parameters for each image point and time location. We address this optimization problem using a multidimensional constrained differential evolution global optimization algorithm, as this improves the efficiency and accuracy of the estimation. We have also designed an efficient processing sequence for multifocusing seismic imaging. The performance of the 2.5D multifocusing procedure has been examined on a synthetic model, generated using the same real acquisition geometry. Numerical tests demonstrate that the 2.5D multifocusing technique can produce a more focused stack with the primary reflections appearing at their poststack correct locations, and the procedure can also provide reliable estimates of interface dips. Due to the importance and difficulty of imaging the data, several conventional and advanced processing strategies have been attempted on the transect, specifically: 2D phase‐shift time migration of a dip moveout corrected stack; 2D prestack Kirchhoff time migration; swath 3D poststack migration; and our 2.5D multifocusing imaging algorithm. We found that applying the 2.5D multifocusing stacking algorithm followed by a poststack time migration approach improved the resolution of the image significantly compared to all the conventional and advanced methods and identified new reflections. The 2.5D multifocusing method also focused the steeply dipping reflections more coherently, which resolved ambiguities in geological architecture by understanding the location and continuity of structures. The method also accurately extracts 3D structural information and results in an improved signal‐to‐noise ratio. [ABSTRACT FROM AUTHOR]

Established 2D seismic data processing methods such as Kirchhoff pre‐stack time migration and Kirchhoff pre‐stack depth migration function relatively well for regular acquisition geometries and well‐constrained velocity models. Recently developed focusing pre‐stack depth migration methods have the potential to enhance image quality in the case of sparse and non‐regular source–receiver distribution. We have tested the performance of the coherency migration method as one of these focusing migration approaches in comparison to standard dip‐moveout and Kirchhoff pre‐stack time migration techniques by applying them to the Swayze East seismic profile acquired in the Abitibi greenstone belt of Canada. This seismic profile represents a crooked‐line survey that intersects several metal‐bearing deformation zones, providing good target geometries to examine various pre‐stack migration methods. Analysis of the seismic data indicates reflectivity associated with shallowly dipping reflections appears relatively well preserved over the entire 0–6 km offset range for the frequency range between 20 to 90 Hz. Although most reflections are visible already in either the dip‐moveout or the Kirchhoff pre‐stack time migration results, the coherency migration method delivers the most improved image showing all reflective structures inferred for this area. The comparisons suggest the coherency migration method can be considered as superior in terms of resulting seismic image quality compared with conventional approaches for this type of crooked‐line seismic survey in such a complex geological setting. [ABSTRACT FROM AUTHOR]

The nitrogen isotopic composition of organic matter is controlled by metabolic activity and redox speciation and has therefore largely been used to uncover the early evolution of life and ocean oxygenation. Specifically, positive δ15N values found in well‐preserved sedimentary rocks are often interpreted as reflecting the stability of a nitrate pool sustained by water column partial oxygenation. This study adds much‐needed data to the sparse Paleoarchean record, providing carbon and nitrogen concentrations and isotopic compositions for more than fifty samples from the 3.4 Ga Buck Reef Chert sedimentary deposit (BRC, Barberton Greenstone Belt). In the overall anoxic and ferruginous conditions of the BRC depositional environment, these samples yield positive δ15N values up to +6.1‰. We argue that without a stable pool of nitrates, these values are best explained by non‐quantitative oxidation of ammonium via the Feammox pathway, a metabolic co‐cycling between iron and nitrogen through the oxidation of ammonium in the presence of iron oxides. Our data contribute to the understanding of how the nitrogen cycle operated under reducing, anoxic, and ferruginous conditions, which are relevant to most of the Archean. Most importantly, they invite to carefully consider the meaning of positive δ15N signatures in Archean sediments. [ABSTRACT FROM AUTHOR]

Petrographic, whole‐rock geochemical and geochronological analysis of polymictic conglomerate, associated siltstone and greywacke in the Neoarchean Gadag Greenstone Belt in the Western Dharwar Craton, India, provides new insights into sedimentary provenance and tectonic setting. The polymictic conglomerate contains granitic, gneissic, felsic and mafic volcanic, quartzite and banded ferruginous chert clasts within a quartzo‐feldspathic matrix. Framework grains in the siltstone and greywacke are quartz, feldspar with rock fragments, embedded in a chlorite‐dominant matrix. The chemical index of alteration values (~70) and A‐CN‐K plot for the rocks suggest a low‐to‐moderate degree of weathering. Rare earth element (REE) patterns show moderate fractionation (LaN/YbN ~ 12.31) with a weak negative europium anomaly (0.82). Enrichment in transition elements (Ni, Cr, Co, Sc) and depletion in high‐field‐strength elements, as well as relatively low La/Co (0.62), moderate to high Th/Yb (3.06), La/Th (5.16), La/Yb (17.5), and La/Sc (~2.37) ratios, suggest a mixed felsic‐mafic provenance. U–Pb dating of detrital zircon from the conglomerate and greywacke revealed major age peaks at ca. (3.2, 2.9, 2.8, 2.6, 2.5 Ga) and a maximum age of deposition of 2,508 ± 26 Ma, 2,493 ± 20 Ma, respectively. The above data suggest low to moderately weathered proximal sources for both conglomerate and greywacke, indicating that these two rock types were not deposited simultaneously, but rather separately. The association of these conglomerates and greywacke with continental arc‐related volcanics indicates the closing of an arc at the time of sedimentation. Complex provenance consisting of recycled and magmatic arc during basin closure confirm the notion of modern style plate tectonics operating during Neoarchaean. [ABSTRACT FROM AUTHOR]

This study presents multiple sulphur isotope (32S, 33S, 34S, 36S) data on pyrites from silicified volcano‐sedimentary rocks of the Paleoarchean Onverwacht Group of the Barberton greenstone belt, South Africa. These rocks include seafloor cherts and felsic conglomerates that were deposited in shallow marine environments preserving a record of atmospheric and biogeochemical conditions on the early Earth. A strong variation in mass independent sulphur isotope fractionation (MIF‐S) anomalies is found in the cherts, with Δ33S ranging between −0.26‰ and 3.42‰. We explore possible depositional and preservational factors that could explain some of this variation seen in MIF‐S. Evidence for microbial activity is recorded by the c. 3.45 Ga Hooggenoeg Formation Chert (HC4) preserving a contribution of microbial sulphate reduction (−Δ33S and –δ34S), and a c. 3.33 Ga Kromberg Formation Chert (KC5) recording a possible contribution of microbial elemental sulphur disproportionation (+Δ33S and –δ34S). Pyrites from a rhyo‐dacitic conglomerate of the Noisy Formation do not plot along a previously proposed global Felsic Volcanic Array, and this excludes short‐lived pulses of intense felsic volcanic gas emissions as the dominant control on Archean MIF‐S. Rather, we suggest that the MIF‐S signals measured reflect dilution during marine deposition, early diagenetic modification, and mixing with volcanic/hydrothermal S sources. Given the expanded stratigraphic interval (3.47–3.22 Ga) now sampled from across the Barberton Supergroup, we conclude that large MIF‐S exceeding >4‰ is atypical of Paleoarchean near‐surface environments on the Kaapvaal Craton. [ABSTRACT FROM AUTHOR]

The carbonates of the Dodguni area of the Chitradurga greenstone belt, Dharwar Craton, India were studied to understand the Archean diagenetic and palaeo‐depositional conditions using carbon and oxygen isotopes along with whole‐rock geochemistry. These carbonates show significant variation in δ13C and δ18O (−1.73‰ Vienna Peedee Belemnite [VPDB] to −0.45‰ VPDB and δ18O vary from −13.51‰ VPDB to −8.46‰ VPDB, respectively). The rare earth element (REE) + Y (rare earth elements and yttrium) of the studied carbonate rocks exhibit flat and uniform patterns (PrSN/YbSN = 0.4–1), slight positive La, Eu and Gd anomalies (CeSN/CeSN* = 0.8–0.9; EuSN/EuSN* = 0.7–1.4 and GdSN/GdSN* = 2–2.3, respectively) with slight positive Ce anomalies (PrSN/PrSN* = 0.84–0.86) and superchondritic Y/Ho ratios (Y/Ho = 29–45; chondritic Y/Ho = 28). Their negative δ13C (−1.75‰ to −0.45‰) values are attributed to the influence of higher bio‐productivity during their deposition and oxidation of organic carbon. The geochemical and isotopic systematics suggest that the Dodguni limestones are not affected by the diagenetic and metamorphic processes and record the REE geochemistry of the ancient seawater in which they were precipitated. The comprehensive geochemical including the isotopic studies of the Archean carbonate rocks of the Dharwar Craton, indicate their deposition in shallow marine conditions, precipitation in high temperatures with significant hydrothermal input under the influence of high bio‐productivity, thereby providing valuable constraints on the palaeoceanography and geochemical evolution of the Archean sea. [ABSTRACT FROM AUTHOR]

The gold mineralization at the Tau deposit in northeastern Botswana can be distinguished into two stages. The first stage of mineralization consists of invisible gold associated with early, sulfur‐rich arsenopyrite (Apy1). The second stage is characterized by native gold associated with late, sulfur‐poor arsenopyrite (Apy2). This study aims to constrain the nature of the ore‐forming fluid at the Tau deposit on the basis of fluid inclusion microthermometry and arsenopyrite geothermometry. Quartz crystals closely associated with gold‐bearing sulfides (Apy1) from the host rock host three types of fluid inclusions occurring in the same assemblages: Type I, two‐phase aqueous fluid inclusions, Type II three‐phase aqueous‐carbonic fluid inclusions and Type III one‐ or two‐phase CO2‐rich fluid inclusions. Microthermometric and Raman spectroscopic studies revealed the dominance of coexisting H2O+NaCl (Type I) and CO2N2CH4 (Type III) fluid inclusions. The coexisting Type I and Type III fluid inclusions could represent products of the immiscibility of a homogenous H2OCO2NaClN2CH4 primary ore fluid. The salinity of Type I (calculated from melting temperature of ice) and Type II (calculated from dissolution temperature of clathrate) fluid inclusions vary from 3.4 to 9.2 wt% NaCl equiv. and 5.8 to 9.8 wt% NaCl equiv., respectively. The overall fluid inclusion salinity range (<10 wt% NaCl equiv.) and gas compositions of fluids suggest that the primary ore‐forming fluid at the Tau deposit was of low salinity and H2OCO2N2CH4NaCl composition. Integration of fluid inclusion microthermometry and arsenopyrite geothermometer results suggest that the first stage and second stages of gold mineralization and the associated alteration at the Tau deposit occurred at pressure and temperature conditions of 75–145 MPa and 290–370°C and 85–160 MPa and 330–370°C, respectively. These results suggest that there was an increase in temperature from the first stage to the second stage of mineralization, resulting in the recrystallization of invisible gold‐bearing arsenopyrite in the first stage to form native gold‐bearing arsenopyrite in the second stage. Fluid composition and the estimated physico‐chemical conditions at the Tau deposit confirm that gold was transported as reduced bisulfide complexes and initial gold deposition was likely caused by a reduction in sulfur contents as a result of sulfidation reactions and pressure‐induced phase separation (fluid immiscibility). [ABSTRACT FROM AUTHOR]

Past orbital parameters of the Moon are difficult to reconstruct from geological records because relevant data sets of tidal strata are scarce or incomplete. The sole Archean data point is from the Moodies Group (ca 3.22 Ga) of the Barberton Greenstone Belt, South Africa. From the time‐series analysis of tidal bundles from a well‐exposed subaqueous sand wave of this unit, Eriksson and Simpson (Geology, 28, 831) suggested that the Moon's anomalistic month at 3.2 Ga was closer to 20 days than the present 27.5 days. This is in apparent accordance with models of orbital mechanics which place the Archean Moon in a closer orbit with a shorter period, resulting in stronger tidal action. Although this study's detailed geological mapping and section measuring of the site confirmed that the sandstone bed in question is likely a migrating dune, the presence of angular mud clasts, channel‐margin slumps, laterally aggrading channel fills and bidirectional paleocurrents in overlying and underlying beds suggests that this bedform was likely located in a nearshore channel near lower‐intertidal flats and subtidal estuarine bars; it thus carries risk of incomplete preservation. Repeated measurements of foreset thicknesses along the published traverse, measured perpendicular to bedding, failed to show consistent spectral peaks. Larger data sets acquired along traverses measured parallel to bedding along the 20.5 m wide exposure are affected by minor faulting, uneven outcrop weathering, changing illumination, weather, observer bias and show a low reproducibility. The most robust measurements herein confirm the periodicity peak of approximately 14 in the original data of Eriksson and Simpson (Geology, 28, 831). Because laminae may have been eroded, the measurements may represent a lower bound of about 28 lunar days per synodic month. This estimate agrees well with Earth–Moon dynamic models which consider the conservation of angular momentum and place the Archaean Moon in a lower orbit around a faster‐spinning Earth. [ABSTRACT FROM AUTHOR]

Palaeo‐Mesoarchean Banded Iron formations (BIFs) of central Bundelkhand greenstone belts occur from Babina (in the west) to Mahoba (in the east) via Mauranipur along with the E–W trending of the Bundelkhand Tectonic Zone (BTZ). In the present study, we report petrological, geochemical, and mineralogical data of BIFs from the Babina, Mauranipur, and Mahoba greenstone belts of central Bundelkhand Greenstone Complex to address their source characteristics and deposition environment. The lithological association of BIFs in the Babina and Mauranipur greenstone belts consists of pillowed basic–ultrabasic volcanics and metasediments, whereas in the Mahoba greenstone belt, BIFs and quartzite occur within basic volcanics. These lithological associations collectively suggest that the entire succession was deposited in a marine environment. Based on geological setting, they are classified as Algoma‐type. The main mineral assemblages of the Babina and Mauranipur BIFs are composed of magnetite, quartz, ±garnet, hornblende, chlorite, and apatite, whereas the Mahoba BIFs along with magnetite and quartz, poised of two distinct mineral assemblages; the first one is Opx–Cpx–Grt and the other one is Grt–Hbl. The preliminary P–T study of these BIFs implies that they had gone through amphibolite‐ to granulite‐facies metamorphism. The geochemical characteristics show that BIFs from the Babina and Mauranipur greenstone belts are dominated by higher quartz and magnetite (total content = 90.63–99.95 wt.%), whereas the Mahoba greenstone belt is characterized by lesser quartz and magnetite components (total content = 86.68–94.58 wt.%). The PAAS (Post Archean Average of Australian Sediments)‐normalized REE patterns display significant positive Eu anomaly (Eu/Eu* up to 2.50) with well‐represented negative Ce anomalies (Ce/Ce* = 0.27–1.20). The REE and trace element ratios of BIFs from the Babina and Mauranipur greenstone belts suggest that they were formed by high‐T hydrothermal fluid activity without or very less continental input. Moreover, the Mahoba greenstone belt BIFs are formed by low‐T hydrothermal fluid activity with substantial continental input. Their chemical variation suggests the shallowing of the proto‐basin from the Babina in the west to Mahoba in the east. Tectonic discrimination plots imply the BIFs of the Babina, Mauranipur, and Mahoba greenstone belts of the central Bundelkhand Greenstone Complex are formed in a back‐arc tectonic setting. [ABSTRACT FROM AUTHOR]

Clast morphometry and sedimentary facies analysis of polymictic conglomerate of the Hiriyur Formation in the Gadag greenstone Belt, Western Dharwar Craton, India, was conducted to constrain the palaeohydraulic condition, depositional environment, and type of sedimentary basin. The conglomerate grades from clast‐supported to matrix‐supported with siltstone‐sandstone intercalations. Eight lithofacies along with five major lithofacies associations are recognized in the Majjur and Attikatti Domains of the Gadag greenstone Belt. The lithofacies architecture suggests sedimentation commenced with rapid deposition of slope‐derived debris in a proximal high‐energy alluvial fan setting followed by a braided river environment. Clast morphometry and palaeohydraulic data indicate a low palaeoslope (0.000024 m/m), and stream discharge value (1.913 m3/s) calculated from the channel fill conglomerates. Greywacke overlying the conglomerate has been interpreted as turbidites from a continental slope. The accompanying 40‐m‐thick banded iron formation and carbonate rocks also support a marine context. The lack of transitional deposits between river and deep marine settings suggests that the greywacke turbidites sequence is separated from the conglomerate deposits by substantial unconformities. This change in depositional setting could be due to a change in basin subsidence rate, tectonic rejuvenation, or major sea‐level changes. [ABSTRACT FROM AUTHOR]

Passive seismic methods are considered cost‐effective and environmentally friendly alternatives to active (reflection) seismic methods. We have acquired colocated active and passive seismic surveys over a metal‐endowed Archean granite‐greenstone terrane in the Larder Lake area to investigate the reliability of estimated elastic properties using passive seismic methods. The passive seismic data were processed using two different data processing approaches, ambient noise surface‐wave tomography (ANSWT) and receiver function analysis, to generate shear‐wave velocity and P to S wave (P‐S) convertibility profiles of the subsurface, respectively. The Cadillac‐Larder Lake Fault (CLLF) was imaged as a south‐dipping subvertical zone of weak reflectivity in the reflection seismic profile. To the north of the CLLF, a package of north‐dipping reflections in the upper crust (at depths of 5–10 km) resides on the boundary of high (on the top) and low (on the bottom) shear‐wave velocity zones estimated using the ANSWT method. This package of reflections is most likely caused by overlaying mafic volcanic and underlying felsic intrusive rocks. The P‐S convertibility profile imaged the Moho boundary at ∼40‐km depth as well as a south‐dipping feature that penetrates the mantle, which is interpreted to be either caused by the delamination of the lower crust or a possible deeper extension of the Porcupine‐Destor Fault. Overall, the reflectivity, shear‐wave velocity, and P‐S convertibility profiles exhibit a good correlation and provided a detailed image of the subsurface lithological structure to a depth of 10 km. Plain Language Summary: It is becoming increasingly important to conduct mineral exploration projects in an environmentally friendly manner with minimal footprints left behind on the natural landscapes. Active source seismic reflection methods are considered the most accurate subsurface imaging geophysical prospecting methods; however, they often have high acquisition costs and might cause significant alterations to the environment. Passive seismic methods that utilize natural seismic sources can overcome most of these challenges. However, benchmark studies are still required to validate the effectiveness and accuracy of the images produced by passive seismic methods. We have conducted such a study by acquiring active and passive seismic surveys along an ∼40‐km transect in a world‐class gold mineralization zone in Larder Lake, Ontario, Canada. Passive seismic records provided a map of surface‐wave (similar to ocean waves) speeds by using everyday environmental seismic noise as well as mapping locations at depth of rock layers that convert seismic P and S waves from distant earthquakes. The good correlation between the active and passive seismic results indicated that properly designed passive seismic surveys can be used as alternatives to active seismic surveys, leading to cheaper acquisition costs and fewer disturbances to the environment and nature. Key Points: We acquired active and passive seismic surveys over a metal‐endowed region to investigate the reliability of passive seismic methodsThe seismic reflectivity, shear‐wave velocity, and P‐S convertibility profiles exhibited a very good correlation and were complementaryThis study provided detailed geophysical models of the upper crust (top 10 km) and upper mantel (beneath the Moho) in the central Abitibi [ABSTRACT FROM AUTHOR]

An occurrence of Palaeoarchaean ferropicrite cumulates and ferrobasalts is being reported from the Jojohatu area of the Iron Ore Group (IOG) greenstone belt, which is situated in the northern part of the Singhbhum Craton (eastern India). The ferropicrite cumulates contain serpentine and clinopyroxene as major constituents and spinel, magnetite, and ilmenite as accessories. Their bulk rock chemistry exhibits an extremely high amount of FeOT (19.0–20.8 wt%) and MgO (22.0–23.9 wt%) and quite low Al2O3 (4.5–5.2 wt%) and Na2O + K2O (<1.0 wt%), thus making them as one of the most Fe‐rich ferropicrite cumulates in the world. They are also characterized by high contents of compatible trace elements (Ni: 986–1,470 ppm; Cr: 990–1,256 ppm) and moderate TiO2 (1.5–1.7 wt%), Nb (15–18 ppm), and Zr (82–90 ppm). These cumulates are possibly formed due to accumulation of olivine from the ferrobasaltic melts. In comparison, ferrobasalts consisting of plagioclase, pyroxene, and opaques are alkaline in nature. Some of the plagioclase and pyroxene grains have shown a signature of metasomatic alteration, which resulted into formation of secondary minerals such as epidote, chlorite, and hornblende. They exhibit relatively low contents of FeOT (14.6–18.4 wt%), MgO (8.4–10.8 wt%), Ni (32–122 ppm), and Cr (41–131 ppm) than the ferropicrite cumulates, while TiO2 (2.9–4.1 wt%), Nb (42–61 ppm), and Zr (216–318 ppm) contents are higher. Incompatible elemental patterns and their ratios, as well as Zr/Y versus Nb/Y plot, indicate their ocean island basalts (OIB) affinity and genesis from a hot mantle plume, having mantle potential temperature of about 1,600°C and pressure of 3.5–5 GPa. Considerably low CaO (3.00–7.16 wt%) and FeO/MgO and CaO/MgO systematics indicate that the primary source of the basaltic melt could be pyroxenite. These volcanic occurrences possibly represent remnants of the OIB formed during the Palaeoarchean in the eastern part of the Indian shield. [ABSTRACT FROM AUTHOR]

The Sonakhan greenstone belt (SGB), located in the north‐eastern Bastar craton of the Indian shield, comprises mafic‐ultramafic and volcanic‐intrusive sequences in the lower stratigraphic units. We investigate the Platinum‐group element (PGE) relations of Boradih intrusion of the SGB to evaluate its tectono‐magmatic evolution. The chondrite‐normalized PGE patterns of boninitic cumulate rocks exhibit higher abundance of Palladium group PGEs (∑PPGE = 292–496 ppb) relative to the Iridium group PGEs (∑IPGE = 32–52 ppb) along with variable Au concentrations (51.34–718.05 ppb). The PGE concentrations are attributed to a boninitic parental melt, where the IPGEs in the source possibly partitioned into a monosulphide solid solution. The Cu (22–80 ppm), elevated Pt (22–238 ppb), and Pd (31–377 ppb) concentrations indicate Pt and Pd have partitioned into a semi‐metal rich melt during the later stages of crystallization. The geochemical characteristics of the basalts and ultramafic cumulates of the SGB indicate a supra‐subduction zone tectonic setting for its formation. Similar geochemical and litho‐tectonic correlations are also noticed between the SGB of Bastar craton and greenstone belts of the Eastern Dharwar craton of south India. The SGB (V/Yb =146 ± 25) and greenstone belts of Eastern Dharwar craton (V/Yb = 134 ± 52) record similar oxidation conditions of Phanerozoic subduction zones. Accordingly, we propose magmatic as well as tectonic correlations are possible for the Archean‐Palaeoproterozoic Bastar and Eastern Dharwar cratons. [ABSTRACT FROM AUTHOR]

The southern basement of the Cuddapah Basin comprises the Dharwar Batholith and greenstone belt complex. Granitoids of the batholith exhibit extensive variation in terms of geomorphology, age, mineralogy, and micro/meso scale structures. The eastern part of Dharwar Craton along 13°50′ to 14°8′N latitude and 78°45′ to 79°05′E longitude was studied to enlighten the rheological influence on crustal evolution. Frequent occurrences of migmatites of restricted dimension are observed in the south of 14°10′N latitude. The granite‐migmatite contacts are not sharp in general. Different types of migmatite complex and their relationships with granitoids as well as older country rocks represent an exhumed segment of the crustal catazone. The widespread group of migmatitic rocks are classified in a composite manner on the basis of morphology and structure. Furthermore, genetic implication vis‐a‐vis anatexis history is also evaluated. Static and dynamic modes of migmatites are recognized with reference to geothermal gradient and tectonics. Based on the degree of anatexis, two categories of migmatites are identified in the field, that is, metatexites and diatexites. In addition, metatexites are classified into four sub‐types (viz, patch, dilatant, net, and stromatic) and diatexites are also sub‐divided into two categories (viz, schollen or raft and schlieren). The hybrid nature of migmatitic rocks with both metamorphic and igneous characteristics are used to analyse pre‐ and post‐anatectic events. The preserved evidences of partial melting are marked as leucocratic patches. In situ stagnation of the melt or subsequent separation from the remaining solid provides different morphology of static mode. Importance of dihedral angle at solid–liquid contacts is also considered in the present context to describe the grain boundary penetration by partial melt. Folds, veins, and boudins of different styles and generations played significant role in dynamic mode migmatitization. The syn‐ and post‐metamorphic deformation events and granite melt generation from migmatites are schematically defined. Spatial and temporal relationships of schist‐gneiss‐migmatites of both static as well as dynamic mode reveal initiation of the crustal development by vertical accretion of ultramafic‐mafic lava and TTG. Cyclic partial remelting of the metabasic lava and TTG and underplating led to development of the lithospheric plate. Later upwelling material at convergent plate and associated heat transfer led to generation of granitic magma. The established prograde and retrograde cycle of metamorphism were possibly interrupted by crustal reworking events. This study confirms about the crustal catazone segment (with >15 km depth and >500°C) in which physical processes control generation, segregation, ascent, and emplacement of juvenile granite from migmatites. [ABSTRACT FROM AUTHOR]

The Neoarchean potassic granite from the Hosadurga region adjacent to the Chitradurga greenstone belt (CGB), part of the western Dharwar Craton (WDC), is studied for its petrogenesis. The combined field, petrographic, whole‐rock elemental, and Nd–Sr isotope data of granite and associated Tonalite–Trondhjemite–Granodiorite (TTG) gneiss from this region are presented here. The granites are alkali‐calcic to calc‐alkalic in terms of modified alkali lime index (MALI) and are weakly peraluminous (molar Al2O3/(CaO + Na2O + K2O) = 1.0–1.1). The geochemical data indicate that these are formed by the melting of TTG gneiss at depths above the garnet stability field. Isotopic data (εNd = −2.9 to −7.6 at T = 2,600 Ma, ISr = 0.715–0.729, TDM > 3.0 Ga) also show the involvement of Archean crustal sources. Trace element modelling was carried out using non‐modal equilibrium melting equation, which constraints partial melting of TTG source to a low degree (11%) for the formation of this granite. This model could also produce a major element composition consistent with this granite. The upper bounds on the magmatic temperatures (724–785°C) assessed from zircon saturation thermometry suggest that fluid influx is required. TTG samples show variable and very high positive epsilon Nd values (1.5–8.9), higher than the contemporaneous mantle, suggesting re‐melting of mafic crust. The observed high Nd isotope ratios in TTG indicate involvement of a mafic source that formed as early as ~3.8 Ga, probably as a result of global differentiation of the early Earth. [ABSTRACT FROM AUTHOR]

In this article, we present the textural, mineralogical, and geochemical studies of a suite of volcanic rocks and their economic mineral potential from the Kadiri Volcanic Province (KVP) – a greenstone belt in the Eastern Dharwar Craton (EDC) of southern peninsular India. The volcanic rocks are represented by primary pyroclastic deposits dominated by tuff breccia, minor lapilli tuff, and pyroclastic flows together with lava flows, namely, metabasalts, andesites, dacites, and rhyolites. Metabasalts and high‐Mg andesites in the KVP are associated with sporadic occurrences of disseminated‐type gold. The ancient works on gold are confined to the ductile‐brittle shear zones in en‐echelon pattern. The source of gold is likely to be from deep fractures (>200 km) at mantle depths that paved the magma to move upper crustal levels due to partial melting of peridotites which tapped the siderophile elements (Au–Ag) from deeper source. Some andesites and dacites contain atomic minerals [uranium, thorium, and rare earth element (REE)], which requires attention in future studies. Monazite occurring in such dacites is a major source of REE such as cerium (Ce), lanthanum (La), neodymium (Nd), and Yttrium (Y), contributing 50–60% of REEs. Presence of thorite (ThSiO4) in dacite, a metamict mineral, strongly radioactive containing upto 10% uranium (U). This study confirms multi‐metal mineralization in KVP, for example, gold, silver, atomic (U and Th), rare‐earths along with base metals. Emplacements of rhyolite and alkali granite appears to be synchronous with the major thermal event at 2.51 Ga of the Dharwar Craton. The diverse volcanic associations are formed in a subduction–accretion orogeny at ~2.7 Ga, coeval with the global accretion event and gold mineralization. Au–U–Th–REE abundances in the composite arc‐back arc system of Kolar‐Hutti‐Kadiri‐Jonnagiri greenstone belts of EDC are primarily attributed to devolatilization and melting of subducted oceanic slab, fluid‐fluxed metasomatism of mantle wedge and elemental cycling associated with different stages of subduction. [ABSTRACT FROM AUTHOR]

Limited taxonomic classification is possible for Archaean microbial mats and this is a fundamental limitation in constraining early ecosystems. Applying Fourier transform infrared spectroscopy (FTIR), a powerful tool for identifying vibrational motions attributable to specific functional groups, we characterized fossilized biopolymers in 3.5–3.3 Ga microbial mats from the Barberton greenstone belt (South Africa). Microbial mats from four Palaeoarchaean horizons exhibit significant differences in taxonomically informative aliphatic contents, despite high aromaticity. This reflects precursor biological heterogeneity since all horizons show equally exceptional preservation and underwent similar grades of metamorphism. Low methylene to end‐methyl (CH2/CH3) absorbance ratios in mats from the 3.472 Ga Middle Marker horizon signify short, highly branched n‐alkanes interpreted as isoprenoid chains forming archaeal membranes. Mats from the 3.45 Ga Hooggenoeg Chert H5c, 3.334 Ga Footbridge Chert, and 3.33 Ga Josefsdal Chert exhibit higher CH2/CH3 ratios suggesting mostly longer, unbranched fatty acids from bacterial lipid precursors. Absorbance ratios of end‐methyl to methylene (CH3/CH2) in Hooggenoeg, Josefsdal and Footbridge mats yield a range of values (0.20–0.80) suggesting mixed bacterial and archaeal architect communities based on comparison with modern examples. Higher (0.78–1.25) CH3/CH2 ratios in the Middle Marker mats identify Archaea. This exceptional preservation reflects early, rapid silicification preventing the alteration of biogeochemical signals inherited from biomass. Since silicification commenced during the lifetime of the microbial mat, FTIR signals estimate the affinities of the architect community and may be used in the reconstruction of Archaean ecosystems. Together, these results show that Bacteria and Archaea flourished together in Earth's earliest ecosystems. [ABSTRACT FROM AUTHOR]

The Neoarchean Shimoga greenstone belt (SGB) of western Dharwar Craton is dominated by ultramafic‐mafic‐felsic magmatic suite and sedimentary rocks. Here, we investigate the mineral chemistry and whole‐rock geochemistry of the Koppa–Herambapura mafic magmatic rocks (tholeiitic metagabbro and metabasalt) from the southern SGB in order to understand their petrogenesis and geodynamic implication. The geochemical features classify the Shimoga rocks as basaltic‐basaltic andesite with a sub‐alkaline tholeiitic signature. Both the rock types display uniform depletion in HFSE relative to LILE‐LREE, higher LILE/HFSE, and LREE/HFSE ratios (La/Nb = 1.30–8.07, Nb/Ta = 11.58–16.19, Zr/Sm = 10.24–29.77) and negative Nb–Ta, Zr–Hf, and Ti anomalies in multi‐element patterns, corresponding to magmatic arc rocks generated within intraoceanic subduction environment. Their Nb/Th (2–15), Zr/Sm (10–29), and Zr/Hf (44–233) ratios indicate a depleted to enriched mantle source, and the parental magma of the mafic rock suite was generated by low to medium degrees (~8–30%) of mantle melting at depths corresponding to spinel to garnet peridotite fields of arc‐back arc setting. Our field and analytical data suggest that the tholeiitic metagabbros were derived from depleted mantle source generated in an arc environment, whereas the metabasalts had a mantle source attributed to (a) development of juvenile back‐arc rift; (b) upwelling of MORB‐like mantle; and (c) flux‐induced melting in the compositional domain of spinel‐garnet peridotite. Based on these results, we conclude that the mafic rock suite from the southern SGB possibly marks one of the earliest Neoarchean arc‐back arc subduction in the western Dharwar Craton. [ABSTRACT FROM AUTHOR]

The Mesoarchean Kalva Rangan Durga Formation of the Shimoga greenstone belt in the western Dharwar Craton consists of orthoquartzite, ferruginous phyllite, banded ferruginous chert, and conglomerates. Thick beds of orthoquartzites of this formation are well exposed in Kalva Rangan Durga ridge, trending northeast to southwest for about 9 km, in the southwest part of the Honnali Dome. Quartzites are fine‐grained in nature and mostly composed of quartz grains and fuchsite mica. In the present study, we have collected quartzite samples and carried out geochemical, Sr, and Nd isotope analyses to decipher their paleo‐weathering conditions, provenance characteristics, and possible tectonic setting of deposition. Geochemical data indicate they are arkose to subarkose in nature. Moderate to intense chemical weathering of the source rocks of these quartzites during the Mesoarchean is suggested based on various weathering indices and ternary plots. Enriched LREE and flat to variably fractionated HREE patterns with negative Eu anomalies of quartzites indicate that they were mainly derived by weathering of tonalities, trondhjemite, and granodiorites (TTG) gneisses and granites. The relatively high concentration of Cr with variable Th/Sc and high Cr/Th ratios indicate both felsic and mafic sources for quartzites. Initial εNd values (t = 3.0 Ga) of quartzites range from −3.04 to +1.24 which further support their derivation from both older evolved continental crustal and juvenile sources. The presence of symmetrical ripple marks on the surface of quartzite indicates a shallow marine environment. [ABSTRACT FROM AUTHOR]

On the basis of phylogenetic studies and laboratory cultures, it has been proposed that the ability of microbes to metabolize iron has emerged prior to the Archaea/Bacteria split. However, no unambiguous geochemical data supporting this claim have been put forward in rocks older than 2.7–2.5 giga years (Gyr). In the present work, we report in situ Fe and S isotope composition of pyrite from 3.28‐ to 3.26‐Gyr‐old cherts from the upper Mendon Formation, South Africa. We identified three populations of microscopic pyrites showing a wide range of Fe isotope compositions, which cluster around two δ56Fe values of −1.8‰ and +1‰. These three pyrite groups can also be distinguished based on the pyrite crystallinity and the S isotope mass‐independent signatures. One pyrite group displays poorly crystallized pyrite minerals with positive Δ33S values > +3‰, while the other groups display more variable and closer to 0‰ Δ33S values with recrystallized pyrite rims. It is worth to note that all the pyrite groups display positive Δ33S values in the pyrite core and similar trace element compositions. We therefore suggest that two of the pyrite groups have experienced late fluid circulations that have led to partial recrystallization and dilution of S isotope mass‐independent signature but not modification of the Fe isotope record. Considering the mineralogy and geochemistry of the pyrites and associated organic material, we conclude that this iron isotope systematic derives from microbial respiration of iron oxides during early diagenesis. Our data extend the geological record of dissimilatory iron reduction (DIR) back more than 560 million years (Myr) and confirm that micro‐organisms closely related to the last common ancestor had the ability to reduce Fe(III). [ABSTRACT FROM AUTHOR]

The ~2.7‐Ga Taishan greenstone belt from the Eastern Block of the North China Craton has well‐exposed komatiite sections. The komatiite outcrops at Sujiagou have well‐preserved primary volcanic texture although they have experienced amphibolite‐facies metamorphism. Two komatiite lava flows are identified in the Sujiagou outcrops: "Flow Ι," with a thickness of 55 m, is characterized by poly‐sutured crust at the top, spinifex texture in the middle, and olivine cumulates at the flow bottom. "Flow ΙΙ" consists of abundant pahoehoe lava lobes with no interstitial materials. These volcanic characteristics, as well as the interbedding with terrestrial sediments, suggest that the Sujiagou komatiite erupted in a subaerial continental environment. The olivine–chromite geothermometer gives peak metamorphic temperatures from 684°C to 764°C. Phase equilibria modelling suggests that the mineral proportions and mineral compositions are consistent with a retrograde temperature of ~488°C, at which the komatiite would have low olivine Fo (79–89) and high bulk‐rock Mg# (83–90). Linear mixing of the in situ trace element compositions of the metamorphic olivine, augite, tremolite, serpentine, and chlorite from Sujiagou komatiite samples can reproduce the trace elements of representative komatiite compositions, suggesting that later metamorphism and fluid–rock interactions played key roles in trace element variations in the bulk‐rock komatiite samples. These results also imply that the "arc signature" of the Sujiagou komatiite may be an overprint from posteruption fluid alteration rather than a primary subduction geochemical feature. Therefore, the Sujiagou komatiites may belong to a part of the global plume‐related greenstone belts at ~2.7 Ga. [ABSTRACT FROM AUTHOR]

The study of climate‐driven effects on seed traits such as germination has gained momentum over the past decade as the impact of global warming becomes more apparent on the health and survival of plant diversity.Seed response to warming was evaluated in a suite of short‐range endemic species from the biodiverse Greenstone Belt of southern Western Australia. The temperature dimensions for germination in 20 woody perennials were identified using small unreplicated samples over 6 weeks on a temperature gradient plate (constant and fluctuating temperatures between 5 and 40 °C). These data were subsequently modelled against current and forecast (2070) mean monthly minimum and maximum temperatures to illustrate seasonal changes to germination timing and final percentage germination.All but one species attained full germination in at least one cell on the gradient plate. Modelling of the data suggested only minimal changes to percentage germination despite a forecast rise in diurnal temperatures over the next 50 years. Nine species were predicted to experience declines of between <1% and 7%, whilst 11 species were predicted to increase their germination by <1% to 3%. Overall, the speed of germination is predicted to increase but the timing of germination for most species shifts seasonally (both advances and delays) as a result of changing diurnal temperatures.The capacity of this suite of species to cope with warmer temperatures during a critical early life stage shows a degree of adaptation to heterogeneous environments. Predicting the effects of global change on terrestrial plant communities is crucial to managing and conserving plant diversity. [ABSTRACT FROM AUTHOR]

An exceptionally well‐exposed part of the Flin Flon Greenstone Belt (Manitoba/Saskatchewan) is used to characterize the mineral assemblage evolution associated with prehnite–pumpellyite through amphibolite facies metamorphism of basalts. Data from these rocks are combined with a large literature data set to assess the ability of current thermodynamic models to reproduce natural patterns, evaluate the use of metabasic rocks at these grades to estimate pressure–temperature (P–T) conditions of metamorphism, and to comment on the metamorphic devolatilization that occurs. At Flin Flon, five major isograds (actinolite‐in, prehnite‐ and pumpellyite‐out, hornblende‐in, oligoclase‐in, and actinolite‐out) collectively represent passage from prehnite–pumpellyite to lower amphibolite facies conditions. The evolution in mineral assemblages occurs in two narrow (~1,000 m) zones: the prehnite–pumpellyite to greenschist facies (PP‐GS) transition and greenschist to amphibolite facies (GS‐AM) transition. Across the GS‐AM transition, significant increases in the hornblende and oligoclase proportions occur at the expense of actinolite, albite, chlorite, and titanite, whereas there is little change in the proportions of epidote. The majority of this mineral transformation occurs above the oligoclase‐in isograd within the hornblende–actinolite–oligoclase zone. Comparison with thermodynamic modelling results suggests data set 5 (DS5) of Holland and Powell (1998, Journal of Metamorphic Geology, 16(3):309–343) and associated activity–composition (a–x) models is generally successful in reproducing natural observations, whereas data set 6 (DS6) (Holland & Powell, 2011, Journal of Metamorphic Geology, 29(3):333–383) and associated a–x models fail to reproduce the observed mineral isograds and compositions. When the data from Flin Flon are combined with data from the literature, two main pressure‐sensitive facies series for metabasites are revealed, based on prograde passage below or above a hornblende–albite bathograd at ~3.3 kbar: a low‐pressure 'actinolite–oligoclase type' facies series, characterized by the appearance of oligoclase before hornblende, and a moderate‐ to high‐pressure 'hornblende–albite type' facies series, characterized by the appearance of hornblende before oligoclase. Concerning the PP‐GS transition, the mineral assemblage evolution in Flin Flon suggests it occurs over a small zone (<1,000 m), in which assemblages containing true transitional assemblages (prehnite and/or pumpellyite coexisting with actinolite) are rare. This contrasts with thermodynamic modelling, using either DS5 or DS6, which predicts a wide PP‐GS transition involving the progressive appearance of epidote and actinolite and disappearance of pumpellyite and prehnite. Patterns of mineral assemblages and thermodynamic modelling suggest a useful bathograd ('CHEPPAQ bathograd'), separating prehnite–pumpellyite‐bearing assemblages at low pressures and pumpellyite–actinolite‐bearing assemblages at higher pressures, occurs at ~2.3 to 2.6 kbar. Observations from the Flin Flon sequence suggests devolatilization across the GS‐AM transition (average: ~1.8 wt% H2O) occurs over a very narrow interval within the actinolite–hornblende–oligoclase zone, associated with the loss of >75% of the total chlorite. By contrast, modelling of the GS‐AM transition zone predicts more progressive dehydration of ~2 wt% H2O over a >50°C interval. Observations from the field suggest devolatilization across the PP‐GS transition occurs over a very narrow interval given the rarity of transitional assemblages. Modelling suggests fluid release of 1.0–1.4 wt% resulting from prehnite breakdown over a ~10°C interval. This fluid may not be entirely lost from the rock package due to involvement in the hydration of igneous mineralogy across the PP‐GS transition as observed in the Flin Flon sequence. [ABSTRACT FROM AUTHOR]

The Kevitsa mafic‐ultramafic intrusion, located within the Central Lapland Greenstone Belt in northern Finland, hosts a large, disseminated Ni–Cu–PGE sulphide deposit. A three‐dimensional seismic reflection survey was conducted over the Kevitsa intrusion in 2010 primarily for open‐pit mine planning and for deep mineral exploration purposes. In the Kevitsa three‐dimensional seismic data, laterally continuous reflections are observed within a constrained region within the intrusion. In earlier studies, it has been suggested that this internal reflectivity mainly originates from contacts between the tops and more sulphide‐rich bottoms of smaller scale, internally differentiated magma layers that represent a spectrum of olivine pyroxenites. However, this interpretation is not unequivocally supported by the borehole data. In this study, data mining, namely the Self‐Organizing Map analysis, of extensive Kevitsa borehole data is used to investigate the possible causes for the observed internal reflectivity within the Kevitsa intrusion. Modelling of the effect of mineralization and alteration on the reflectivity properties of Kevitsa rock types, based on average modal compositions of the rock types, is presented to support the results of the Self‐Organizing Map analysis. Based on the results, we suggest that the seismic reflectivity observed within the Kevitsa intrusion can possibly be attributed to alteration, and may also be linked to the presence of sulphide minerals. [ABSTRACT FROM AUTHOR]

Recent advancements in geophysical exploration have been realized through reliably integrating unmanned aerial vehicle platforms with lightweight, high‐resolution magnetometer payloads. Unmanned aerial vehicle aeromagnetic surveys can provide a contemporary data product between the two end‐members of coverage and resolution attained using manned airborne and terrestrial magnetic surveys. This new data product is achievable because unmanned aerial vehicle platforms can safely traverse with magnetometer payloads at flight elevations closer to ground targets than manned airborne surveys, while also delivering an increased coverage rate compared to walking conventional terrestrial surveys. This is a promising new development for geophysical and mineral exploration applications, especially in variable terrains. A three‐dimensional unmanned aerial vehicle aeromagnetic survey was conducted within the Shebandowan Greenstone Belt, northwest of Thunder Bay, Ontario, Canada, in July 2017. A series of two‐dimensional grids (∼500 m × 700 m) were flown at approximate elevations of 35, 45 and 70 m above ground level using a Dà‐Jiāng Innovations multi‐rotor unmanned aerial vehicle (S900) and a GEM Systems, Inc., Potassium Vapour Magnetometer (GSMP‐35U). In total, over 48 line‐km of unmanned aerial vehicle aeromagnetic data were flown with a line spacing of 25 m. The collected aeromagnetic data were compared to a regional heliborne aeromagnetic survey flown at an elevation of approximately 85 m above the terrain, with a line spacing of 100 m, as well as a follow‐up terrestrial magnetic survey. The first vertical derivative of the gathered unmanned aerial vehicle total magnetic field data was calculated both directly between each of the different flight elevations, and indirectly by calculating the values predicted using upward continuation. This case study demonstrates that low flight elevation unmanned aerial vehicle aeromagnetic surveys can reliably collect industry standard total magnetic field measurements at an increased resolution when compared to manned airborne magnetic surveys. The enhanced interpretation potential provided by this approach also aided in delineating structural controls and hydrothermal fluid migration pathways (a pair of adjacent shear zones) related to gold mineralization on site. These structural features were not clearly resolved in the regional manned airborne magnetic data alone, further demonstrating the utility of applying high‐resolution unmanned aerial vehicle aeromagnetic surveys to mineral exploration applications. The conclusions and interpretations drawn from the unmanned aerial vehicle aeromagnetic data, coupled with historical data, were applied to make a new gold mineralization discovery on the site, assayed at 15.7 g/t. [ABSTRACT FROM AUTHOR]

In 2017, the Metal Earth multi‐disciplinary exploration project acquired a total of 921 km of regional deep seismic reflection profiles and 184 km of high‐resolution seismic reflection profiles in the Abitibi and Wabigoon greenstone belts of the Superior province of Canada. The Abitibi belt hosts several world‐class mineral deposits, whereas the Wabigoon has sparse economic mineral deposits. Two high‐resolution surveys in the Swayze area, a poorly endowed part of the western Abitibi greenstone belt, served as pioneer surveys with which to better understand subsurface geology and design a strategy to process other surveys in the near future. Swayze seismic data were acquired with crooked survey geometries along roads. Designing an effective seismic processing flow to address these geometries and complex geology required straight common midpoint lines along which both two‐dimensional prestack dip‐moveout correction and poststack migration processing were applied. The resulting seismic sections revealed steeply dipping and subhorizontal reflections; some correlate with folded surface rocks. An interpreted fault/deformation zone imaged in Swayze north would be a target for metal endowment if it extends the Porcupine–Destor structure. Because of the crooked line geometry of the surveys, two‐dimensional /three‐dimensional prestack time migration and swath three‐dimensional processing were tested. The prestack time migration algorithm confirmed reflections at the interpreted base of the Abitibi greenstone belt. The swath three‐dimensional images provided additional spatial details about the geometries of some reflections, but also had less resolution and did not detect many reflectors observed in two dimensions. Geological contacts between felsic, mafic and ultramafic greenstone rock layers are thought the main cause of reflectivity in the Swayze area. [ABSTRACT FROM AUTHOR]

The Neoarchean Sonakhan greenstone belt (SGB) in the north‐eastern Bastar Craton is mainly composed of an association of pillowed and massive tholeiitic basalts emplaced within an intraoceanic environment. Two types of ultrabasic rocks were identified and are designated as TH‐1 and TH‐2 on the basis of geochemical parameters. Both sample suites exhibit depletion of HFSE with reference to LILE and LREE, LREE/HFSE ratios, and negative Nb–Ta–Ti anomalies in the primitive mantle‐normalized multi‐element diagrams. The geochemical characters of TH‐1 and TH‐2 are consistent with Island arc tholeiites (IAT) and boninite‐like rocks of both Archean and Phanerozoic terranes. Mineral chemistry of clinopyroxenes from both volcanic suites indicate an oceanic arc affinity. The chromite chemistry indicate its derivation from a boninite‐like magma in a suprasubduction zone (SSZ) environment. Trace element modelling depicts that source depletion with significant influence of fluids derived from the subducting oceanic slab collectively controlled the trace element inventory of the mantle wedge, which result to the higher abundance of LREE and LILE compared to HREE and HFSE. The occurrence of lower basalt sequence followed by IAT and boninite‐like rocks in the SGB define a magmatic evolution which is comparable to the Phanerozoic ophiolite suites that exhibit subduction initiation prior to forearc rifting and suprasubduction zone magmatism. The subduction initiation in the intraoceanic lithosphere and the initial decompression melting followed by the upwelling of the MORB‐related magmas were attributed to the formation of the lower pillow basalts. Dehydration of the subducting plate and the melt extraction processes in the hydrous lherzolite mantle wedge account for the formation of TH‐1. Subsequent depletion and significant modification of a more refractory harzburgite source by the slab‐derived fluids generated the TH‐2 rocks. The compositionally diverse magmatic imprints with IAT and boninite affinity in the SGB indicate the significance of episodic melt extraction processes, dehydration of the subducting plate, and hydrous fluxing in SSZ tectonic setting. [ABSTRACT FROM AUTHOR]

Archean spherule layers represent the only currently known remnants of the early impact record on Earth. Based on the lunar cratering record, the small number of spherule layers identified so far contrasts to the high impact flux that can be expected for the Earth at that time. The recent discovery of several Paleoarchean spherule layers in the BARB5 and CT3 drill cores from the Barberton area, South Africa, drastically increases the number of known Archean impact spherule layers and may provide a unique opportunity to improve our knowledge of the impact record on the early Earth. This study is focused on the spherule layers in the CT3 drill core from the northeastern Barberton Greenstone Belt. We present highly siderophile element (HSE: Re, Os, Ir, Pt, Ru, and Pd) concentrations and Re‐Os isotope signatures for spherule layer samples and their host rocks in order to unravel the potential presence of extraterrestrial fingerprints within them. Most spherule layer samples exhibit extreme enrichments in HSE concentrations of up to superchondritic abundances in conjunction with, in some cases, subchondritic present‐day 187Os/188Os isotope ratios. This indicates a significant meteoritic contribution to the spherule layers. In contrast to some of the data reported earlier for other Archean spherule layers from the Barberton area, the CT3 core is significantly overprinted by secondary events. However, HSE and Re‐Os isotope signatures presented in this study indicate chondritic admixtures of up to (and even above) 100% chondrite component in some of the analyzed spherule layers. There is no significant correlation between HSE abundances and respective spherule contents. Although strongly supporting the impact origin of these layers and the presence of significant meteoritic admixtures, peak HSE concentrations are difficult to explain without postdepositional enrichment processes. [ABSTRACT FROM AUTHOR]

Archean ultramafic–mafic magmatism associated with dynamic mantle melting processes represents an integral part of crustal evolution and continental growth. Archean mantle plumes and their high temperature derivatives in komatiitic magmas provide a cornerstone in understanding the thermal and chemical evolution of the early Earth and its mantle. In this study, we evaluate the geochemical characteristics of the temporally distinct Sargur Group and Dharwar Supergroup greenstone belts of Dharwar Craton in southern India. The komatiites associated with these greenstone belts are characterized by Al‐depleted and Al‐undepleted compositions. Their MgO, Ni, Co, and Cr concentrations reflect primitive, undifferentiated nature of precursor melts, whereas the HFSE and REE chemistry corroborates high‐degree (30–50%) partial melting of mantle with prominent role of majorite garnet and perovskite in the generation of komatiitic melts. The Al‐depleted komatiites were formed at a greater depth (~13 GPa) by equilibrium melting leaving a garnet‐bearing residue. The resultant komatiitic melt retained buoyancy under extreme pressure and high temperature conditions, segregated and accumulated in the ambient peridotite mantle source and subsequently escaped with progressive decrease in pressure in the ascending plume. The Al‐undepleted and relatively rare Al‐enriched komatiites were derived by fractional melting at intermediate to shallow depths after the discharge of a large proportion of melt ensued by the collapse and entrance of residual garnet into the melt phase. The Mesoarchean–Neoarchean Dharwar komatiites provide evidence for heterogeneous, hydrated Archean upper mantle trapped by ascending mantle plumes. The non‐plume, arc‐related signatures invoke contributions from (a) sub‐cratonic lithospheric mantle roots influenced by ancient subduction events and (b) hydrated Archean upper mantle. The Sargur Group and Dharwar Supergroup komatiites record a distinct temporal transition and geochemical heterogeneity in the Archean mantle beneath the Dharwar Craton and can be attributed to Archean upper mantle hydration by flat slab subduction of >3.3 Ga oceanic crust at shallow level with vestiges of primordial oceanic crust forming deep cratonic mantle roots beneath the Dharwar Craton. The temporal transition towards mantle hydration beneath Dharwar Craton during the Mesoarchean can be correlated with the onset of subduction‐driven plate tectonics and ocean–crust–mantle interactions. [ABSTRACT FROM AUTHOR]

The Neoarchaean era is characterized by rapid crustal growth corresponding to some fundamental global changes in geodynamic processes. However, the nature of crustal growth including the mechanism and tectonic setting of the Neoarchaean are controversial issues. The eastern Dharwar Craton (EDC) exposes widespread Neoarchaean granite‐greenstone belts, which provide an opportunity to evaluate the various models proposed for Neoarchaean crustal growth. In this study, we present field, petrographic, and geochemical data and discuss the petrogenesis and significance for crustal evolution for a suite of previously undescribed banded gneisses, TTG (tonalite–trondhjemite–granodiorite), biotite granites, alkali feldspar granite and gabbro. These rocks are associated with Neoarchaean metavolcanic and metapelites rocks of the Tsundupalle greenstone belt, in the eastern fringe of the EDC. Whole‐rock major and trace element geochemical data are consistent with diverse sources, including both crust and enriched mantle in an evolving subduction zone. A convergent orogenic setting is proposed for interpreting the association of various granitoids in the Tsundupalle area. Finally, intrusion of crustally derived, highly silicic, alkali‐rich granite, and mantle‐derived gabbro emplaced in a post‐subduction regime is proposed. Lithospheric delamination and attendant mantle melting are suggested as possible mechanisms for generation of these rocks. The understanding of generation of the different granitoid types along with gabbro provides significant insights into the mechanism of Neoarchaean crustal growth. [ABSTRACT FROM AUTHOR]

Shales are significant sedimentary units in the Archean greenstone belts and Proterozoic Cuddapah sequence of Dharwar Craton. We present the geochemical studies of the Archean shales from the Chitradurga greenstone belt and the Proterozoic Vempalle Formation of the Cuddapah Basin to evaluate their chemical composition, weathering, provenance, and depositional conditions. The Archean shales are depleted in transition metals (Ni and Co) but enriched in V, Cr, and Sc relative to upper continental crust, while the Proterozoic shales are depleted in Cr, Co, Ni, Sc, and V compared with Post‐Archean Australian shale reflecting on negligible mafic source during their deposition. The REE patterns of these shales are uniform with moderately flat LREE and negative to positive Ce anomalies reflecting on marine conditions of their deposition. The presence of both positive and negative Ce anomalies indicate fluctuating oxic and anoxic conditions. The Archean and Proterozoic shales show negative and positive Eu anomalies, respectively, along with slightly enriched HREE. Compositional variation is observed in the Archean shales, whereas the Proterozoic counterparts were affected by sediment recycling as displayed by the Th/Sc and Zr/Sc relationship. Th/U and Th along with (Gd/Yb)n ratios display significant heavy mineral enrichment in these shales. The chemical index of alteration (CIA) and chemical index of weathering (CIW) of these shales suggest moderate to intense chemical weathering during the Archean and low to moderate weathering during Proterozoic times. The overall geochemical signatures collectively indicate granitic and tonalitic provenance for the Archean and Proterozoic shales, which were deposited in an active and passive continental margins. [ABSTRACT FROM AUTHOR]

The Chakradharpur granite gneiss (CGG) represents an uplifted Archaean basement within the North Singhbhum Orogen (NSO) of Singhbhum‐Orissa Craton in the eastern Indian shield and shares a Mesoarchaean 3.12 Ga age equivalent to the emplacement of Singhbhum granite (SBG) phase III. The CGG hosts numerous enclaves of tonalitic gneisses, metamorphosed ultramafic and mafic volcanics, metagabbros, metasediments, and conglomerates that collectively represent vestiges of an older greenstone belt preserved within it. The mineralogical composition of the ultramafic volcanic enclaves of CGG has been overprinted by greenschist facies metamorphism presenting a talc‐tremolite‐phlogopite‐actinolite assemblage with prominent development of crenulation cleavage, pressure solutions and relict spinifex texture. These are characterised by restricted low SiO2 (39.7–46.8 wt.%) at consistently high MgO (20.7–28 wt.%) contents, and geochemically classified as: (a) subalkaline (Na2O + K2O < 2) komatiite and meimechite and (b) an alkaline (Na2O + K2O > 2) type picrobasalt‐foidite‐basanite assemblage. Depleted LILE and LREE chemistry, Al2O3/TiO2 versus (Gd/Yb)N and HFSE abundances suggest that the studied Al‐undepleted Munro‐type komatiite and meimechite were derived by high degree (30%–50%), shallow level (<90 km) partial melting of a hot, anhydrous mantle plume carrying depleted components. It is suggested that the komatiite‐meimechite melts were deflected by an Archaean cratonic keel and erupted through thinned continental lithosphere at a rifted cratonic margin. Geochemical evidence of crustal contamination preserved in these komatiites are equated with minor input from reworking of older continental materials and interaction between plume‐derived asthenospheric melts and metasomatized subcontinental lithospheric mantle (SCLM). Zr/Hf, Zr/Sm, Nb/Ta, Zr/Nb, and Nb/Th ratios for the picrobasalt, high Mg basalt, foidite and basanite rocks corroborate their generation through variable degrees of partial melting of a heterogeneous lithospheric mantle source carrying depleted plume‐derived melts and enriched components from metasomatized lithosphere. Mantle processes involved assimilation of metasomatic components of SCLM by ascending melts of plume incubating at the base of lithosphere ensued by melt generation at different mantle depths extending from garnet to spinel peridotite domains. Therefore, the geochemical signatures of ultramafic enclaves in CGG invoke distinct magmatic episodes during plume‐craton interaction, melt generation at thinned craton margin to rifted continental interior and melting of metasomatized continental lithosphere that collectively contributed to the evolution of Archaean mantle lithosphere system, volcanism with diverse chemical compositions and greenstone generation in the Singhbhum Craton. [ABSTRACT FROM AUTHOR]

The Neoarchean Sonakhan Greenstone Belt, located in the northeastern fringes of Bastar Craton, Central India, is dominated by basalts, andesites, dacites, and rhyolites and also contains some basic rocks with very high MgO (up to 33.4 wt%). Chromite mineralization is present in these rocks along with the cumulates of olivine and clinopyoxenes. The rocks are classified as siliceous high‐magnesium basalts (SHMB) exhibiting enriched large ion lithophile elements (LILE) and light rare earth elements (LREE) relative to the high field strength elements. Elevated Th/Yb ratios and negative Nb‐Ta‐Ti anomalies in the primitive mantle normalized multielement diagram indicates a significant role of subduction‐related melts/fluids in their genesis. The chromites in SHMB have high Cr# (0.67–0.75) and moderate Mg# (0.11–0.5) values. Parental melt calculations in the chromites indicate that they are crystallized from an SHMB magma in an island‐arc setting. A plausible model for the genesis of the rocks of Sonakhan Greenstone Belt includes initial subduction of an intraoceanic lithosphere followed by eruption of lava in an oceanic environment. Continued subduction of the slab followed by slab rollback followed by the generation of SHMB parental magma, which was introduced into the basal portions of the lithosphere in which cumulates of olivine and clinopyroxene have been developed and the chromite mineralization occurred in the inter cumulus space. Final emplacement of the magma took place in a forearc suprasubduction‐zone environment with SHMB signature carrying the cumulates, which were located in the lower part of the lithosphere. [ABSTRACT FROM AUTHOR]

We show the effectiveness of forward and inversion modelling of high‐resolution magnetic data in deciphering the geological framework in a polydeformed Proterozoic Kaladgi basin. The Meso to Neo Proterozoic Kaladgi basin exposes platformal sediments in the northern margin of Dharwar Craton, Peninsular India. The study of high‐resolution magnetic data over Deshnur locality suggests two prominent trends NW–SE and NE–SW, followed by two minor trends of E–W and N–S. Analysis of the magnetic anomalies aided in understanding the succession of deformation events and their impact over sedimentation. The NW–SE trending Nalur shear zone marks the western contact between the Chitradurga Schist belt and Peninsular gneisses that are traced beneath the Badami sediments. The forward model suggests that the NE–SW trending block faulting resulted in generating a series of Horst and Graben structures. Three‐dimensional compact inversion of circular features bearing remanent magnetisation indicates elliptical‐shaped pipe‐like bodies. The three‐dimensional inversion of magnetic data implied thicker sediments within these Graben structures. The basement configuration depicted as elevation of magnetic basement corroborates these three‐dimensional inversion results. The derived results are validated by drill holes, and the intercepts substantiate the inferred structural setup over the study area. Available drill hole and magnetic data interpretation are combined with field information to reconstruct the tectonostratigraphy and the architecture of the Kaladgi basin around Deshnur locality. [ABSTRACT FROM AUTHOR]

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The Maevatanana greenstone belt in north-central Madagascar contains widespread exposures of tonalite-trondhjemite-granodiorite (TTG) gneisses, and is important for its concentrations of various metal deposits (e.g., chromium, nickle, iron, gold). In this paper we report on the petrography, and major and trace element compositions of the TTG gneisses within the Berere Complex of the Maevatanana area, as well as LA-ICP-MS U-Pb ages and Lu-Hf isotopic compositions of zircons from the gneisses. The gneisses consist mainly of granitoid gneiss and biotite (± hornblende) plagiogneiss, and analysis of thin sections provides evidence of crushing, recrystallization, and metasomatism related to dynamic metamorphism. Samples have large variations in their major and trace element contents, with SiO2 = 55.87-68.06 wt%, Al2O3 = 13.9-17.8 wt%, and Na2O/K2O = 0.97-2.13. Geochemically, the granitoid gneisses and biotite plagiogneisses fall on a low-Al trondhjemite to granodiorite trend, while the biotite-hornblende plagiogneisses represent a high-Al tonalite TTG assemblage. Zircon U-Pb dating shows that the Berere Complex TTG gneisses formed at 2.5-2.4 Ga. Most ∊Hf(t) values of zircons from the biotite (± hornblende) plagiogneisses are positive, while most ∊Hf(t) values from the granitoid gneisses are negative, suggesting a degree of crustal contamination. Two-stage Hf model ages suggest that the age of the protolith of the TTG gneisses was ca. 3.4-2.6 Ga, representing a period of paleocontinent formation in the Mesoarchean. Geothermometries indicate the temperature of metamorphism of the TTG gneisses was 522-612°C. Based on these data, the protolith of the TTG gneisses is inferred to have formed during the development of a Mesoarchean paleocontinent that is now widely exposed as a TTG gneiss belt (mostly lower amphibolite facies) in the Maevatanana area, and which records a geological evolution related to the subduction of an ancient oceanic crust and the collision of microcontinents during the formation of the Rodinia supercontinent. The lithological similarity of Precambrian basement, the close ages of metamorphism within greenstone belts and the comparable distribution of metamorphic grade all show a pronounced Precambrian geology similarity between Madagascar and India, which can provide significative clues in understanding the possible Precambrian Supercontinent tectonics, and also important constraints on the correlation of the two continental fragments. [ABSTRACT FROM AUTHOR]

Pillow basalt and chert form integral lithologies comprising many Archean greenstone belt packages. To investigate details of these lithologies in the >3.7 Ga Isua Greenstone Belt, SW Greenland, we measured silicon isotope compositions of quartz crystals, by secondary ion mass spectrometry, from a quartz-cemented, quartz-amygdaloidal basaltic pillow breccia, recrystallized chert and chert clasts thought to represent silica precipitation under hydrothermal conditions. The recrystallized chert, chert clasts and quartz cement have overlapping δ30Si values, while the δ30Si values of the quartz amygdules span nearly the entire range of previously published values for quartz precipitates of any age, despite amphibolite facies metamorphism. We suggest that the heterogeneity is derived from kinetic isotope fractionation during quartz precipitation under disequilibrium conditions in a hydrothermal setting, consistent with the pillow breccia origin. On the basis of the present data, we conclude that the geological context of each sample must be carefully evaluated when interpreting δ30Si values of quartz. [ABSTRACT FROM AUTHOR]

The Neoarchaean Jonnagiri greenstone terrane (JGT) is located at the centre of the arcuate Hutti-Jonnagiri-Kadiri-Kolar composite greenstone belt in the eastern Dharwar Craton. High MgO (MgO = ~14 wt.%; Nb = 0.2 ppm), low Nb (LNB) (MgO = 7.8-12 wt.%; Nb = 0.1-5.1 ppm) and high Nb basalts (HNB) (MgO = 5.6-10.1 wt.%; Nb = 9.0-10.6 ppm) metamorphosed to lower amphibolite facies are identified based on their geochemical compositions. These metabasalts exhibit depleted HFSE (Nb-Ta, Zr-Hf), pronounced LREE and LILE enrichments suggesting contribution from subduction-related components during their genesis. Th and U enrichment over Nb-Ta indicates influx of fluids dehydrated from subducted oceanic lithosphere. The high MgO basalts with higher Mg# (51) than that of the associated LNB and HNB (Mg# = 34-47) represent early fractionated melts of subduction-modified mantle peridotite. The LNB were produced by partial melting of mantle wedge metasomatized by slab-dehydrated fluids, whereas the HNB represents melts of subducted oceanic crust and hybridized mantle wedge. Lower Dy/Yb and variable La/Yb ratios suggest their generation at shallower depth within spinel peridotite stability field. The low Ce-Yb trend of these metabasalts reflects intraoceanic type subduction which straddles the fields of arc and back-arc basin basalts, resembling the Mariana-type arc basalts. The Jonnagiri metabasalts were derived in a paired arc-back-arc setting marked by nascent back-arc rift system that developed in the proximity of an intraoceanic arc. Copyright © 2014 John Wiley & Sons, Ltd. [ABSTRACT FROM AUTHOR]

Högbomite, a rare exotic mineral, is found to be associated with the vanadiferous-titaniferous (V-Ti) bearing magnetite bands at Bhakatarhalli, Nuggihalli greenstone belt, western Dharwar Craton, India. We report on a second occurrence of högbomite from the Dharwar craton in Karnataka, which is the sixth documented occurrence of this mineral from India. We evaluate the chemical characteristics of högbomite and associated Fe-Ti-minerals in an attempt to identify its formation as a primary hydrothermal mineral in a metamorphosed magnetite layer. We report here the presence of högbomite as a complex oxide of Fe, Mg, Al and Ti with accessory of Zn, V and Sn. Petrographic studies suggest the (V-Ti) bearing magnetite (Mt) contain spinel, högbomite, chlorite, martite, ilmenite (Il) and minor amounts of diaspore. The högbomite displays euhedral to subhedral textures, and is up to 250 μm along the grain boundaries of magnetite and ilmenite. In the samples studied, högbomite is prismatic, irregular and elongated in shape. The genesis of högbomite in veins between magnetite and ilmenite implies its precipitation from fluids without involving complicated reactions. Several models were proposed for the formation of högbomite; however, the subject is still debatable. [ABSTRACT FROM AUTHOR]

Phenocrystic chrome spinel crystallized in normal MORB-type greenstones in the East Takayama area. Associated phenocryst minerals show a crystallization sequence that was olivine first, followed by plagioclase, and finally clinopyroxene. Chrome spinel ranges from 0.54 to 0.77 in Mg/( Mg+ Fe2+) and 0.21 to 0.53 in Cr/( Cr+ Al); the Fe3+ content varies from 0.07 to 0.22 p.f.u. ( O = 4). Significant compositional differences of spinel were observed among the phenocryst mineral assemblages. Chrome spinel in the olivine-spinel assemblage shows a wide range in Cr/( Cr+ Al), and is depleted in Fe2+ and Fe3+. Chrome spinel in the olivine-plagioclase-clinopyroxene-spinel assemblage is Fe2+- and Fe3+-rich at relatively high Cr/( Cr+ Al) ratios. Basalt with the olivine-plagioclase-spinel assemblage contains both aluminous spinel and Fe2+- and Fe3+-rich spinel. The assumed olivine-spinel equilibrium suggests that chrome spinel in the olivine-spinel assemblage changed in composition from Cr- and Fe2+-rich to Al- and Mg-rich with the progress of fractional crystallization. Chrome spinel in the olivine-plagioclase-clinopyroxene-spinel assemblage, on the other hand, exhibits the reversed variations in Mg/( Mg+ Fe2+) and in Cr/( Cr+ Al) ratios that decrease and increase with the fractional crystallization, respectively. The entire crystallization course of chrome spinel, projected onto the Mg/( Mg+ Fe2+)- Cr/( Cr+ Al) diagram, exhibits a U-turn, and appears to be set on a double-lane route. The U-turn point lies in the compositional field of chrome spinel in the olivine-plagioclase-spinel assemblage, and may be explained by plagioclase fractionation that began during the formation of the olivine-plagioclase-spinel assemblage. [ABSTRACT FROM AUTHOR]

The Archean (2.8 Ga) Banded Iron Formation (BIF) of the Bell Lake region of Yellowknife greenstone belt, Canada is recrystallized to metamorphic assemblages of the amphibolite facies. This BIF is characterized by centimetre-scale Fe-rich and Si-rich mesobands. In the Si-rich mesobands, thin layers of magnetite microbands are developed in a quartz matrix. The Fe-rich mesobands are composed mainly of Ca-amphibole (hornblende), Fe-Mg amphibole (grunerite), and magnetite. The metamorphic foliation locally cuts across the mesoband boundaries, indicating the mesobanding was formed prior to peak metamorphism. Variations in mineral modal proportions between Fe-rich mesobands and microbands are diagnostic of depositional compositional differences between beds. Micro-X-ray fluorescence imaging reveals metamorphic differentiation within Fe-rich mesobands, with segregation of Fe-Mg amphibole, and the incompatible element Mn is concentrated at the margins of the Fe-rich mesobands during the amphibole-forming reactions. Ti was relatively immobile during metamorphic segregation and its distribution provides a record of the original structures in the Fe-rich mesobands. [ABSTRACT FROM AUTHOR]

The production of large volumes of fluid from metabasic rocks, particularly in greenstone terranes heated across the greenschist–amphibolite facies transition, is widely accepted yet poorly characterized. The presence of carbonate minerals in such rocks, commonly as a consequence of sea-floor alteration, has a strong influence, via fluid-rock buffering, on the mineral equilibria evolution and fluid composition. Mineral equilibria modelling of metabasic rocks in the system Na2O-CaO-FeO-MgO-Al2O3-SiO2-CO2-H2O (NCaFMASCH) is used to constrain the stability of common metabasic assemblages. Calculated buffering paths on T– XCO2 pseudosections, illustrate the evolution of greenstone terranes during heating across the greenschist-amphibolite transition. The calculated paths constrain the volume and the composition of fluid produced by devolatilization and buffering. The calculated amount and composition of fluid produced are shown to vary depending on P– T conditions, the proportion of carbonate minerals and the XCO2 of the rocks prior to prograde metamorphism. In rocks with an initially low proportion of carbonate minerals, the greenschist to amphibolite facies transition is the primary period of fluid production, producing fluid with a low XCO2. Rocks with greater initial proportions of carbonate minerals experience a second fluid production event at temperatures above the greenschist to amphibolite facies transition, producing a more CO2-rich fluid ( XCO2 = 0.2–0.3). Rocks may achieve these higher proportions of carbonate minerals either via more extensive seafloor alteration or via infiltration of fluids. Fluid produced via devolatilization of rocks at deeper crustal levels may infiltrate and react with overlying lower temperature rocks, resulting in external buffering of those rocks to higher XCO2 and proportions of carbonate minerals. Subsequent heating and devolatilization of these overlying rocks results in buffering paths that produce large proportions of fluid at XCO2 = 0.2–0.3. The production of fluid of this composition is of importance to models of gold transport in Archean greenstone gold deposits occurring within extensive fluid alteration haloes, as these haloes represent the influx of fluid of XCO2 = 0.2–0.3 into the upper crust. [ABSTRACT FROM AUTHOR]

Recent geological investigations of the Isua Supracrustal Belt (3.8 Ga), southern West Greenland, have suggested that it is the oldest accretionary complex on earth, defined by an oceanic plate-type stratigraphy and a duplex structure. Plate history from mid-oceanic ridge through plume magmatism to subduction zone has been postulated from analysis of the reconstructed oceanic plate stratigraphy in the accretionary complex. Comparison between field occurrence of greenstones in modern and ancient accretionary complexes reveals that two types of tholeiitic basalt from different tectonic settings, mid-oceanic ridge basalt (MORB) and oceanic island basalt (OIB), occur. This work presents major, trace and rare earth element (REE) compositions of greenstones derived from Isua MORB and OIB, and of extremely rare relict igneous clinopyroxene in Isua MORB. The Isua clinopyroxenes (Cpx) have compositional variations equivalent to those of Cpx in modern MORB; in particular, low TiO2 and Na2O contents. The Isua Cpx show slightly light (L)REE-depleted REE patterns, and the calculated REE pattern of the host magma is in agreement with that of Isua MORB. Analyses of 49 least-altered greenstones carefully selected from approximately 1200 samples indicate that Isua MORB are enriched in Al2O3, and depleted in TiO2, FeO*, Y and Zr at the given MgO content, compared with Isua OIB. In addition, Isua MORB show an LREE-depleted pattern, whereas Isua OIB forms a flat REE pattern. Such differences suggest that the Early Archean mantle had already become heterogeneous, depending on the tectonic environment. Isua MORB are enriched in FeO compared with modern MORB. Comparison of Isua MORB with recent melting experiments shows that the source mantle had 85–87 in Mg♯ and was enriched in FeO. Potential mantle temperature is estimated to be approximately 1480°C, indicating that the Early Archean mantle was hotter by at most approximately 150°C than the modern mantle. [ABSTRACT FROM AUTHOR]

Abstract The Cretaceous accretionary complexes of the Idonnappu Zone in the Urakawa area are divided into five lithological units, four of which contain greenstone bodies. The Lower Cretaceous Naizawa Complex consists of two lithologic units. The Basaltic Unit (B-Unit) is a large-scale tectonic slab of greenstone, consisting of depleted tholeiite similar to that of the Lower Sorachi Ophiolite (basal forearc basin ophiolite) in the Sorachi-Yezo Belt. The Mixed Unit of Naizawa Complex (MN-Unit) contains oceanic island-type alkaline greenstones which occur as slab-like bodies and faulted blocks with tectonically dismembered trench-fill sediments. Repeated alternations of the two units in the Naizawa Complex may have been formed by the collision of seamounts with forearc ophiolitic body (Lower Sorachi Ophiolite) in the trench. The Upper Cretaceous Horobetsugawa Complex structurally underlies the Naizawa Complex in its original configuration, and it also contains greenstone bodies. Greenstones in the MH-Unit occur as blocks and sedimentary clasts in a clastic matrix, and exhibit depleted tholeiite and oceanic-island alkaline basalt/tholeiite chemistry. This unit is interpreted as submarine slide and debris flow deposits. Greenstones in the PT-Unit occur at the base of several chert-clastic successions. Most of the greenstones are severely sheared and show normal-type mid-ocean ridge basalt composition. The PT-Unit greenstones are considered to have been derived from abyssal basement peeled off during accretion. The different accretion mechanism of the greenstones in the Naizawa and Horobetsugawa complexes reflects temporal changes in subduction zone conditions. Seamount accretion and tectonic erosion were dominant in the Early Cretaceous, due to highly oblique subduction of the old oceanic crust and minimal sediment supply. Whereas, thick sediments with minor mid-ocean ridge basalt and olistostrome accreted in the Late Cretaceous, due to near-orthogonal subduction of... [ABSTRACT FROM AUTHOR]

Abstract Greenstones, representing remnants of paleo-oceanic crust, occur in Permian and Jurassic accretionary complexes of the Inner Zone in the Southwestern Japan arc. The formation age of most of the greenstones is early Carboniferous, based on fossil ages for overlying limestones and Sm-Nd isotope ages of the greenstones themselves. The geochemistry of such greenstones is similar to those of present-day oceanic islands. Greenstones of the Permian accretionary complex (Akiyoshi belt) are alkalic and tholeiitic in composition. Some alkali basalts show peculiar features from an EM-1 mantle source, such as the Gough Island and Tristan da Chunha basalts in the South Atlantic. Greenstones of the Jurassic accretionary complex (Tamba belt) are also alkali and tholeiitic basalts with both basalt types in the northern part of the Tamba belt coming from strongly depleted characters similar to a mid-ocean ridge basalt source mantle. The variable geochemistry of the oceanic basalts is explained by hypothesis on existence of a Carboniferous mantle plume below the spreading ridge which divides the Farallon and Izanagi plates. The Akiyoshi belt seamounts and/or oceanic islands of the Farallon plate and Tamba belt seamounts and/or oceanic islands of the Izanagi plate formed simultaneously by the upwelling of the thermal plume. Some part of the Akiyoshi belt basalts originated locally from an EM-1 mantle source, while basalts from the northern parts of the Tamba belt have a normal-type mid-ocean ridge basalt (N-MORB) source component. Existence of an N-MORB signature is consistent with the presence of a spreading center in a Carboniferous ‘Pacific Ocean’ that caused separation of the Farallon and Izanagi plates. Disparity in accretion ages of the basaltic rocks in the Permian and Jurassic may have been caused by differences in the relative motion of the two plates. [ABSTRACT FROM AUTHOR]

Presents a study on the tectonic evolution of the Harare-Shamva greenstone belt in northern Zimbabwe focusing on sequential early stacking and pluton diapirism. Regional setting of the Harare-Shamva greenstone belt; Deformation and structure; Thermal constraints on regional metamorphism and doming; Age constraints; Tectonic reconstruction.