1. The Exceptional Diversity of Homoleptic Uranium–Methyl Complexes.
- Author
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Sears, Jeffrey D., Sergentu, Dumitru‐Claudiu, Baker, Tessa M., Brennessel, William W., Autschbach, Jochen, and Neidig, Michael L.
- Subjects
ELECTRONIC structure ,URANIUM compounds ,MONOMERS ,ORGANOMETALLIC compounds ,CHEMISTRY - Abstract
Homoleptic σ‐bonded uranium–alkyl complexes have been a synthetic target since the Manhattan Project. The current study describes the synthesis and characterization of several unprecedented uranium–methyl complexes. Amongst these complexes, the first example of a homoleptic uranium–alkyl dimer, [Li(THF)4]2[U2(CH3)10], as well as a seven‐coordinate uranium–methyl monomer, {Li(OEt2)Li(OEt2)2UMe7Li}n were both crystallographically identified. The diversity of complexes reported herein provides critical insight into the structural diversity, electronic structure and bonding in uranium–alkyl chemistry. [ABSTRACT FROM AUTHOR]
- Published
- 2020
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