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Organic contaminants with designed molecular bioactivity, such as pesticides and pharmaceuticals, originate from human and agricultural sources, occur frequently in surface waters, and threaten the structure and function of aquatic and terrestrial ecosystems. Congaree National Park in South Carolina (USA) is a vulnerable park unit due to its location downstream of multiple urban and agricultural contaminant sources and its hydrologic setting, being composed almost entirely of floodplain and aquatic environments. Seventy-two water and sediment samples were collected from 16 sites in Congaree National Park during 2013 to 2015, and analyzed for 199 and 81 targeted organic contaminants, respectively. More than half of these water and sediment analytes were not detected or potentially had natural sources. Pharmaceutical contaminants were detected (49 total) frequently in water throughout Congaree National Park, with higher detection frequencies and concentrations at Congaree and Wateree River sites, downstream from major urban areas. Forty-seven organic wastewater indicator chemicals were detected in water, and 36 were detected in sediment, of which approximately half are distinctly anthropogenic. Endogenous sterols and hormones, which may originate from humans or wildlife, were detected in water and sediment samples throughout Congaree National Park, but synthetic hormones were detected only once, suggesting a comparatively low risk of adverse impacts. Assessment of the biodegradation potentials of 8 14 C-radiolabeled model contaminants indicated poor potentials for some contaminants, particularly under anaerobic sediments conditions. Environ Toxicol Chem 2017;36:3045-3056. Published 2017 Wiley Periodicals Inc. on behalf of SETAC. This article is a US government work and, as such, is in the public domain in the United States of America.

Endocrine-disrupting chemicals (EDCs) in surface water and bed sediment threaten the structure and function of aquatic ecosystems. In natural, remote, and protected surface-water environments where contaminant releases are sporadic, contaminant biodegradation is a fundamental driver of exposure concentration, timing, duration, and, thus, EDC ecological risk. Anthropogenic contaminants, including known and suspected EDCs, were detected in surface water and sediment collected from 2 streams and 2 lakes in Rocky Mountain National Park (Colorado, USA). The potential for aerobic EDC biodegradation was assessed in collected sediments using 6 (14) C-radiolabeled model compounds. Aerobic microbial mineralization of natural (estrone and 17β-estradiol) and synthetic (17α-ethinylestradiol) estrogen was significant at all sites. Bed sediment microbial communities in Rocky Mountain National Park also effectively degraded the xenoestrogens bisphenol-A and 4-nonylphenol. The same sediment samples exhibited little potential for aerobic biodegradation of triclocarban, however, illustrating the need to assess a wider range of contaminant compounds. The present study's results support recent concerns over the widespread environmental occurrence of carbanalide antibacterials, like triclocarban and triclosan, and suggest that backcountry use of products containing these compounds should be discouraged.

Glyphosate use in the United States increased from less than 5,000 to more than 80,000 metric tons/yr between 1987 and 2007. Glyphosate is popular due to its ease of use on soybean, cotton, and corn crops that are genetically modified to tolerate it, utility in no-till farming practices, utility in urban areas, and the perception that it has low toxicity and little mobility in the environment. This compilation is the largest and most comprehensive assessment of the environmental occurrence of glyphosate and aminomethylphosphonic acid (AMPA) in the United States conducted to date, summarizing the results of 3,732 water and sediment and 1,018 quality assurance samples collected between 2001 and 2010 from 38 states. Results indicate that glyphosate and AMPA are usually detected together, mobile, and occur widely in the environment. Glyphosate was detected without AMPA in only 2.3% of samples, whereas AMPA was detected without glyphosate in 17.9% of samples. Glyphosate and AMPA were detected frequently in soils and sediment, ditches and drains, precipitation, rivers, and streams; and less frequently in lakes, ponds, and wetlands; soil water; and groundwater. Concentrations of glyphosate were below the levels of concern for humans or wildlife; however, pesticides are often detected in mixtures. Ecosystem effects of chronic low-level exposures to pesticide mixtures are uncertain. The environmental health risk of low-level detections of glyphosate, AMPA, and associated adjuvants and mixtures remain to be determined.

Recent national concerns regarding the environmental occurrence of emerging contaminants (ECs) have catalyzed a series of recent studies. Many ECs are released into the environment through discharges from wastewater treatment plants (WWTPs) and other sources. In 2005, the U.S. Geological Survey and the City of Longmont initiated an investigation of selected ECs in a 13.8-km reach of St. Vrain Creek, Colorado. Seven sites were sampled for ECs following a Lagrangian design; sites were located upstream, downstream, and in the outfall of the Longmont WWTP, and at the mouths of two tributaries, Left Hand Creek and Boulder Creek (which is influenced by multiple WWTP outfalls). Samples for 61 ECs in 16 chemical use categories were analyzed and 36 were detected in one or more samples. Of these, 16 have known or suspected endocrine-disrupting potential. At and downstream from the WWTP outfall, detergent metabolites, fire retardants, and steroids were detected at the highest concentrations, which commonly exceeded 1 μg/l in 2005 and 2 μg/l in 2006. Most individual ECs were measured at concentrations less than 2 μg/l. The results indicate that outfalls from WWTPs are the largest but may not be the sole source of ECs in St. Vrain Creek. In 2005, high discharge was associated with fewer EC detections, lower total EC concentrations, and smaller EC loads in St. Vrain Creek and its tributaries as compared with 2006. EC behavior differed by individual compound, and some differences between sites could be attributed to analytical variability or to other factors such as physical or chemical characteristics or distance from contributing sources. Loads of some ECs, such as diethoxynonylphenol, accumulated or attenuated depending on location, discharge, and distance downstream from the WWTP, whereas others, such as bisphenol A, were largely conservative. The extent to which ECs in St. Vrain Creek affect native fish species and macroinvertebrate communities is unknown, but recent studies have shown that fish respond to very low concentrations of ECs, and further study on the fate and transport of these contaminants in the aquatic environment is warranted.

The use of glyphosate has increased rapidly, and there is limited understanding of its environmental fate. The objective of this study was to document the occurrence of glyphosate and the transformation product aminomethylphosphonic acid (AMPA) in Midwestern streams and to compare their occurrence with that of more commonly measured herbicides such as acetochlor, atrazine, and metolachlor. Water samples were collected at sites on 51 streams in nine Midwestern states in 2002 during three runoff events: after the application of pre-emergence herbicides, after the application of post-emergence herbicides, and during harvest season. All samples were analyzed for glyphosate and 20 other herbicides using gas chromatography/mass spectrometry or high performance liquid chromatography/mass spectrometry. The frequency of glyphosate and AMPA detection, range of concentrations in runoff samples, and ratios of AMPA to glyphosate concentrations did not vary throughout the growing season as substantially as for other herbicides like atrazine, probably because of different seasonal use patterns. Glyphosate was detected at or above 0.1 μg/l in 35 percent of pre-emergence, 40 percent of post-emergence, and 31 percent of harvest season samples, with a maximum concentration of 8.7 μg/l. AMPA was detected at or above 0.1 μg/l in 53 percent of pre-emergence, 83 percent of post-emergence, and 73 percent of harvest season samples, with a maximum concentration of 3.6 μg/l. Glyphosate was not detected at a concentration at or above the U.S. Environmental Protection Agency's maximum contamination level (MCL) of 700 μg/l in any sample. Atrazine was detected at or above 0.1 μg/l in 94 percent of pre-emergence, 96 percent of post-emergence, and 57 percent of harvest season samples, with a maximum concentration of 55 μg/l. Atrazine was detected at or above its MCL (3 μg/l) in 57 percent of pre-emergence and 33 percent of post-emergence samples.

Most herbicides applied to crops are adsorbed by plants or transformed (degraded) in the soil, but small fractions are lost from fields and either move to streams in overland runoff, near surface flow, or subsurface drains, or they infiltrate slowly to ground water. Herbicide transformation products (TPs) can be more or less mobile and more or less toxic in the environment than their source herbicides. To obtain information on the concentrations of selected herbicides and TPs in surface waters of the Midwestern United States, 151 water samples were collected from 71 streams and five reservoir outflows in 1998. These samples were analyzed for 13 herbicides and 10 herbicide TPs. Herbicide TPs were found to occur as frequently or more frequently than source herbicides and at concentrations that were often larger than their source herbicides. Most samples contained a mixture of more than 10 different herbicides or TPs. The ratios of TPs to herbicide concentrations can be used to determine the source of herbicides in streams. Results of a two-component mixing model suggest that on average 90 percent or more of the herbicide mass in Midwestern streams during early summer runoff events originates from the runoff and 10 percent or less comes from increased ground water discharge.

Current and historical data show that nitrogen concentrations and flux in the Mississippi River Basin have increased significantly during the past 100 years. Most of the increase observed in the lower Mississippi River has occurred since the early 1970s and is due almost entirely to an increase in nitrate. The current (1980–99) average annual nitrogen (N) flux from the Mississippi Basin to the Gulf of Mexico is about 1 555 500 t year−1, of which about 62% is nitrate-N. The remaining 38% is organic nitrogen and a small amount of ammonium. The current (1980–99) average nitrate flux to the Gulf is almost three times larger than it was during 1955–70. This increased supply of nitrogen to the Gulf is believed to be partly responsible for the increasing size of a large hypoxic zone that develops along the Louisiana–Texas shelf each summer. This zone of oxygen-depleted water has doubled in areal extent since it was first measured in 1985. The increase in annual nitrate flux to the Gulf can be largely explained by three factors: increased fertilizer use, annual variability in precipitation and increased streamflow, and the year-to-year variability in the amount of nitrogen available in the soil-ground water system for leaching to streams. The predominant source areas for the nitrogen transported to the Gulf of Mexico are basins draining southern Minnesota, Iowa, Illinois, Indiana, and Ohio. Basins in this region yield 1801 to 3050 kg N km−2 year−1 to streams, several times the N yield of basins outside this region. Published in 2001 by John Wiley & Sons, Ltd.

An Erratum has been published for this article in Hydrological Processes 16(5) 2002, 1129–1130. Nitrate (NO3) and other nutrients discharged by the Mississippi River are suspected of causing a zone of depleted dissolved oxygen (hypoxic zone) in the Gulf of Mexico each summer. The hypoxic zone may have an adverse affect on aquatic life and commercial fisheries. The amount of NO3 delivered by the Mississippi River to the Gulf of Mexico is well documented, but the relative contributions of different sources of NO3, and the magnitude of subsequent in-stream transformations of NO3, are not well understood. Forty-two water samples collected in 1997 and 1998 at eight stations located either on the Mississippi River or its major tributaries were analysed for NO3, total nitrogen (N), atrazine, chloride concentrations and NO3 stable isotopes (δ15N and δ18O). These data are used to assess the magnitude and nature of in-stream N transformation and to determine if the δ15N and δ18O of NO3 provide information about NO3 sources and transformation processes in a large river system (drainage area 2 900 000 km2) that would otherwise be unavailable using concentration and discharge data alone. Results from 42 samples indicate that the δ15N and δ18O ratios between sites on the Mississippi River and its tributaries are somewhat distinctive, and vary with season and discharge rate. Of particular interest are two nearly Lagrangian sample sets, in which samples from the Mississippi River at St Francisville, LA, are compared with samples collected from the Ohio River at Grand Chain, II, and the Mississippi River at Thebes, IL. In both Lagrangian sets, mass-balance calculations indicate only a small amount of in-stream N loss. The stable isotope data from the samples suggest that in-stream N assimilation and not denitrification accounts for most of the N loss in the lower Mississippi River during the spring and early summer months. Published in 2001 by John Wiley & Sons, Ltd.

The environmental occurrence of trace organic compounds such as pharmaceuticals, personal care products, pesticides, and hormones, and their potential adverse effects on aquatic and terrestrial life and on human health is an issue that concerns not only scientists and engineers, but also the general public. Such trace organic compounds are being found with increasing frequency in the environment on a global scale (Halling-Sorensen et al., 1998; Kolpin et al., 2002; Ashton et al., 2004; Moldovan, 2006; Gulkowska et al., 2007). Research has shown that there is a wide variety of sources and pathways for these compounds to enter the environment (Campagnolo et al., 2002; Bound and Voulvoulis, 2005; Clara et al., 2005; Glassmeyer et al., 2005; Lindqvist et al., 2005; Brown et al., 2006; Conn et al., 2006; Larsson et al., 2007; Watkinson et al., 2007). Detection capabilities for organic compounds in the environment continue to be refined and detection levels continue to become ever lower. This has lead to the documented presence of many targeted compounds in water resources around the world including in sources of public drinking water (Wiegel et al., 2004; Focazio et al., 2008). Recent studies have focused on questions concerning contaminant environmental fate and behavior (Loffler et al., 2005), as well as wastewater and drinkingwater-treatment efficacies (Stackelberg et al., 2004; Westerhoff et al., 2005). As the evidence mounts that some of these contaminants can have human or ecological health effects (Smital, 2008) there is a need for both better understanding of their fate in environmental systems and better communication of what the results of scientific investigations mean to the general public.

Reservoirs are used to store water for public water supply, flood control, irrigation, recreation, hydropower, and wildlife habitat, but also often store undesirable substances such as herbicides. The outflow from 76 reservoirs in the midwestern USA, was sampled four times in 1992 and four times in 1993. At least one herbicide was detected in 82.6 percent of all samples, and atrazine was detected in 82.1 percent of all samples. Herbicide properties; topography, land use, herbicide use, and soil type in the contributing drainage area; residence time of water in reservoirs; and timing of inflow, release, and rainfall all can affect the concentration of herbicides in reservoirs. A GIS was used to quantify characteristics of land use, agricultural chemical use, climatic conditions, topographic character, and soil type by reservoir drainage basins. Multiple linear and logistic regression equations were used to model mean herbicide concentrations in reservoir outflow as a function of these characteristics. Results demonstrate a strong association between mean herbicide concentrations in reservoir outflow and herbicide use rates within associated drainage basins. Results also demonstrate the importance of including soils and basin hydrologic characteristics in models used to estimate mean herbicide concentrations.

Nitrate in surface water can have adverse effects on aquatic life and, in drinking-water supplies, can be a risk to human health. As part of a regional study, nitrate as N (NO 3 -N) was analyzed in water samples collected from streams throughout 10 Midwestern states during synoptic surveys in 1989, 1990, and 1994. Data from the period immediately following crop planting at 124 sites were analyzed using logistic regression to relate discrete categories of NO 3 -N concentrations to characteristics of the basins upstream from the sites. The NO 3 -N data were divided into three categories representing probable background concentrations ( 10 mg L -1 ). Nitrate-N concentrations were positively correlated to streamflow, upstream area planted in corn (Zea mays L.), and upstream N-fertilizer application rates. Elevated NO 3 -N concentrations were associated with poorly drained soils and were weakly correlated with population density. Nitrate-N and streamflow data collected during 1989 and 1990 were used to calibrate the model, and data collected during 1994 were used for verification. The model correctly estimated NO 3 -N concentration categories for 79% of the samples in the calibration data set and 60% of the samples in the verification data set. The model was used to indicate where NO 3 -N concentrations might be elevated or exceed the NO 3 -N MCL in streams throughout the study area. The potential for elevated NO 3 -N concentrations was predicted to be greatest for streams in Illinois, Indiana, Iowa, and western Ohio.

The Gunnison River drains a mountainous basin in western Colorado, and is a large contributor of water to the Colorado River. As part of a study to assess water resource sensitivity to alterations in climate in the Gunnison River basin, climatic and hydrologic processes are being modeled. A geographic information system (GIS) is being used in this study as a link between data and modelers - serving as a common data base for project personnel with differing specialties, providing a means to investigate the effects of scale on model results, and providing a framework for the transfer of parameter values among models. Specific applications presented include: (1) developing elevation grids for a precipitation model from digital elevation model (DEM) point-elevation values, and visualizing the effects of grid resolution on model results; (2) using a GIS to facilitate the definition and parameterization of a distributed-parameters, watershed model in multiple basins; and (3) nesting atmospheric and hydrologic models to produce possible scenarios of climate change.

Efforts to relate shallow ground-water quality to the land use near a well lead to several statistical difficulties. These include potential uncertainty in land-use categorical data due to misclassification, data closure, distributional skewing, and spatial autocorrelation. Methods of addressing these problems are, respectively, the establishment of limits on minimum buffer radius, the estimation of contrasts, rank-based tests of association, and subsampling to prevent buffer overlap. Relations between the presence of purgeable organic compounds in ground water and land use are used to illustrate these problems and methods.