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19. Facile Reduction of Early Transition Metal Halides with Nonconventional, Mild Reductants. Part 5. Gallium and Gallium Dichloride, New Solid‐State Reductants in Preparative Transition Metal Chemistry. New, Lower Temperature Syntheses and Convenient Isolation of Hexatantalum Tetradecachloride Octahydrate, Ta6(μ‐Cl)12Cl2 (OH2)4×4H2O, and Synthesis and Solid‐State Structure of a Tetraalkylammonium Derivative, [N(CH2Ph)Bu3]4 [Ta6(μ‐Cl)12Cl6], of the Reduced [Ta6(μ‐Cl)12]2+ Cluster Core.

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