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Synthesis of a pentasil‐type zeolite with ultra‐small few‐unit‐cell crystalline domains, which we call FDP (few‐unit‐cell crystalline domain pentasil), is reported. FDP is made using bis‐1,5(tributyl ammonium) pentamethylene cations as structure directing agent (SDA). This di‐quaternary ammonium SDA combines butyl ammonium, in place of the one commonly used for MFI synthesis, propyl ammonium, and a five‐carbon nitrogen‐connecting chain, in place of the six‐carbon connecting chain SDAs that are known to fit well within the MFI pores. X‐ray diffraction analysis and electron microscopy imaging of FDP indicate ca. 10 nm crystalline domains organized in hierarchical micro‐/meso‐porous aggregates exhibiting mesoscopic order with an aggregate particle size up to ca. 5 μm. Al and Sn can be incorporated into the FDP zeolite framework to produce active and selective methanol‐to‐hydrocarbon and glucose isomerization catalysts, respectively., A simple di‐quaternary ammonium cation was used as structure‐directing agent to prepare few‐unit‐cell (ca. 10 nm) MFI type zeolite catalysts and adsorbents with a wide range of composition (pure silica, aluminosilicate and stannosilicate). The SDA design was selected based on simple heuristic arguments regarding contributions of its structural elements to early crystal growth characteristics of MFI.

ispartof: JOURNAL OF RAMAN SPECTROSCOPY vol:52 issue:12 pages:2338-2347 status: published

Most of the heavy metals (HMs), and metals/metalloids are released into the nature either by natural phenomenon or anthropogenic activities. Being sessile organisms, plants are constantly exposed to HMs in the environment. The metal non-hyperaccumulating plants are susceptible to excess metal concentrations. They tend to sequester metals in their root vacuoles by forming complexes with metal ligands, as a detoxification strategy. In contrast, the metal-hyperaccumulating plants have adaptive intrinsic regulatory mechanisms to hyperaccumulate or sequester excess amounts of HMs into their above-ground tissues rather than accumulating them in roots. They have unique abilities to successfully carry out normal physiological functions without showing any visible stress symptoms unlike metal non-hyperaccumulators. The unique abilities of accumulating excess metals in hyperaccumulators partly owes to constitutive overexpression of metal transporters and ability to quickly translocate HMs from root to shoot. Various metal ligands also play key roles in metal hyperaccumulating plants. These metal hyperaccumulating plants can be used in metal contaminated sites to clean-up soils. Exploiting the knowledge of natural populations of metal hyperaccumulators complemented with cutting-edge biotechnological tools can be useful in the future. The present review highlights the recent developments in physiological and molecular mechanisms of metal accumulation of hyperaccumulator plants in the lights of metal ligands and transporters. The contrasting mechanisms of metal accumulation between hyperaccumulators and non-hyperaccumulators are thoroughly compared. Moreover, uses of different metal hyperaccumulators for phytoremediation purposes are also discussed in detail.