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28. Green composites and blends from leather industry waste

Author

Stefano Pandini, Luciana Sartore, Alberto D'Amore, Fabio Bignotti, Luca Di Landro, Sartore, Luciana, Bignotti, Fabio, Pandini, Stefano, D'Amore, Alberto, and Di Landro, Luca

Subjects
Materials Chemistry2506 Metals and Alloys, Bio-based components, 010407 polymers, Materials science, Hydrolyzed protein, Polymers and Plastics, Poly(ethylene-co-vinylacetate), macromolecular substances, 02 engineering and technology, 01 natural sciences, Hydrolysate, Ceramics and Composites, Chemistry (all), Rheological behaviors, chemistry.chemical_compound, Cross linking agents, Physicochemical property, Rheology, PEG ratio, Materials Chemistry, Vinyl acetate, Composite material, Biodegra-dable materials, Hydrolyzed proteins, Protein hydrolysate, chemistry.chemical_classification, technology, industry, and agriculture, General Chemistry, Transesterification, Polymer, 021001 nanoscience & nanotechnology, 0104 chemical sciences, chemistry, 0210 nano-technology, Ethylene glycol
Abstract

Blends based on protein hydrolysate (PH), derived from waste products of the leather industry, and poly(ethylene-co-vinyl acetate) (EVA), were obtained by reactive blending and their physico-chemical properties as well as their mechanical and rheological behavior were evaluated. The effect of vinyl acetate content and of a transesterification agent added to increase interaction between polymer and bio-based components were investigated. Novel biodegradable polymeric materials for spray mulching coatings were also obtained from hydrolyzed proteins and end-functionalized poly(ethylene glycol) (PEG), which was used as crosslinking agent. These products, almost entirely obtained from renewable sources, represent a new type of biodegradable material which looks promising for several applications, for instance in packaging or in agriculture as transplanting or mulching films with additional fertilizing action of PH. POLYM. COMPOS., 37:3416–3422, 2016. © 2015 Society of Plastics Engineers

Published
2015

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