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Biting midges, Culicoides spp. (Diptera: Ceratopogonidae), are important vectors of viral pathogens. Following the outbreak of bluetongue serotype 8 in Europe between 2006 and 2009, many Culicoides surveillance programmes were initiated to identify vector-active periods, in accordance with European Commission regulation 2007/1266/EC. This study utilized surveillance data from 4 years of continuous light-trapping at 14 sites in Northern Ireland. The number of captured Culicoides varied from none during the vector-free period (December–April) to more than 36 000 per night during peak activity in the summer. The Obsoletus group represented 75% of Culicoides collected and the Pulicaris group represented 21%. A total of 91% of Culicoides were female, of which 42% were parous. Abundance data, sex ratios and parous rates suggested that both the Obsoletus and Pulicaris groups underwent three generations/year. The Obsoletus group was associated with cattle-rearing habitats and woodland, the Impunctatus group was found in habitats related to sheep rearing and the Pulicaris group were associated with both cattle and sheep. Housing did not reduce incursion of female Obsoletus group Culicoides but it did for males and for the Pulicaris group Culicoides. The influence of housing was strongly affected by time of year, probably reflecting the presence of livestock indoors/outdoors.

Five varieties of willow were planted in a randomised block design at the Northern Ireland Horticulture and Plant Breeding Station, Loughgall, County Armagh in 1997. Three treatments were applied: control (no treatment), manual defoliation and routine control (spraying) of willow beetles. The defoliation was carried out at 75% for the first 2 years and thereafter 25% up to the first harvest in January 2001. During the second production cycle, no manual defoliation was applied in order to observe the ability of the different varieties to recover from earlier damage. The variety 78112 exhibited the highest yield loss in the first cycle as a result of defoliation (∼70%), while the vigorous variety Tora suffered least yield loss (35-43%). In the recovery phase (second production cycle 2001-2003), all the varieties showed little improvement in yields in plots that had been defoliated previously, indicating a long-term legacy of yield loss as a result of defoliation. The possible reasons for this inability to recover are discussed.

The phenology and some aspects of the biology of the clover weevil Sitona lepidus Gyll. were studied in the field and the laboratory. Oviposition and hatching were temperature dependent. Most eggs were laid in September and October, although there was also an oviposition period in early summer. Hatching was largely confined to late spring and early summer. The relevance of this to control strategies is discussed. Most eggs were laid on the plant but(were very easily dislodged and probably usually hatch on the ground. In no-choice tests, there were as many eggs laid on more cyanogenic as on less cyanogenic plants and cultivars. There was no evidence that the cyanogenic ability or any other cultivar characteristic would be useful in control strategies.

A series of tantalum oxyfluoride materials containing the [Ta4F16O4]4− and [Ta8F24O12]8− anion clusters have been synthesized and characterized using X-ray diffraction (XRD) and solid-state nuclear magnetic resonance (SSNMR) spectroscopy. The structure of both tantalum oxyfluoride materials display octahedrally bonded tantalum atoms with bridging oxygen and terminal fluoride atoms. The [Ta4F16O4]4− cluster is an eight-membered ring, whereas the [Ta8F24O12]8- cluster forms a cagelike structure. Solid-state dynamics of these clusters were explored by monitoring the impact of temperature on the one-dimensional (1D) 19F magic angle spinning (MAS) NMR, 13C cross-polarization (CP) MAS NMR, and two-dimensional (2D) double quantum (DQ) 19F MAS NMR spectra. The DQ 19F NMR correlation experiments allowed the through space connectivity between the different resolved fluorine environments to be determined, thus aiding in the spectral assignment and structural refinement of these materials. Ab initio 19F NMR chemical ...