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1. ChemInform Abstract: Silica Sulfuric Acid as a Highly Efficient Catalyst for the Synthesis of Diarylacetic Acids

Author

Allison E. Denton, Desiree L. Moore, Rose M. Kohinke, Brandon R. Craig, and William E. Brenzovich

Subjects
inorganic chemicals, chemistry.chemical_compound, chemistry, Silica sulfuric acid, Organic chemistry, General Medicine, Efficient catalyst, Mandelic acid, Glyoxylic acid, Catalysis
Abstract

An efficient heterogeneous method for the synthesis of diarylacetic acids was developed utilizing silica sulfuric acid as a catalyst. The reaction is highly efficient with a small amount of catalyst for the combination of a variety of electron-neutral to electron-rich arenes with glyoxylic acid. The reaction can also be utilized to synthesize unsymmetric derivatives from activated mandelic acids in good to excellent yields.

Published
2016

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