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Two complementary routes were developed for preparing novel octaphosphonate porphyrins. The use of protected/deprotected phosphonate-substituted precursors in the rational synthesis gave an overall yield 16%. A more streamlined synthetic path gave 21% overall yield of the target molecule. Octaphosphonate porphyrin possesses promising properties in supramolecular aggregate formation with cyclam. Cofacial reversible self-assembly of a meso-substituted octaphosphonate porphyrin with cyclam yields micrometer-long nanowires with a height of about 1-1.5 nm. The resulting wires were characterized by UV/Vis absorption, emission and atomic force microscopy and transmission electron microscopy.

The reaction in polyethylene glycol in the absence of any catalyst is a novel and eco-friendly method for the synthesis of pyridones.

The ring transformation of 2H-pyran-2-ones by N-aryl amidines is strongly influenced by the amidine substituents and leads to title compounds of type (III).

The ring transformation of 2H-pyran-2-ones by N-aryl amidines is strongly influenced by the amidine substituents and leads to title compounds of type (III).