1. Distorted Phthalocyanines by Click Chemistry: Photoacoustic, Photothermal, and Surface‐Enhanced Resonance Raman Studies
- Author
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Rizvi, Waqar, Berisha, Naxhije, Farley, Christopher, Bhupathiraju, N. V. S. Dinesh K., Andreou, Chrysafis, Khwaja, Emaad, Fuentes, German V., Kircher, Moritz F., Gao, Ruomei, Drain, Charles Michael, and Andreou, Chrysafis [0000-0002-3464-9110]
- Subjects
Annulation ,Isoindoles ,010405 organic chemistry ,Chemistry ,Organic Chemistry ,Resonance ,General Chemistry ,Photothermal therapy ,010402 general chemistry ,Photochemistry ,Internal conversion (chemistry) ,01 natural sciences ,Article ,Catalysis ,0104 chemical sciences ,chemistry.chemical_compound ,symbols.namesake ,Excited state ,Phthalocyanine ,symbols ,Raman spectroscopy - Abstract
Distortion of nominally planar phthalocyanine macrocycles affects the excited state dynamics in that most of the excited-state energy decays through internal conversion. A click-type annulation reaction on a perfluorophthalocyanine platform appending a seven-membered ring to the ?-positions on one or more of the isoindoles distorts the macrocycle and modulates solubility. The distorted derivative enables photoacoustic imaging, photothermal effects, and strong surface-enhanced resonance Raman signals. 25 64 14517 14521
- Published
- 2019
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