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1. ChemInform Abstract: BaNbO(IO3)5: A New Polar Material with a Very Large SHG Response

Author

Xiang Xu, Chuan-Fu Sun, Jiang-Gao Mao, Fang Kong, Ji-Bei Ling, Chun-Li Hu, Ting Hu, and Xifa Long

Subjects
chemistry.chemical_compound, chemistry, Polar material, Analytical chemistry, Thermal stability, General Medicine, Electron configuration, Iodate, Ion
Abstract

By combination of Nb5+ (having a d0 electronic configuration) and the lone-pair-containing iodate anion, a new SHG material, BaNbO(IO3)5, has been prepared. It exhibits a very large SHG response (∼14 times that of KH2PO4 and ∼660 times that of α-SiO2) and is phase-matchable. The material has high thermal stability and a wide transparent region.

Published
2009
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