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The single‐molecule conductance of a series of BN‐acene‐like derivatives has been measured by using scanning tunneling break‐junction techniques. A strategic design of the target molecules has allowed us to include azaborine units in positions that unambiguously ensure electron transport through both heteroatoms, which is relevant for the development of customized BN‐doped nanographenes. We show that the conductance of the anthracene azaborine derivative is comparable to that of the pristine all‐carbon anthracene compound. Notably, this heteroatom substitution has also allowed us to perform similar measurements on the corresponding pentacene‐like compound, which is found to have a similar conductance, thus evidencing that B–N doping could also be used to stabilize and characterize larger acenes for molecular electronics applications. Our conclusions are supported by state‐of‐the‐art transport calculations., MICINN, European Research Council (ERC), Junta de Andalucía, Comunidad de Madrid, Depto. de Química Física, Fac. de Ciencias Químicas, TRUE, pub

Life insurance enhances households' capacity to absorb financial shocks and protects against personal risks that no one likes to contemplate. This is even more important in times of economic hardship such as now, when many Europe countries and particularly Spain are going through difficult times due to rising inflation, the war in Ukraine, and the ongoing COVID-19 pandemic. Although previous studies have analysed the driving forces of life insurance demand, the influence of the individual's financial planning horizon, financial knowledge, and financial self-control have been underexplored. This study analyses the influence of personal financial attributes on life insurance demand and, in so doing, explores whether the effects of such attitudes differ across different generational cohorts (i.e., the silent generation, baby boomers, Gen Xers, and millennials). The data, taken from the Survey of Financial Competences, comprises 7245 Spanish individuals. Evidence from multivariate analyses reflects the relevance of standard sociodemographic characteristics in explaining individuals' decisions to become life insurance holders. In contrast, evidence does not support a statistically significant relationship in the case of behavioural variables such as financial self-control and the financial planning horizon

Research on consumer financial vulnerability (CFV) was especially encouraged in the aftermath of the 2007–2008 financial crisis, becoming a phenomenon of global interest to academics and policy makers. This paper reviews the existing academic literature on CFV with the aim of mapping out four research fields (i.e., the concept, the measures, the methods, and the drivers of this phenomenon) and providing a roadmap for a future research agenda for this field. To this end, we review the last two decades of academic research on households’ financial vulnerability, thereby presenting a hybrid literature review. Evidence from a comprehensive analysis of 98 academic papers suggests that this is still an emerging and highly fragmented field and, therefore, a comprehensive future research agenda is offered, including concrete suggestions for research designs and measurements. The proposal of a homogeneous definition of financial vulnerability, the consideration of measures that include subjective aspects of the phenomenon, the use of qualitative methods, and the development of more detailed theoretical and empirical research on the drivers of CFV, are among the authors’ recommendations for future research

Research on salesperson creativity remains as one of the most under-researched topics in the sales literature despite the evidence that encouraging creativity in the sales domain is a source of competitive advantage. This paper aims to fill this research gap by exploring the influence of perceived ethical climate on salesperson creative performance, paying special attention to the role that emotions play in this process. Data provided by 176 supervisor–salesperson dyads confirm that the trust/responsibility dimension of an ethical climate is positively related to salesperson creative selling by increasing salespeople's organizational pride. Similarly, the perception of unethical selling practices negatively affects salesperson organizational pride, reducing the expression of creative behaviors. Moreover, the negative effect of unethical selling practices on creative performance is stronger (more negative) when salespeople's identification with an organization increases. Managerial implications and future research directions are also addressed.

Research on salesperson creativity remains as one of the most under-researched topics in the sales literature despite the evidence that encouraging creativity in the sales domain is a source of competitive advantage. This paper aims to fill this research gap by exploring the influence of perceived ethical climate on salesperson creative performance, paying special attention to the role that emotions play in this process. Data provided by 176 supervisor–salesperson dyads confirm that the trust/responsibility dimension of an ethical climate is positively related to salesperson creative selling by increasing salespeople's organizational pride. Similarly, the perception of unethical selling practices negatively affects salesperson organizational pride, reducing the expression of creative behaviors. Moreover, the negative effect of unethical selling practices on creative performance is stronger (more negative) when salespeople's identification with an organization increases. Managerial implications and future research directions are also addressed

BACKGROUNDThe use of traps and other attract-and-kill devices in pest management strategies to reduce Mediterranean fruit fly populations has proved to be efficient. Nevertheless, many farmers are concerned about the effect of these devices on the trees where they are hung. Direct field observations have revealed that fruit damage is higher in trees with traps than in trees without them. This work evaluates the efficacy of different types of attract-and-kill device to protect fruit of the single tree on which the device is placed. RESULTSResults suggested that trees with traps had at least the same fruit damage than trees without them. When traps were baited with protein hydrolysate, fruit damage was even higher than in trees without traps. However, fruit damage was significantly diminished when efficient bait station devices were used. CONCLUSIONAlthough mass trapping is able to control fruit fly populations as a control method, trees with some types of trap and bait are more susceptible to fly puncture. However, bait station devices reduce fruit damage in the single trees where they are hung. Bait stations are more efficient in fruit protection because fruit flies are affected as soon as they contact the device. Some recommendations for the use of the different attract-and-kill devices are discussed. (c) 2014 Society of Chemical Industry

Bait stations are widely used to control Ceratitis capitata, even though the effect of intrusion from untreated areas decreases the efficacy of the technique. In this work, the edge effect of outer fruit fly populations from untreated areas and backyard orchards has been studied. For this purpose, a field trial was carried out during four years in a wide area of 10 000 ha located in Valencia (Spain). The main growing species were Prunus persica, Prunus domestica, Citrus sinensis, Citrus reticulata and Diospyros kaki. An area of 3,600 ha was treated with chemosterilant bait stations. Fruit fly populations were monitored during the 4 years of study inside and outside the treated area using Tephri-traps baited with trimedlure. A grid of 180 traps was placed in the field with an intertrap distance of 450 m. Multiple linear regression was applied to model population levels as a function of distance to untreated areas and backyards. The distance at which outer medfly populations influenced the treated wide-area population was about 1.3 km. This value reflects the distance at which a given fruit fly population is influenced by outer populations and suggests that C. capitata is able to move more than 1 km seeking for hosts. Thus, buffer areas in area-wide integrated pest management of Mediterranean fruit fly should be at least 1.3 km wide.

BACKGROUND: The control of Ceratitis capitata Wiedemann traditionally has relied on chemical control with organophosphate insecticides. The use of many of these substances has been banned by new European directives; therefore, the development of new controlmethods is essential to manage this pest. Bait sprays with spinosad,mass trapping and lure-and-kill techniques have been the base for new integrated pest management programmes. In this study, a 2 year field trial was conducted in two citrus areas to test the efficacy of attract-and-kill devices against mass trapping and spinosad-plus-bait treatments. RESULTS: TheMagnet MEDattract-and-kill device, Spintor treatments andmass trapping achievedgoodcontrolof C. capitata populations, as confirmed by low percentages of damaged fruit in the assessments performed during the harvest period. On the other hand, fly population levels on plots treated with other attract-and-kill prototype devices increased more than threefold by comparison with the populations recorded in the rest of the treated plots. The same effect was observed for fruit damage, with 6 8 times less damage with Magnet MED and spinosad treatments, respectively, than with the attract-and-kill prototype devices. CONCLUSION: By using an effective attractant, conventional trapping systems can be replaced with cheaper and easier-tohandle attract-and-kill devices. The efficacy of these devices and their advantages over conventional mass trapping systems are discussed.

BACKGROUND: In recent years, environmentally safe measures to control the California red scale (CRS), Aonidiella aurantii (Maskell), have been successfully implemented. These measures include mating disruption (MD) and biological control. The goal of this study was to examine the effect of high concentrations of the CRS sex pheromone on its life history parameters and scale-cover surface area under controlled laboratory conditions. RESULTS: The developmental time of bothmales and females of CRS increased with exposure to airborne pheromone.MD had an effect on both the total number of progeny and on the crawler production period for females. Accordingly, demographic parameters such as net fecundity (R0) and intrinsic rate of increase (rm) were significantly lower in the pheromone-treated populations. The largest scale-cover surface areas were observed in the CRS reared in the pheromone environment. CONCLUSION:Aclear influence of airborne pheromone on the biology of CRS has been demonstrated. In addition to the classical mating disruption benefits of this technique, additional benefits, such as increase in the duration of exposure to natural enemies and increase in size, which benefits some species of parasitoids, have been confirmed.

Background: New directives on sustainable use of pesticides have encouraged research on efficient alternative pest control methods. In the case of the California red scale (CRS), Aonidiella aurantii (Maskell), this imperative, along with the many difficulties in controlling this pest, have led to the investigation of new approaches. Previously developed mating disruption (MD) dispensers, together with the augmentative releases of the parasitoid Aphytis melinus DeBach, are here considered as a combined strategy for use against A. aurantii. Results: Efficacy of MD was demonstrated by a mean reduction of 80% in CRS male catches and a mean fruit damage reduction of 83% compared with the control. A delay in the development of A. aurantii instars was observed in the MD plot. This delay increased the period of exposure of the susceptible instars to natural enemies, which resulted in higher predation and parasitism levels in the MD plot. Under laboratory conditions, A. melinus mating behaviour and effects on A. aurantii were not significantly altered in a CRS-pheromone-saturated environment. Conclusion: Mating disruption pheromone did not affect the behaviour or level of parasitism by A. melinus or the incidence of other generalist predators. Therefore, A. aurantii pheromone appears to be compatible with augmentative releases and biological control, making its use a good strategy for CRS management. © 2011 Society of Chemical Industry.

BACKGROUND: The tomato leafminer (Tuta absoluta Povolny) has rapidly colonised the whole Mediterranean and South-Atlantic coasts of Spain, and it has become a key problem in both outdoor and greenhouse crops. New control methods compatible with biological control are required, and mating disruption appears to be a perfect method in current agriculture, as it is an environmentally friendly and residue-free technique. IPM packages tested have included the use of pheromones to detect populations, but there has not been much previous research on mating disruption of T. absoluta. In this work, pheromone doses varying from 10 to 40 g ha(-1), emitted at a constant rate over 4 months, were tested in greenhouses with different levels of containment in order to evaluate the efficacy of mating disruption on T. absoluta. RESULTS: Trials on containment level revealed that the flight of T. absoluta was satisfactorily disrupted with an initial pheromone dose of 30 g ha(-1), and levels of damage did not significantly differ from those in reference plots with insecticide treatments. Later efficacy trials confirmed previous experiences, and release studies showed that control of damage and flight disruption were taking place when releasing at least 85 mg pheromone per ha per day. CONCLUSION: Effective control using pheromone application against T. absoluta can be achieved, in greenhouses with high containment levels, for 4 months, with initial doses of 30 g ha(-1). Further research must be conducted in order to evaluate the prospect of outdoor application of mating disruption systems.