1. Plastic Deformation of Hydroxyapatites and Its Application to Joining
- Author
-
Jules L. Routbort, Eldon D. Case, M. de la Cinta Lorenzo-Martin, Dileep Singh, and F. Gutierrez-Mora
- Subjects
Marketing ,Materials science ,Strain (chemistry) ,Diffusion creep ,Activation energy ,Strain rate ,Condensed Matter Physics ,Stress (mechanics) ,Deformation mechanism ,Cavitation ,Materials Chemistry ,Ceramics and Composites ,Composite material ,Grain Boundary Sliding - Abstract
A plastic deformation process was demonstrated to self-join hydroxyapatite (HA), fabricating pore-free joints at 1275°C at a strain rate of 10−5 s−1. To determine optimum joining conditions, high-temperature compressive deformation of HA was investigated for strain rates between 5 × 10−6 and 10−4 s−1 at temperatures 1175–1275°C. X-ray diffraction revealed primarily the HA phase with the presence of tri- and tetra-calcium phosphate phases. Steady-state flow stresses were 0.6–45 MPa and increased with increasing strain rates. Stress exponents of ≈1 indicated a viscous diffusion-controlled deformation mechanism with an activation energy of ≈354±36 kJ/mol. Absence of cavitation and grain shape changes was consistent with grain boundary sliding.
- Published
- 2005
- Full Text
- View/download PDF