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Hydrogenolysis of the scorpionate-supported barium alkyl complex (Tp^Ad,iPr)Ba[CH(SiMe3)2](THF) (Tp^Ad,iPr = hydrotris(3-adamantyl-5-isopropyl-pyrazolyl)borate) afforded the dinuclear barium hydrido complex [(Tp^Ad,iPr)Ba(µ-H)]2 (2), which was characterized by NMR spectroscopy and single crystal X-ray analysis. Exposure of 2 with 1 atm of CO resulted in a reductive coupling process to form the cis-ethendiolate dianion (3). Reaction of 2 with one equivalent of PhCC-CCPh gave barium 1,4-diphenyl-2-butyne-1,4-diyl complex {[(Tp^Ad,iPr)Ba]2(PhCH-CC-CHPh) (4).

A series of PB-g-SAN impact modifiers (polybutadiene particles grafted by styrene and acrylonitrile) are synthesized by seed emulsion copolymerization initiated by oil-soluble initiator, azobisiobutyronitrile (AIBN). The ABS blends are obtained by mixing SAN resin with PB-g-SAN impact modifiers. The mechanical behavior and the phase morphology of ABS blends are investigated. The graft degree (GD) and grafting efficiency (GE) are investigated, and the high GD shows that AIBN has a fine initiating ability in emulsion grafting of PB-g-SAN impact modifiers. The morphology of the rubber particles is observed by the transmission electron microscopy (TEM). The TEM photograph shows that the PB-g-SAN impact modifier initiated by AIBN is more likely to form subinclusion inside the rubber particles. The dynamic mechanical analysis on ABS blends shows that the subinclusion inside the rubber phase strongly influences the Tg, maximum tan δ, and the storage modulus of the rubber phase. The mechanical test indicates that the ABS blends, which have the small and uniform subinclusions dispersed in the rubber particles, have the maximum impact strength. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007