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6 results on '"Andrew Pacheco"'

4. ChemInform Abstract: Nitrosobenzene Complexes of (Octaethylporphinato)ruthenium(II)

Author

Andrew Pacheco, Corrado Crotti, Brian R. James, and Chand Sishta

Subjects
Nitrosobenzene, chemistry.chemical_compound, chemistry, chemistry.chemical_element, General Medicine, Medicinal chemistry, Ruthenium
Abstract

Isolement du Ru(OEP)(PhNO) 2 et Ru(OEP)(PhNO)py et generation in situ de Ru(OEP)(PhNO)L ou (OEP=octaethylporphyrine, py=pyridine, L=vacant, CO, H 2 O ou PPh 3 )

Published
1988

5. ChemInform Abstract: Activation of Dihydrogen by Ruthenium(II)-Chelating Phosphine Complexes, and Activation of Dioxygen by Ruthenium(II) Porphyrin Complexes: An Update

Author

Andrew Pacheco, James A. Ibers, Richard G. Ball, S. J. Rettig, Brian R. James, and Ian S. Thorburn

Subjects
chemistry.chemical_compound, Chemistry, Asymmetric hydrogenation, chemistry.chemical_element, Chelation, General Medicine, Porphyrin, Combinatorial chemistry, Phosphine, Catalysis, Ruthenium
Abstract

This presentation reviews some recent studies from these laboratories that concern activation of dihydrogen and of dioxygen by various ruthenium complexes in solution. Part 1 describes developments in the catalytic chemistry of Ru(II)/chelating ditertiary phosphine complexes, in particular their applications in asymmetric hydrogenation, while Part 2 outlines work on O 2 -oxidation of thioethers catalyzed by Ru(II) porphyrin complexes. An experimental section, giving full details on the syntheses and characterization of the complexes, including X-ray crystallographic analyses, and on the catalysis experiments, is not given in this paper; such details will appear in future publications, but are meanwhile available on request.

Published
1988

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