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In this study, B4C-TiB2 ceramic composites were manufactured by hot pressing method. The raw materials for the in-situ synthesis of TiB2 were TiO2 and TiC. After being sintered at 1900°C for 60min under a pressure of 30MPa, compact composites samples with a TiB2 volume fraction range from 0 to 11.05% were prepared. The relative density, fracture toughness and flexural strength of different sample were tested. Microstructures on the fracture surface were studied by SEM. The result shows that B4C-TiB2 ceramic composites sintered from B4C-TiC had a better mechanical property than the one sintered from B4C-TiO2. When the content of TiB2 (reacted from TiC) was 11.05vol.%, the strength and toughness of B4C-TiB2 ceramics can reach 598MPa and 6.45MPa·m1/2. The toughening mechanisms of B4C-TiB2 composites include micro-crack toughening and energy consumption by the pulling out process of second phase.

Using the first principles method, which is based on the density function theory (DFT), the structures and electronic properties for different concentration of H2S are adsorbed on the Fe (100) surface, and their molecular orbital and absorption energies were calculated with the generalized gradient approximation. The results show that, whether one or two molecules of H2S adsorpted Fe (100) surface, adsorption of single molecules Fe (100) surface partial density of states between pure Fe (100) and two molecules, and the total density of states is mainly composed of 3d electronic contribution.

With development of network and communication technology, cable network on university campus brings much convenience for teaching and research work. But for mobility and flexibility, it has obvious shortcoming. Wireless network can overcome these drawbacks and has been applied in university campus. In this paper, we present the advantages of wireless network and propose the design standards, construction and security measures for wireless network on university campus.

Density functional theory calculations have been performed for sulfur atom adsorption on the Fe(111) surface at 0.5 and 1.0 ML. The geometry structures, density of the state, charge population and adsorption energy were calculated. It is found that the most favored adsorption site for sulfur atom is the hollow site, and the interaction between Fe and S comes in large part from the hybridization of Fe 3d orbital and S 3p orbital. Our results have shown that the force between iron atom and sulfur atom is very small.

Using periodic density functional theory within the generalized-gradient approximation to electron exchange and correlation, we have studied S adsorption four-fold hollow site on Fe(100) in different hydrostatic pressure. We find that the adsorption height decreases with hydrostatic pressure increasing is non-monotonic. The adsorption energy decreases with an increase with pressure is monotonic and we have obtained density of states is almost unchanged, the adsorption energy change is mainly caused by lattice deformation in the hydrostatic pressure, and the adsorption energies increase linearly with pressure.

Using the first principles method, which is based on the density function theory (DFT), the structures and electronic properties of S atoms are adsorbed on the Fe (100) surface for X(X is Cr, Ni, Mo, C, Mn ,Si,P and S) impurities in Fe, and their molecular orbital and absorption energies were calculated with the generalized gradient approximation. The results show that S adsorbed on H site for Cr, Ni, Mn, C and Mo impurities in Fe is stable but for Si, S and P is B site. The adsorption energy for Ni in impurity Fe is almost nearby for the purity Fe and the effect for Ni in S absorption on Fe (100) surface is very small. In order to prevent S absorption on Fe surface，we can reduce the percentage of Ni.

Using the first principles method, which is based on the density function theory (DFT), the structures and electronic properties of S atoms are adsorbed on the Fe (100) surface, and their molecular orbital and binding energies were calculated with the generalized gradient approximation. The results show that the S atom is adsorbed hollow site is stable. With partial density of states, we have obtained the interaction of s and p states for S and Fe. It shows that the interaction between the S adsorption on the clean Fe (100) surface does lead to FeS comes into being.

A back analysis procedure synthetically using parameters sensitivity analysis based on orthogonal design variance analysis, support vector regression modeling of nonlinear relation between mechanical parameters and displacement, and a hybrid optimization algorithm of particle swarm optimizer (PSO) and differential evolution (DE), was proposed. Optimum values of elasto-plastic mechanic parameters of rock mass were identified using the back analysis procedure and the measured displacement data. Assigning to the numerical model the optimum values of parameters, numerical simulation of powerhouse construction process was carried out to investigate the reliability of result of back analysis and the stability of powerhouse cavern. The result shows that calculated displacements are in good agreement with the measured, the powerhouse cavern is stable and has a considerable safety margin, and the existing support system can satisfy the need of local stability of powerhouse.