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The liquid-phase exfoliation process has been successfully applied to nonlayered materials to produce quasi-2D nanoplatelets. A slight variation in bonding anisotropy in the starting material can result in the formation of 2D platelet-shaped particles with a relatively low aspect ratio. This advancement offers a promising strategy to create 2D materials from previously unexplored materials. In this study, we investigate the liquid-phase exfoliation of arsenic sulfide (As 4 S 4 ), an intriguing nonlayered van der Waals material. The liquid exfoliation process generates highly disordered, low aspect ratio quasi-2D platelets. These As 4 S 4 flakes can be easily mixed with carbon nanotubes to create nanocomposite anodes, which are appropriate for use in both Li-ion and Na-ion batteries eliminating the need for extra binders or conductive additives. The As 4 S 4 /SWCNT electrodes exhibit impressive low-rate capacities of 1202 mA h g -1 at 0.1 A g -1 for Li-ion cells and 753 mA h g -1 at 0.05 A g -1 for Na-ion cells, along with commendable cycling stability over more than 300 cycles. Detailed quantitative rate assessment clearly shows that these electrodes are limited by solid-state diffusion and emphasizing the possibility of reaching a capacity that comes close to the theoretical value which confirms the near full utilization of the active material., Competing Interests: The authors declare no competing financial interest., (© 2024 The Authors. Published by American Chemical Society.)