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Oxygenated polycyclic aromatic hydrocarbons (OPAHs) are polycyclic aromatic hydrocarbons (PAHs) functionalized with at least one carbonyl group and are generally thought to be more toxic than PAHs. In this review, the physical-chemical properties, toxicity, occurrence, and potential sources of OPAHs in food were comprehensively discussed. The toxicities of 1,2-naphthoquinone, 1,4-naphthoquinone, 6H–benzo[cd]pyren-6-one, benzo[a]anthracene-7,12-quinone and 9,10-phenanthrenequinone were prominent among the OPAHs. Both 1,4-naphthoquinone and 1,2-naphthoquinone exhibited strong genotoxicity, cytotoxicity, and developmental toxicity. 6H–benzo[cd]pyren-6-one and benzo[a]anthracene-7,12-quinone showed high genotoxicity and cardiovascular toxicity. Although 9,10-phenanthrenequinone showed no genotoxicity, it exhibited almost the strongest cytotoxicity. For the majority of foods, the concentrations of OPAHs and PAHs were on the same order of magnitude. OPAHs tend to be positively correlated with the corresponding PAH concentrations in oil and fried food, while for barbequed food and seafood, no obvious correlation was found. In addition, 9-fluorenone, 9,10-anthraquinone, benzanthrone and 1,2-acenaphthenequinone had high abundance in food. Environmental pollution, food composition, storage conditions, heating methods, and other treatments influence the accumulation of OPAHs in food. Furthermore, oxygen and water played an important role in the transformation from PAHs to OPAHs. In short, this review guides the evaluation and further reduction of OPAH-related health risks in food. [ABSTRACT FROM AUTHOR]

The occurrence of polycyclic aromatic hydrocarbons (PAHs) in dairies has been widely reported. Consumers may be overly exposed to PAHs through dairies causing health risks. Hazards can be reduced by controlling influencing factors in the full-chain of dairy production. This review briefly introduces research trends and analytical methods concerning PAHs in dairies. Additionally, this review discusses influencing factors of PAH concentrations in various dairies to avoid PAHs' formation and accumulation during manufacture. Relevant regulations are referred to and the reported risk assessment methods are summarized. Furthermore, indicators of health risks including TEQBaP, the number and the rate of over-standard are calculated based on PAH concentrations. Through analyses, we find PAH and BaP contamination in dairies are complex problems depending on environment, processing and storage. There was a significant correlation between fat contents and PAH concentrations. Results of infant formula in certain research were worrying and those of smoked cheeses are remarkably high indicating the dangerous smoking process. It is significant to monitor PAHs and calculate TEQBaP from meadows to feeders. Moreover, the existing regulations are insufficient and need strengthening. The data and discussions in this review contribute to worldwide Big Data, further scientific investigation and regulations for PAHs in dairies. [ABSTRACT FROM AUTHOR]

Natural vitamin E, which is mainly extracted from vegetable oil deodoriser distillate (VODD), is likely contaminated by carcinogenic polycyclic aromatic hydrocarbons (PAHs). A total of 26 commercial vitamin E products from six countries were investigated for 16 EPA PAHs using QuEChERS combined with gas chromatography triple quadrupole mass spectrometry (GC-QQQ-MS). The concentrations of total PAHs in the samples ranged from 46.5 μg kg−1 to 215 μg kg−1, while the concentrations of PAH4 (BaA, Chr, BbF and BaP) ranged from 4.43 μg kg−1 to 20.1 μg kg−1. Risk assessment indicates that maximum intake of PAHs is 0.2 mg day−1, which is less than the LD50 and no observed adverse effect levels (NOAEL) of PAHs. However, chronic carcinogenicity of PAHs needs to be considered. The results suggested that PAH concentrations as well as toxicity equivalent should be considered as important indicator of risk of vitamin E products. [ABSTRACT FROM AUTHOR]

Edible coatings and films are very promising and are one of the most analyzed strategies for maintenance of the quality of foods and improving their shelf life. They provide an effective approach to mitigate adverse environmental concerns arising from the use of petroleum-derived packaging by replacing them with edible or biodegradable food packaging substances. Lipids are widely used in edible coatings and films for protecting many food products. This document is a comprehensive review describing the importance of lipids in edible coating and film formulations. A detailed account of lipid and lipid-containing edible coatings and films is presented. We also surveyed the trends in the literature related to this work, using data from SciFinder and Scopus scientific databases. The findings infer that lipids are becoming a hotspot and important substance in the study of edible coatings or films. This review further covers the application of lipid-containing coatings and films to various types of foods. [ABSTRACT FROM AUTHOR]

The bioactivity of onion, particularly its oil, has gained increasing research attention. Preparation of onion oil is challenging due to its low oil content and abundance of water. In this study, pilot-scale drying combined with laboratory extraction was conducted for sample preparation. GC/MS and solid phase microextraction (SPME) analyses were performed to evaluate the correlation between onion oil and drying. Results showed that drying significantly influenced the sulfocompounds composition of onion oils. Dipropyl disulfide and dispropyl trisulfide were the most abundant compounds in fresh onions (accounting for 68.41% to 93.13% of the total volatile sulfocompounds). The total contents of sulfocompounds in vacuum freeze dried and hot air dried onion powder were 4.96% and 39.79%, respectively, which account for 24.59% to 48.89% of the total content. Dimethyl sulfides and thiophenes were the main compounds in the onion oils. The highest content of sulfocompounds was obtained in the oil of hot air dried powder. Pilot-scale hot air drying was the optimal pretreatment method for onion oil extraction. It enjoys lower energy lost, shorter process time, and higher quality of the oil compared with freeze drying. The results may be helpful for onion oil production and bioactivity evaluation. [ABSTRACT FROM AUTHOR]

Youtiao is a typical, traditional and widely consumed fried food in China. Fermentation of youtiao involves the use of aluminium potassium sulphate (alum). There are health concerns related to the levels of aluminium in food; therefore, we aimed to determine the aluminium concentrations of youtiao from various locations, and to estimate the dietary exposure by different age groups in southern and northern China. The aluminium content of youtiao samples varied considerably (range = 4.46–852.69 mg kg−1). Both the mean and median aluminium contents of youtiao exceeded 100 mg kg−1, which is the China National Standard (GB) 2760-2014 National Food Safety for Standards for food additives. However, the median and 97.5th percentile of weekly dietary exposure to aluminium from youtiao, estimated using Monte Carlo simulation, did not exceed the provisional tolerable weekly intake (PTWI) set by the joint FAO/WHO Expert Committee on Food Additives (JECFA) for children, adolescents, adults and seniors. The weekly dietary exposure to aluminium would exceed the PTWI if children, adolescents, adults and seniors consumed 134.47, 260.98, 327.10 or 320.41 g of youtiao per week, respectively. [ABSTRACT FROM AUTHOR]

The physicochemical properties and volatile profiles of cold-pressedTrichosanthes kirilowiiMaxim (T. kirilowii) seed oils from four regions in China were determined in this study. The total oil content and cold-pressed oil yield of the four different sourced seeds were 38.06–44.33% and 15.17–30.97%, respectively. All the cold-pressed oil samples were found to be rich in polyunsaturated fatty acids, with content ranging from 45.41 to 75.32% of the total fatty acids. Punicic, α-eleostearic and catalpic acids were the main conjugated linolenic acid isomers in the cold-pressedT. kirilowiiseed oils. The results of melting and crystallization profiles indicated that each oil sample exhibited different transitions steps due to its triacylglycerol composition, crystal structure and total unsaturation. Analysis of volatile profiles showed that 2,4-nonadienal was one of the most important aldehydes in the cold-pressedT. kirilowiiseed oils, and less short chain acids (0.20%) but more esters (5.48%) were found in the sample with high content of punicic acid (Hebei sample). Results of oil quality indices indicated that cold-pressedT. kirilowiiseed oils were liable to be oxidized, and their stabilities reduced with the increase of acid values. In general, more attention should be paid to improve the oxidative stability of cold-pressedT. kirilowiiseed oils in their further application in food industry. [ABSTRACT FROM AUTHOR]