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Parallel programming libraries have been proposed to simplify programming for parallel raster-based geocomputation through hiding parallel programming details for users. However, the strategy of data domain decomposition used in existing libraries often leads to load imbalance owing to inherent characteristics of geocomputation including not only irregular spatial data distribution, but also spatial variation in the amount of computation, thereby impeding their parallel performances. This paper thus proposes a load-balancing strategy of data domain decomposition in parallel programming libraries for raster-based geocomputation based on the concept of spatial computational domain, which characterizes the distribution of computational intensity based on geocomputation characteristics. By implementing the proposed strategy with the message passing interface (MPI), a set of parallel raster-based geocomputation operators across different parallel computing platforms (known as PaRGO V2) was upgraded to improve load-balancing parallelization. The proposed strategy was evaluated by parallelizing two typical geocomputation algorithms (i.e. inverse distance weight interpolation and fuzzy c-means clustering) using PaRGO V2 with uneven distributed computational intensity. The results show that the proposed strategy with PaRGO V2, compared with the previously adopted data domain decomposition strategy, yielded significant improvements to the load balance (i.e. better parallel performance). [ABSTRACT FROM AUTHOR]

A new 3-trifluoromethyl-substituted triphenylamine-containing aromatic diacid monomer,N,N-bis(4-carboxyphenyl)-3-trifluoromethylaniline, was prepared by the substitution reaction of 3-trifluoromethylaniline with 4-fluorobenzonitrile, followed by alkaline hydrolysis of the dinitrile intermediate. Novel aromatic polyamides with 3-trifluoromethyl-substituted triphenylamine moieties were prepared from the diacid and various aromatic diaminesviathe direct phosphorylation polycondensation. All the polyamides were amorphous and readily soluble in many polar organic solvents such asN,N-dimethylacetamide andN-methyl-2-pyrrolidone, and could be solution-cast into transparent, tough, and flexible films with good mechanical properties. They exhibited good thermal stability with relatively high glass-transition temperatures (258–327°C), 10% weight-loss temperatures above 500°C, and char yields higher than 60% at 800°C in nitrogen. These polymers had low dielectric constants of 3.22–3.70 (100 Hz), low moisture absorption in the range of 1.75–2.58%, and high transparency with an ultraviolet–visible absorption cut-off wavelength in the 375–395 nm range. Cyclic voltammograms of the polyamide films cast onto an indium tin oxide coated glass substrate exhibited a reversible oxidation redox couple with oxidation half-wave potentials (E1/2) of 0.95–1.00 V vs. Ag/AgCl in an acetonitrile solution. [ABSTRACT FROM AUTHOR]