1. Structural and Magnetic Characterisation of the Double Perovskites AA′MnWO 6 (AA′ = Ba 2 , SrBa, Sr 2 , SrCa and Ca 2 ).
- Author
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Azad, A.K., Eriksson, S.-G., Ivanov, S.A., Rundlöf, H., Eriksen, J., Mathieu, R., and Svedlindh, P.
- Subjects
PEROVSKITE ,NEUTRON diffraction ,MAGNETIC materials - Abstract
The double perovskites AA′ MnWO 6 (AA′ = Ba 2 , SrBa, Sr 2 , SrCa and Ca 2 ) have been prepared as pure powders by a conventional solid-state reaction process. Stoichiometric amounts of BaCO 3 , SrCO 3 , CaCO 3 , MnO and WO 3 were mixed, ground and calcined in a nitrogen atmosphere. The materials have been studied by X-ray and neutron powder diffraction (NPD), and magnetization measurements. NPD and magnetization measurements have been carried out at different temperatures in order to correlate their structural and magnetic properties. Susceptibility- Temperature (χ-T) curves were measured between 2K and 200K in field cooled (FC) and zero-field-cooled (ZFC) modes with an applied field (H) up to 3T. Rietveld analysis of NPD data shows that the samples were B-site ordered perovskites with different types of lattice distortions. Magnetisation measurements at low temperatures indicate the antiferromagnetic ordering of magnetic moments. [ABSTRACT FROM AUTHOR]
- Published
- 2002
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