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In order to develop methods to further enhance oil recovery after water flooding in low permeability reservoirs by improving oil displacement efficiency, the displacement mechanism of residual oil was studied by the application of different pertinent measures. For in-depth investigation of oil displacement and variations in residual oil saturation, a large number of visual glass model displacement experiments were performed with different methods, such as changing the displacement direction, cyclic water flooding, displacement pressure difference variation and polymer flooding. In this paper, the models were divided into three (low, medium and high) permeability levels, and the residual oil after water flooding was categorized in five different types: cluster, oil film, oil drop, columnar and blind end residual oil. The experimental results showed that cluster residual oil accounted for the largest proportion after water flooding. In addition, with the increase in model permeability, cluster residual oil saturation increased and other types of residual oil saturations decreased. Compared to other methods, polymer flooding showed maximum displacement efficiency for the same displacement pressure and permeability model. The procedure was then followed by changing the displacement direction, cyclic water flooding and changing the displacement pressure difference. The different residual oil types can be activated by different methods, for example, cluster and columnar residual oil by changing the displacement direction, cluster and columnar residual oil by cyclic water flooding, cluster and oil drop residual oil by increasing displacement pressure difference. Moreover, all of the above mentioned five (05) types of residual oil can be activated by polymer flooding. [ABSTRACT FROM AUTHOR]

In this paper, wax deposition in waxy crude oil transportation process was regarded as an irreversible process. Based on the entropy production rate equations, the linear phenomenological equations for the diffusion of wax molecules were derived by using the theory and method of non-equilibrium thermodynamics and heat-mass transfer. Combined with the mass and energy conservation laws, the differential equations of heat and mass transfer in the process of pipeline transportation were established, and the molecular diffusion rate of dissolved wax was solved. On the basis of this, the mathematical model of actual wax deposition rate was established by considering the attachment process and scouring process of the wax molecules. Taking an oil pipeline in Daqing as an example, the change law and influencing factors of the wax molecular diffusion coefficient, the wax deposition rate, and the net wax deposition rate were studied by numerical simulation. The wax deposition rate test results of the laboratory loop test were compared with the theoretical calculation results in order to analyze the accuracy and the adaptability of heat and mass coupling mechanism and to provide a theoretical basis for further study of wax deposition in the process of waxy oil pipeline transportation. [ABSTRACT FROM AUTHOR]

Based on the phase equilibrium model of the paraffin wax precipitation in the process of oil pipeline transportation, theory and method of non-equilibrium thermodynamics were applied to obtain the linear phenomenological equations for the cross-interaction of heat and mass transfer during pipeline transport, which were derived from the irreversible entropy production rate equation. Then, the analysis of the irreversible heat flow and the mass flow were carried out, and the mathematical expressions of the phenomenological coefficient of liquid phase, the phenomenological coefficient of solid phase flow, and the heat flow phenomenological coefficient were obtained. Taking a waxy crude oil transportation pipeline in Daqing Oilfield as an example, based on the analysis of liquid–solid phase equilibrium, the irreversible linear phenomenological mechanism of heat and mass coupling in waxy crude oil pipeline transportation was analyzed in detail from three levels: phenomenological coefficients which reflect characteristic of the effect of force on flow in heat and mass transfer; thermodynamic forces which trigger heat and mass transfer; transmitted heat and mass flow density, providing a theoretical basis for the further study of the wax deposition in the process of pipeline transportation. [ABSTRACT FROM PUBLISHER]