1. The Tetra[N-phenylanthranilato](O,O')bis[(2-amino-4-methyl)pyridine Copper(II)] Complex Crystal
- Author
-
Hakan Dal, Abdullah Titiz, Murat Taş, Elif Karabağ, Mehmet Ataseven, Mukadder Kaya, Anadolu Üniversitesi, Fen Fakültesi, Fizik Bölümü, Dal, Hakan, Fakülteler, Fen - Edebiyat Fakültesi, Kimya Bölümü, and Taş, Murat
- Subjects
Carboxylate Ligands ,biology ,Stereochemistry ,Interactions ,Supramolecular chemistry ,chemistry.chemical_element ,biology.organism_classification ,Ring (chemistry) ,Copper ,Inorganic Chemistry ,Crystal ,chemistry.chemical_compound ,Crystallography ,chemistry ,Binuclear Copper Complex ,Pyridine ,Tetra ,Molecule ,Physical and Theoretical Chemistry ,Amino Acids ,O Donor Ligands ,Dichloromethane - Abstract
WOS: 000319325600022, Tetra[N-phenylanthranilato](O,O)bis[2-amino-4-methyl) pyridine copper(II)] (bisdichloromethane solvate and unsolvate) in one crystalline contains two independent binuclears, one of which is unsolvate and the other one is dichloromethane solvate. The phenyl ring planes in the asymmetric units were not parallel to each other [44.47(14)degrees and 52.50(13)degrees for unsolvate unit, 53.30(14)degrees and 49.59(13)degrees for solvate unit] and the distance between the two centers of phenyl rings was measured as 5.064 angstrom (for Cg2-Cg3), 5.005 angstrom (for Cg4-Cg5), 5.048 angstrom (for Cg7-Cg8), and 5.088 angstrom (for Cg9-Cg10) for NPA ligands. The complex molecules showed three dimensional supramolecular networks by OH center dot center dot center dot O, CH center dot center dot center dot O, CH center dot center dot center dot, and center dot center dot center dot interactions.
- Published
- 2013