1. Effect of Magnesium on Microstructure Refinements and Properties Enhancements in High-Strength CuNiSi Alloys
- Author
-
Jialun Zhu, Tao Xiao, Qian Lei, Ze-Ru Liu, Zhou Li, Shengyao Li, and Xiaofei Sheng
- Subjects
010302 applied physics ,Materials science ,Precipitation (chemistry) ,Magnesium ,Alloy ,Metals and Alloys ,Nucleation ,chemistry.chemical_element ,02 engineering and technology ,engineering.material ,021001 nanoscience & nanotechnology ,Microstructure ,01 natural sciences ,Industrial and Manufacturing Engineering ,chemistry ,0103 physical sciences ,Ultimate tensile strength ,Stress relaxation ,engineering ,Ingot ,Composite material ,0210 nano-technology - Abstract
Microalloying is an effective method to improve the comprehensive properties of copper alloys. The effects of magnesium on the microstructure, mechanical properties and anti-stress relaxation properties of CuNiSi alloys have been investigated. Results demonstrated that magnesium plays significant roles in refining the dendritic microstructure of the as-cast ingot, accelerating the precipitation decomposition, improving the mechanical properties and increasing the anti-stress relaxation properties. The incremental strength increase is due to the Orowan strengthening from the nanoscale Ni2Si and Ni3Al precipitates. As compared with the Cu–6.0Ni–1.0Si–0.5Al (wt%) alloy, the ultimate tensile strength of the designed Cu–6.0Ni–1.0Si–0.5Al–0.15Mg (wt%) alloy increases from 983.9 to 1095.7 MPa, and the electrical conductivity decreases from 27.1 to 26.6% IACS, respectively. The stress relaxation rates of the designed Cu–6.0Ni–1.0Si–0.5Al–0.15Mg alloy are 4.05% at 25 °C, 6.62% at 100 °C and 9.74% at 200 °C after having been loaded for 100 h, respectively. Magnesium significantly promotes nucleation during precipitation and maintains small precipitate size.
- Published
- 2019