1. Partial oxidation of methane into synthesis gas over a Pt-supported complex fluorite-like oxide: one-channel studies in realistic feeds
- Author
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Svetlana A. Pokrovskaya, Vladislav A. Sadykov, Aleksey S. Bobin, N. N. Sazonova, Elena L. Gubanova, Claude Mirodatos, Institut de recherches sur la catalyse et l'environnement de Lyon (IRCELYON), Université Claude Bernard Lyon 1 (UCBL), and Université de Lyon-Université de Lyon-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)
- Subjects
Methane reformer ,Inorganic chemistry ,Oxide ,chemistry.chemical_element ,[CHIM.CATA]Chemical Sciences/Catalysis ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,[SDE.ES]Environmental Sciences/Environmental and Society ,7. Clean energy ,01 natural sciences ,Catalysis ,Methane ,0104 chemical sciences ,chemistry.chemical_compound ,chemistry ,Oxidative coupling of methane ,Partial oxidation ,Physical and Theoretical Chemistry ,0210 nano-technology ,Platinum ,Syngas - Abstract
Partial oxidation of methane (POM) into synthesis gas over a single channel of monolithic catalyst 1.4 wt% Pt/Gd0.3Ce0.35Zr0.35Ox/α-Al2O3 was investigated. The effect of the catalyst pretreatment and of the process parameters (temperature, contact time, feed composition) on the catalytic activity and synthesis gas (syngas) selectivity was studied at conditions close to realistic ones with a minimum impact of the mass and heat transfer phenomena. Experimental data are in favor of the direct route of the syngas formation via the methane pyrolysis—selective oxidation sequence.
- Published
- 2009
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