1. Reactivity of heterocyclic α-aminomethylsilanes with alcohols
- Author
-
Mariusz Mojzych and Krzysztof Pypowski
- Subjects
Primary (chemistry) ,Solvent free ,010405 organic chemistry ,Organic Chemistry ,010402 general chemistry ,01 natural sciences ,Medicinal chemistry ,0104 chemical sciences ,Catalysis ,chemistry.chemical_compound ,Azepane ,chemistry ,Morpholine ,Reactivity (chemistry) ,Tertiary alcohols ,Alkoxylation - Abstract
Alkoxylation of N-substituted heterocyclic aminomethylsilyl moieties was studied using primary and tertiary alcohols. The reaction of 4-(silylmethyl)morpholine and 1-(silylmethyl)azepane under catalyst- and solvent-free conditions leads to the formation of dialkoxy- and trialkoxyaminomethylsilyl derivatives. The methanolysis of 4-(silylmethyl)morpholine resulted in trimethoxyaminomethylsilane formation as the main product and two byproducts, i.e., tetramethoxysilane and N-methylmorpholine.
- Published
- 2021