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Renewable energy sources have received much attention in recent years due to concerns about global climate and environmental changes. Solar energy appears to be a promising alternative, especially dye-sensitized solar cells (DSSC), which, according to the literature, can achieve a power conversion efficiency in excess of 11%, depending on the semiconductor oxide used in their fabrication. The aim of this paper is to investigate the performance of DSSCs using cerium oxide (CeO2), titanium oxide (TiO2), and commercial dye N719. CeO2 was obtained using the Pechini and precipitation methods. The characterization techniques employed were x-ray diffraction, Raman spectroscopy, scanning electron microscopy, ultraviolet-visible spectroscopy, dynamic light scattering, and photoelectrochemical measurements. The results indicate that the efficiency of the DSSC CeO2/TiO2 obtained using the precipitation method was about 20% higher than that of the DSSC TiO2. [ABSTRACT FROM AUTHOR]

Hybrid solar cells of semiconductor oxides and conductive polymers have been broadly studied. Poly(3-octylthiophene) (P3OT), is an organic polymer formed by conjugated structures with conductive properties, photoluminescence, a relatively high charge mobility and stability. Zinc oxide (ZnO) has been used as an electron acceptor in this cell type because it offers great electron transport properties, simple manufacturing techniques, non-toxicity, variation and morphologic control. Different ZnO morphologies allow distinct properties in terms of electronic transport in solar cell interfaces. The objective of this paper was to evaluate whether ZnO with its different morphologies can improve the anchorage of P3OT and influence the conductive properties of hybrid solar cells of ZnO/P3OT. ZnO particles were synthetized by co-precipitation with Zn(NO)·6HO in concentrations of 0.05, 0.10 and 0.15 mol L. The morphology was evaluated by scanning electron microscopy (SEM), and the suspension was evaluated by thermogravimetric analysis and differential scanning calorimetry and X-ray diffraction. Cells containing the working electrode (ZnO/P3OT) were evaluated by open circuit potential (V) and electrochemical impedance spectroscopy (EIS). The SEM images showed three morphologies: spherical ZnO (ZnOE), hexagonal ZnO (ZnOH) and ZnO without defined morphology (ZnOM) due to the variation of the precursor salt concentration. Cells with different morphologies presented medium values of V = −0.438 ± 0.027 V. The EIS indicated that ZnOM/P3OT cells have lower values of charge transfer resistance and higher values of capacitance at intermediate frequencies. ZnOM/P3OT solar cells presented the best results in relation to the electron transfer processes. [ABSTRACT FROM AUTHOR]