1. Tailoring an HSO4− anion hybrid receptor based on a phenazine derivative.
- Author
-
Qi, Xiao-Ni, Dong, Hong-Qiang, Yang, Hai-Long, Qu, Wen-Juan, Zhang, You-Ming, Yao, Hong, Lin, Qi, and Wei, Tai-Bao
- Subjects
- *
HYDROGEN bonding interactions - Abstract
A catechol-functionalized phenazine imidazole (PD) was tailored with 2,3-diaminophenazine and 3,4-dihydroxy benzaldehyde, and it served as a hybrid acceptor for capturing HSO4− anions. The selectivity and sensitivity of the PD receptor for anion sensing were studied. It was found that the PD receptor could not only display a preferable sensitivity to HSO4− ions with a "turn–off" fluorescence response, but also have a strong anti-interference ability toward other common anions, especially basic anions such as CH3COO−, HPO42−, and H2PO4−. The anion recognition mechanism of PD towards HSO4− is based on multiple hydrogen bond interactions. Finally, the strips for anion detection were prepared, which were verified to be a convenient and high-efficiency test kit for detecting HSO4− ions with the naked eye. [ABSTRACT FROM AUTHOR]
- Published
- 2020
- Full Text
- View/download PDF