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This study aimed to optimize the methods for sampling and analyzing methylmercury (MeHg) concentrated within diffusive gradients in thin films (DGT) and its application to different water bodies. We explored the elution solution for MeHg, comprised of 1.13 mM thiourea and 0.1M HCl, optimizing its volume to 50 mL. In addition, we found that it is necessary to analyze the entire extraction solution after adjusting its pH, to ensure completion of the ethylation reaction. The DGT samplers were deployed in two distinct aquatic environments (i.e., Okjeong Lake and Nakdong River) for up to 6 weeks, and this study demonstrated to predict the time-weighted average concentration with a diffusion coefficient of 7.65 × 10−6 cm2 s−1 for MeHg in the diffusive gel. To assess the diffusive boundary layer (DBL) effects, the DGT samplers with different agarose diffusive gel thickness were deployed. The mass of MeHg accumulated in the DGT resin at a given time decreased with increasing diffusive gel thickness, because of creating longer diffusion pathways within thicker gels. The labile MeHg concentration estimated by the DGT in Okjeong Lake and Nakdong River are found in the range of 61–111 and 55–105 pg L−1, respectively, which were found to be similar to the grab sampling data. Additionally, this study evaluated depth-dependent MeHg in Okjeong Lake. The vertical profile results showed that the concentration of MeHg at the depth of 2.3 and 15.7 m are about 1.5 and 4.6 times of the DGT installed at 0.3 m of the surface layer, respectively, suggesting potential mercury methylation in deep waters. These findings have practical implications for predicting bioavailability, assessing risks, and formulating strategies for water body management and contamination remediation. [ABSTRACT FROM AUTHOR]

Purpose: In this study, the effectiveness of in situ sediment capping was investigated as a remediation option for total mercury (THg) and methylmercury (MeHg) in the Hyeongsan River estuary, South Korea. Materials and methods: A small plot study was conducted by capping four different sites with different capping materials (HS1 with zeolite, HS2 with activated carbon (AC)/zeolite, HS3 with AC/sand, and HS4 with zeolite/sand), and one uncapped site (HS5) was used as a control. The capping effectiveness was evaluated ex situ by collecting sediment cores after 2 months, 1 year, and 2 years of cap residence. Results and discussions: Capping in HS1, HS2, and HS3 reduced > 90% of the THg sediment after 2 months and > 83% of the MeHg after 1 year. HS4 reported a relatively low reduction (56% for THg and 83% for MeHg). In pore water, after 2 months, HS1, HS3, and HS4 led to higher reductions (93–95% for THg and 34–41% for MeHg) than HS2 (77% for THg and 20% for MeHg). The capping effectiveness declined after 1 year and 2 years, presumably because of the redistribution of contaminated sediments onto the small capped demonstration area. Despite reduced effectiveness over time, the capped sites reported lower concentrations of THg and MeHg compared to the uncapped site, which may be attributed to the combined effects of the treatment and natural attenuation. Conclusions: Overall, the results imply that AC and zeolite as active sorbents and sand as passive caps can be potential mercury remediation options for contaminated sediments. [ABSTRACT FROM AUTHOR]

The potential of diffusive gradient in thin film (DGT) as a long-term monitoring tool to assess trace level mercury (Hg) in surface waters was evaluated. A piston type DGT sampler and a plate-type device that could hold 15 DGTs were designed. The device contained piston type DGT samplers with varying diffusive gel thicknesses, that is, 0.5, 0.75, and 1.0 mm, respectively. Three DGT devices were deployed in a lake for 5 weeks, and two were deployed in a stream for 3 weeks. In the lake, the total Hg (THg) mass accumulated in the DGT varied between 0.05 and 0.15 ng, which increased with an increase in deployment time and decreased with an increase in agarose diffusion gel thickness. The DGT concentration in the lake water for a 2 week period was estimated to be about 0.8–1.0 ng/L, which was close to the measured value of 1.1 (± 0.13) ng/L, using the grab sampling technique. However, the DGT estimated at 4 and 6 weeks showed a concentration of about 0.5–0.7 ng/L, which is about twice as small as that measured by grab sampling. This underestimation of the THg levels in water appear to be caused by additional thicknesses of the physical diffusive boundary layer (0.15, 0.5, 1.29 mm) and biofilm, outside the DGT filter. The predicted DGT concentration in the upper stream of the Nakdong River was estimated to be about 0.8–1.4 ng/L, which is similar to the value of 1.22 (± 0.29) ng/L measured in the field by grab sampling. The concentration of THg was estimated to be about 1.0–1.2 ng/L, which is similar to the values measured by grab sampling. The additional diffusion thickness formed outside the DGT filter was 0.018 mm and 0.093 mm at 1 and 3 weeks, respectively, which is not larger than the diffusion gel thickness (0.5–1.0 mm). This was because DGT was installed in a region where the flow velocity is high, and the thickness of the diffusion boundary layer outside the filter is negligible. [ABSTRACT FROM AUTHOR]

Heavy metal contamination in aquatic systems is a big problem in many areas around the world. In 2016, high mercury concentrations were reported in bivalves (Corbicula leana) and sediments near the confluence of the Hyeongsan River and Chilseong Creek located in Pohang, a steel industrial city in the south-east coast of the Korean peninsula. Given that both the Chilseong and Gumu creeks run through the Pohang industrial complex and ultimately flow to the Hyeongsan River, it is imperative to determine if the industrial effluents have any impact on the mercury contamination in these two streams and the Hyeongsan River. In this work, we investigated the concentration levels of different heavy metals using cold vapor atomic fluorescence spectroscopy and inductively coupled plasma-mass spectroscopy. The metal concentration in the water samples from the Hyeongsan River, Gumu Creek, and Chilseong Creek did not exceed the limits for drinking water quality set by the US EPA and World Health Organization. However, the sediment samples were found to be heavily contaminated by Hg with levels exceeding the toxic effect threshold. Gumu Creek was found to be heavily contaminated. The concentrations of the different heavy metals increased downstream, and the samples collected from the sites in the Hyeongsan River near the Gumu Creek, an open channel for wastewater discharge of companies in the Pohang Industrial Complex, showed higher contamination levels, indicating that the effluents from the industrial complex are a possible source of contamination in the river. [ABSTRACT FROM AUTHOR]