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Artificial photosynthesis in carbon dioxide (CO2) conversion into value-added chemicals attracts considerable attention but suffers from the low activity induced by sluggish separation of photogenerated carriers and the kinetic bottleneck-induced unsatisfied selectivity. Herein, we prepare a new-style Bi/TiO2 catalyst formed by pinning bismuth clusters on TiO2 nanowires through being confined by pores, which exhibits high activity and selectivity towards photocatalytic production of CH4 from CO2. Boosted charge transfer from TiO2 through Bi to the reactants is revealed via in situ X-ray photon spectroscopy and time-resolved photoluminescence (PL). Further, in situ Fourier transform infrared results confirm that Bi/TiO2 not only overcomes the multi-electron kinetics challenge of CO2 to CH4 via boosting charge transfer, but also facilitates proton production and transfer as well as the intermediates ⋆CHO and ⋆CH3O generation, ultimately achieving the tandem catalysis towards methanation. Theoretical calculation also underlies that the more favorable reaction step from ⋆CO to ⋆CHO on Bi/TiO2 results in CH4 production with higher selectivity. Our work brings new insights into rational design of photocatalysts with high performance and the formation mechanism of CO2 to CH4 for solar energy storage in future. [ABSTRACT FROM AUTHOR]

Most reported risk factors for developmental speech delay (DSD) remain controversial, and studies on paternal influencing factors are rare. This study investigated family environmental risk factors for DSD in northern China. The medical records of 276 patients diagnosed with DSD at four centres between October 2018 and October 2019 were retrospectively analysed. A questionnaire was designed that contained items such as maternal age at the child's birth, child sex, child age, birth order, family type and parental personality. Patients whose medical records lacked complete information for this investigation were contacted by e-mail or phone. Additionally, 339 families whose children received routine physical examinations at the four involved centres completed the survey. Data were collected, and potential risk factors were analysed using the t test or chi-square test; the obtained outcomes were subjected to multivariable logistic regression for further analysis. The multivariable regression showed that older maternal age at the child's birth (OR = 1.312 (1.192–1.444), P < 0.001), introverted paternal personality (OR = 0.023 (0.011–0.048), P < 0.001), low average parental education level (OR = 2.771 (1.226–6.263), P = 0.014), low monthly family income (OR = 4.447 (1.934–10.222), P < 0.001), and rare parent–child communication (OR = 6.445 (3.441–12.072), P < 0.001) were independent risk factors for DSD in children in North China. The study results may provide useful data for broadening and deepening the understanding of family risk factors for DSD. [ABSTRACT FROM AUTHOR]

Visible light-responsive ZnFeO photocatalyst with a spinel structure was synthesized via a sol-gel method. The visible light photocatalysis of ZnFeO was investigated by decomposing Rhodamine B (RhB) solution. Under ∼30 min of visible light irradiation, the decomposition ratio of RhB is up to ∼97.4%. The excellent photocatalytic performance of ZnFeO photocatalyst is attributed to the high effective oxidation-reduction reaction caused by light irradiation excitation. With the increase of decomposition time, the wavelength of the maximum absorption peak of RhB solutions shifts from 557 nm to 498 nm ('blue shift'), which is because of the N-deethylation and cleavage of the conjugated chromophore structure of RhB. ZnFeO photocatalyst also exhibits a weak ferromagnetism performance. The decomposition ratio of RhB for the magnetically recycled ZnFeO is ∼94.6%. Strong visible light photocatalysis and convenience of magnetic recycling make ZnFeO promising for photocatalytic applications in dye wastewater treatment. [ABSTRACT FROM AUTHOR]