1. Thermally stable double perovskite Ca2YTaO6: Tb3+, Eu3+ phosphor for warm white LEDs.
- Author
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Lü, Jian-tao, Mai, Jun-xian, Fan, Ting, and Liang, Jie
- Abstract
A series of single-phase double perovskite Ca
2 YTaO6 : Tb3+ , Eu3+ phosphors were successfully synthesized by means of a high-temperature solid-state method. The crystal structure, luminescence spectrum, decay lifetime, thermal stability and energy transfer properties were investigated in detail. Under the excitation of 250 nm, Ca2 YTaO6 : Tb3+ , Eu3+ had notable green and red light emissions at 551 nm and 618 nm, respectively. The optimal doping concentration of Tb3+ was 16 mol%. Owing to the energy transfer effect between Tb3+ and Eu3+ , a tuneable luminescence from green to yellow was realized with the increase in Eu3+ doping concentration. When the temperature of the phosphor was increased from 300 to 500 K, the emission intensity remained 75% of that at room temperature. The Ca2 Y0.82 TaO6 : 0.16Tb3+ , 0.02Eu3+ phosphor was encapsulated with a 365 nm chip, and a warm white LED with CIE colour coordinates (0.365, 0.371) and low colour temperature (CCT < 5000 K) was successfully prepared. [ABSTRACT FROM AUTHOR]- Published
- 2024
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