1. Effects of substituents of imidazolium cations on the performance of dye-sensitized TiO2 solar cells.
- Author
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Kyung Mo Son, Man Gu Kang, Vittal, R., Lee, Jiwon, and Kang-Jin Kim
- Subjects
ELECTROCHEMICAL research ,ELECTROCHEMICAL analysis ,VOLTAMMETRY ,DYE-sensitized solar cells ,SOLAR cells ,PHOTOVOLTAIC cells ,SOLAR energy ,CATIONS ,IODIDES ,IMPEDANCE spectroscopy - Abstract
Imidazolium iodides (Im
+ I− s) were synthesized with different substituents of the cation and used as electrolytes in dye-sensitized solar cells (DSSCs), and the effects of such substituents were investigated in terms of the photovoltaic performance of the cells. Synthesized iodides were verified by1 H-NMR. Among the iodides, 1,3-diethylimidazolium iodide enabled a solar energy conversion efficiency of 4.8% for its DSSC, while 1-(4-acetophenyl)-3-ethylimidazolium iodide rendered an efficiency of 3.1% for its cell. In all cases the short-circuit photocurrent ( Jsc ) was found to increase with decrease in size of the substituent, which was also verified to be valid in the case of a quasi-solid state DSSC. Results are explained by the electrostatic interactions between solvated Im+ and negatively charged species based on the correlation between diffusion coefficients of I− and I and Jsc values. These explanations are supported by steady-state voltammetry and electrochemical impedance spectroscopy (EIS). [ABSTRACT FROM AUTHOR]- Published
- 2008
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