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The gradual depletion of fossil fuel reserves and the sharp rise in the cost of fossil fuels have generated a frenzy of activities in the quest to search for renewable source-based alternatives. Epoxides are an intermediate product that can be converted into value-added polymers. In the industry, epoxidation of vegetable oils is most frequently carried out with performic and peracetic acids. The aim of this study is to investigate the influence of the type of oxygen carrier (formic acid, acetic acid, and hybrid solution of formic and acetic acid) on the epoxidation of palm oleic acid. The peracids were formed in situ in this study. Based on the results, the highest relative conversion to oxirane (RCO) is achieved using formic acid, with a value of 82% at a reaction time of 25 min. Interestingly, a high RCO (82%) can also be achieved by using a hybrid solution of formic and acetic acid at a molar ratio of 1:1. The use of a hybrid oxygen carrier solution can help minimize the use of formic acid, which would create a strong acidic environment. In addition, the kinetic model is capable of predicting the reaction kinetics of the epoxidation process since the simulation results show good agreement with the experimental data, particularly for a formic acid/acetic acid molar ratio of 0.5:1.0. [ABSTRACT FROM AUTHOR]

This study represents an experimental investigation, complemented with a mathematical model, to decipher the effect of gravity on the spreading dynamics of a water droplet. For the theoretical discussion, an overall energy balance approach is adopted to explain the droplet spreading under both microgravity (μg) and terrestrial gravity condition. Besides explaining the mechanism of the droplet spreading under microgravity condition achieved during the parabolic flight, a technique with a detailed experimental set-up has also been developed for the successful deposition of droplet. A rational understanding is formulated through experimental investigation and theoretical analysis, which allows us to distinguish the transient variation of the spreading of a droplet, between microgravity and terrestrial gravity condition. The spreading of the droplet is predicted by the non-linear overall energy balance equation, which accounts for the operating parameters in the form of non-dimensional groups like Reynolds number (Re ), Weber number (We) and Bond number (Bo). To distinctly identify the difference in the drop spreading at terrestrial and microgravity conditions, the Bo with transient gravitational field obtained through the on-board accelerometer is considered. The obtained theoretical results are further corroborated by experimental results which are obtained from the parabolic flight. [ABSTRACT FROM AUTHOR]

The coral health of Pulau Anak Datai (PAD), located off the northwest of Langkawi, Malaysia, was assessed using the Coral Health Index (CHI) method. Three ecological parameters, namely, benthic cover, fish biomass, and microbes (Vibrio) were determined at four sites around the island in 2019. In addition, community parameters such as coral mortality index, coral richness, relative abundance, diversity index, Evenness tests, and reef morphology were measured for each site. The results revealed that the benthic cover consists of less than 40% of scleractinian corals at all sites. A total of 25 genera of hard corals comprising of 11 families and 1 scleractinian Incertae sedis were observed, with the most dominant corals belong to the genera Porites, Favites, and Diploastrea. The average fish biomass of PAD was low (16.76 g/m2), with only 19 non-cryptic fish species observed. The abundance of Vibrio around the island was within the average range of 29.58 cfu/ml. Based on the benthos, fish, and Vibrio values, the Coral Health Index (CHI) of PAD was classified on the low side of the fair status. All sites tended toward high values of the mortality index (MI > 0.33). Reef morphology was strongly influenced by stress-tolerant corals, dominated by massive and sub-massive corals. The data presented here suggested that the reefs of PAD could be rated as stressed and becoming unhealthy and disturbed. However, in view of the rarity of coral reef ecosystems in the Straits of Malacca, this island deserves increased attention for conservation planning and coral reef protection. [ABSTRACT FROM AUTHOR]

Pulau Tioman is a famous tourist island off Peninsular Malaysia with beautiful coral reefs. This study aims to assess the health of the coral reefs surrounding Pulau Tioman based on the application of the Foraminifera in Reef Assessment and Monitoring Index (FI). Ten sampling sites around Pulau Tioman were studied with a total of 30 samples. Eight orders, 41 families, 80 genera, and 161 species of benthic foraminifera were identified. The agglutinated type of foraminifera constituted 2–8% of the total assemblages. Calcareous hyaline and porcelaneous groups represented 79% and 19% of the total assemblages, respectively. Symbiont-bearing taxa were the most common foraminifera. The results indicate that most of the sampling sites are conducive for coral reef growth with good recoverability from future stress to the ecosystem. However, several areas with higher coastal development and tourism have reduced water and sediment quality. Therefore, the limit on the number of visitors and tourists should be revised to enable coral growth and health. The FI values in this study showed a positive correlation with good water qualities and a negative correlation with organic matter enrichment. The FI is a good measure to assess the health of a coral reef and can be applied to other reef ecosystems around Malaysia. [ABSTRACT FROM AUTHOR]

Excessive heat from microelectronic components is essential to remove to increase the reliability of the system. In this paper, various types of perforations in the form of small channels such as square, circular, triangular and hexagonal cross sections are introduced and thermal performances are compared to improve the cooling performance of heat sink. The governing equations are solved by adopting a control volume based finite element method with an unstructured non-uniform grid system. Flow and heat transfer characteristics are presented for Reynolds numbers from 2 × 10 to 4 × 10 based on the fin length and Prandtl number is taken as Pr = 0.71. RANS based k-ε turbulence model is used to predict the turbulent flow parameters. The predicted results are validated by the previously published experimental data and in reasonable agreement with the experiment. Results show that fins having circular perforations have better thermal and fluid dynamic performances than the other types of fins considered here. [ABSTRACT FROM AUTHOR]

Material selection is an onerous process of design activities which needs to be carefully carried out in order to increase the probability of success. A lot of multi-criteria decision-making methods have been proposed in material selection, many of which require quantitative weights for the attributes. Since weights play a very significant role in the ranking results of the materials, this paper presents a framework for determining importance degree of criteria to overcome the shortcomings of this subject in material selection. Furthermore, the suggested framework covers the situation of interdependent relationship between the criteria which has not been surveyed in material selection yet. An example was considered to illustrate how this framework is conducted. On the basis of the numerical results, it can be concluded that the proposed method can soundly deal with the material selection problems. [ABSTRACT FROM AUTHOR]

The concern over ensuing freshwater scarcity has forced the developing countries to delve for alternative water resources. In this study, we examined the potential of stagnant surface water bodies (SSWBs) as alternative freshwater resources in the densely populated Chittagong metropolitan area (CMPA) of Bangladesh-where there is an acute shortage of urban freshwater supply. Water samples were collected at 1-month intervals for a period of 1 year from 12 stations distributed over the whole metropolis. Samples were analyzed for pH, water temperature (WTemp), turbidity, electrical conductivity (EC), total dissolved solids, total solids, total hardness, dissolved oxygen (DO), chloride, orthophosphates, ammonia, total coliforms (TC), and trace metal (Cd, Cr, Cu, Pb, As, and Fe) concentrations. Based on these parameters, different types of water quality indices (WQIs) were deduced. WQIs showed most of CMPA-SSWBs as good or medium quality water bodies, while none were categorized as bad. Moreover, it was observed that the minimal water quality index (WQI), computed using five parameters: WTemp, pH, DO, EC, and turbidity, gave a reliable estimate of water quality. The WQI gave similar results in 72% of the cases compared with other WQIs that were based on larger set of parameters. Based on our finding, we suggest the wider use WQI in developing countries for assessing health of SSWBs, as it will minimize the analytical cost to overcome the budget constraints involved in this kind of evaluations. It was observed that except turbidity and TC content, all other quality parameters fluctuated within the limit of the World Health Organization suggested standards for drinking water. From our findings, we concluded that if the turbidity and TC content of water from SSWBs in CMPA are taken care of, they will become good candidates as alternative water resources all round the year. [ABSTRACT FROM AUTHOR]