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Sulfate radical (SO4•−)–based advanced oxidation processes (AOPs) from sulfite activation have recently received attention for abatement of microorganic pollutants in the aquatic environments. Trace-level Co(II) has been demonstrated to be effective for promoting sulfite activation (simplified as the Co(II)/sulfite system) and the corresponding radical formation, yet this process is challenged by the limited valence inter-transformation of Co(II)/Co(III). In order to enhance this valence inter-transformation, a novel Co(II)/HPO42−/sulfite system is developed in this work, because HPO42−, as a typical radical scavenging agent, has the advantage of complexing with Co(II) without quenching effect. In this work, complexation of Co(II) with HPO42− can regulate the electronic structure of Co(II), accelerate electron transfer, and promote valence inter-transformation of Co(II)/Co(III) during the sulfite activation process. The Co(II)/HPO42−/sulfite system exhibits superior iohexol abatement performance under circumneutral conditions. For pH 8.0 and Co(II) dose of 1 μM, the iohexol abatement efficiency is as high as 98%, which is considerably higher than that of the Co(II)/sulfite system (50%). SO4•− is identified as the predominant reactive radical contributing to iohexol abatement. The presence of HPO42− broadens the pH adaptability of the Co(II)/sulfite system for iohexol abatement. In addition, the coexisting Cl− exerts an inhibitory effect on iohexol abatement while the other cations and anions show negligible effect. The Co(II)/HPO42−/sulfite system displays good reusability and adaptability towards various organic pollutants. This study highlights the important role of complexation of Co(II) with HPO42− in sulfite activation and provides a feasible idea for abatement of the microorganic pollutants. [ABSTRACT FROM AUTHOR]