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The study of the fluid inclusions of W–Mo deposits in the mineralization area of Ningshan–Zhen'an , Shaanxi Province, China shows that the gas–liquid two-phase inclusions are mainly present in W–Mo deposits, and the ore-forming fluid can be divided into four types: high-temperature type, middle–high-temperature type, middle-temperature type and low-temperature type. The formation depths of the W–Mo mineralization range from 4.2 to 8.4 km. The boiling and mixing of fluid may have been important mechanisms for the formation of W–Mo mineralization. The skarn-type mineralization is dominated by magmatic water, the quartz-vein-type mineralization includes both magmatic water and meteoric water, and the meteoric water is more involved in the quartz-fluorite-vein-type, beryl-quartz-vein-type and pegmatite-type mineralization. Magma is the main source of sulfur; that is, magma is the main source of mineralization. Combined with the metallogenic setting and geological characteristics of typical ore deposits, in the process of structural system transformation in South Qinling, the ore-forming magma fluid in the Late Indosinian–Yanshanian period was uplifted and emplaced along the NW–WNW direction and NE–NNE direction, and eventually, NW–WNW fault-controlled skarn-type W–Mo mineralization and quartz-vein-type W–Mo deposits accompanied by greisenization, albitization and potash feldspathization formed. [ABSTRACT FROM AUTHOR]

The Chayong Cu-polymetallic deposit is a recently discovered Cu-polymetallic deposit hosted in the Sanjiang Metallogenic Belt within the Tibetan Plateau of China to the northeast of the North Qiangtang terrane. The ore body occurs in siltstone and is controlled by a northwest-trending fault structure. According to the associations, assemblages, and cutting relationships between ore veins, the hydrothermal mineralization period can be divided into three mineralization stages: (1) a molybdenite mineralization stage, (2) a Cu-polymetallic sulfide stage, and (3) a quartz-carbonate stage. Two types of fluid inclusions (FIs), namely, liquid and vapor-rich inclusions, are present in quartz associated with sulfide minerals. Early-stage FIs are both liquid and vapor-rich, homogenized at temperatures ranging from 364.1 to 384.2 °C, and have salinities ranging from 0.70% to 9.60% NaCl equivalent (eqv). The middle-stage FIs are also both liquid- and vapor-rich, homogenized at temperatures ranging from 272.4 to 355.6 °C, and have salinities ranging from 0.53%–17.10% NaCl eqv. The late-stage FIs are liquid, homogenized at temperatures ranging from 209.4 to 255.3 °C, and have salinities ranging from 0.35%–6.87% NaCl eqv. The samples from the deposit have δ34S values of − 21.8‰ to − 19.2‰ and − 5.5‰ to − 6.0‰, suggesting that sulfur was derived from the host sediments and magmatic fluids, respectively. The metallic minerals within the deposit have 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb values of 18.439–18.458, 15.656–15.679, and 38.772–38.863, respectively, suggesting that the metals were derived from the upper crust and orogenic belts. The samples from the deposit have δ18OW values of 2.99‰–7.99‰ and δDW values ranging from − 84.4‰ to − 73.9‰, indicating that the ore-forming fluids were magmatic and mixed with minor amounts of meteoric water. The ore-forming fluid of the Chayong copper polymetallic deposit was a high-temperature, medium- to low-salinity H2O–NaCl–CH4–N2 ± CO2 fluid system. The early high-temperature magmatic fluid, due to boiling, decreased in temperature, and via the mixing of meteoric water, gradually evolved towards the later-stage medium- to low-temperature and low-salinity fluid, causing molybdenite mineralization and forming copper polymetallic sulfide veins and quartz carbonate veins. [ABSTRACT FROM AUTHOR]

We studied the fluid inclusions of the Jiguanshan Mo deposit in China, which is a large porphyry deposit located in the southern Xilamulun Metallogenic Belt. The irregular Mo ore body with various types of hydrothermal veinlets is hosted by Late Jurassic granite porphyry. Intense hydrothermal alterations in the deposit from the core to margin are silicification–potassium feldspar alteration, pyrite–quartz–sericite–fluorite alteration, and propylitic alteration. Based on the mineral assemblages and crosscutting relationships of ore veins, the ore-forming process were divided into three stages and two substages: quartz–pyrite veins (stage I) associated with potassic alteration; quartz–molybdenite–chalcopyrite–pyrite veins (substage II-1) and quartz–molybdenite–fluorite veins (substage II-2) associated with phyllic alteration; and fluorite–quartz–carbonate veins (stage III) with carbonation. Five major fluid inclusions (FIs) types were distinguished in the quartz associated with oxide and sulfide minerals, i.e. polyphase brine (Pb-type), opaque-bearing brine (Ob-type), solid halite (S-type), two-phase aqueous (A-type), and vapor (V-type) inclusions. The FIs of stage I were composed of liquid-rich S-, A-, and V-type FIs with homogenization temperatures and salinities of 490 to 511 °C and 8.9 to 56.0 wt% NaCl equiv., respectively. The FIs of substage II-1 are composed of Pb-, Ob-, S-, A-, and V-type FIs with homogenization temperatures and salinities of 352 to 460 °C and 3.7 to 46.1 wt% NaCl equiv, respectively. The FIs of substage II-2 are Ob-, S-, A-, and V-type FIs with homogenization temperatures and salinities of 234 to 309 °C and 3.7 to 39.2 wt% NaCl equiv, respectively. The FIs of stage III are A-type FIs with homogenization temperatures and salinities of 136 to 172 °C and 1.1 to 8.9 wt% NaCl equiv, respectively. Fluid boiling, which resulted in the precipitation of sulfides, occurred in stages I and II. The initial ore-forming fluids of the Jiguanshan deposit had high temperature, high salinity, and belonged to an F-rich NaCl ± KCl–H2O system. The fluids gradually evolved to low temperature, low salinity, and belonged to a NaCl–H2O system. Studies of the hydrogen and oxygen isotope compositions of quartz (δ18OH2O = − 7.3 to 6.3‰, δDH2O = − 104.3 to − 83.3‰) show that the ore-forming fluids gradually evolved from magmatic water to meteoric water. [ABSTRACT FROM AUTHOR]