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1. Stannoxanes and phosphonates: New approaches in organometallic and transition metal assemblies.

Author

Chandrasekhar, Vadapalli, Gopal, Kandasamy, Nagarajan, Loganathan, Sasikumar, Palani, and Thilagar, Pakkirisamy

Subjects
*LIGANDS (Chemistry), *PHOSPHONATES, *TRANSITION metals, *TRANSITION metal complexes, *ORGANOTIN compounds, *FERROCENE, *PORPHYRINS, *PYRAZOLES
Abstract

Phosphonate ligands, [RPO3]2-, are extremely versatile in the assembly of multi-tin and multi-copper architectures. We have used organostannoxane cores for supporting multi-ferrocene and multi-porphyrin peripheries. The copper-metalated multi-porphyrin compound is an excellent reagent for facile cleavage of DNA, even in the absence of a co-oxidant. Reaction of t-BuPO3H2 with Cu(ClO4)2. 6H2O in the presence of 2-pyridylpyrazole (2-Pypz) leads to the synthesis of a decanuclear copper (II) assembly. [ABSTRACT FROM AUTHOR]

Published
2006
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