1. Laboratory, ground-based, and airborne tunable diode laser systems: performance characteristics and applications in atmospheric studies.
- Author
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Fried, A., Henry, B., Wert, B., Sewell, S., and Drummond, J.R.
- Subjects
ABSORPTION spectra ,DIODES ,TUNABLE lasers ,FORMALDEHYDE ,SPECTRUM analysis - Abstract
Abstract. Tunable diode laser absorption spectroscopy has been employed by our group at the National Center tot Atmospheric Research to study a number of important trace atmospheric gases and processes over the past 10 years. This paper presents an overview of these studies along with details on instrument hardware and software features implemented for high sensitivity. The merits of four different approaches in assessing instrument performance are presented with formaldehyde (CH[sub 2]O) used as the target gas. One method utilizes the Allan variance. When our present aircraft system is operated in the laboratory, the Allan variance indicates a CH[sub 2]O detection limit of 0.031 ppbv for integration times of 25 s. This sensitivity corresponds to a minimum detectable absorbance of 1.0 x 10[sup -6], and this is within a factor of two of that reported by Werle et al. who used high-frequency modulation spectroscopy. The present instrument utilizes conventional low-frequency (2f = 100 kHz) wavelength modulation. Instrument performance, obtained from replicate measurements of CH[sub 2]O standards acquired over time periods as long as 1.5 hours, on average resulted in a factor of two poorer precision than indicated by the Allan variance. Since replicate measurements precisely simulate the acquisition procedures... [ABSTRACT FROM AUTHOR]
- Published
- 1998
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