1. Higher stability and better photoluminescence quantum yield of cesium lead iodide perovskites nanoparticles in the presence of CTAB ligand.
- Author
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Al-Tawil, Christina, El Kurdi, Riham, and Patra, Digambara
- Subjects
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LEAD iodide , *PEROVSKITE , *CESIUM iodide , *PHOTOLUMINESCENCE , *CHEMICAL decomposition , *LEAD halides , *SILICA nanoparticles - Abstract
Inorganic halide perovskites, such as CsPbI3, have unique optoelectronic properties which made them promising candidates for several applications. Unfortunately, these perovskites undergo rapid chemical decomposition and transformation into yellow δ-phase. Thus, the synthesis of stable cesium lead iodide perovskites remains an actual challenging field and it is imperative to develop a stabilized black phase for photovoltaic applications. For this purpose, a surfactant ligand was used to control the synthesis of inorganic perovskite CsPbI3 nanoparticles. Herein we demonstrate a new avenue for lead halide perovskites with the addition of either hexadecyltrimethylammonium bromide (CTAB) or silica nanoparticles to maintain in the first place; the stability of the α-CsPbI3 phase, and later on to boost their photoluminescence quantum yield (PLQY). The prepared perovskites were characterized using UV–visible absorption spectroscopy, fluorescence spectroscopy, scanning electron microscopy, thermogravimetric analysis and X-Ray diffraction technique. Results show higher stability of α-CsPbI3 phase and improvement in PLQY % to reach 99% enhancement in presence of CTAB. Moreover, the photoluminescence intensity of CsPbI3 nanoparticles was higher and was maintained for a longer duration in the presence of CTAB. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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