Bian, Xilei, Şopu, Daniel, Wang, Gang, Sun, Baoan, Bednarčik, Jozef, Gammer, Christoph, Zhai, Qijie, and Eckert, Jürgen
The design of ductile heterogeneous metallic glasses (MGs) with enhanced deformability by purposely controlling the shear-band dynamics via modulation of the atomic-scale structures and local stress states remains a significant challenge. Here, we correlate the changes in the local atomic structure when cooling to cryogenic temperature with the observed improved shear stability. The enhanced atomic-level structural and elastic heterogeneities related to the nonaffine thermal contraction of the short-range order (SRO) and medium-range order (MRO) change the characteristics of the activation process of the shear transformation zones (STZs). The experimental observations corroborated by Eshelby inclusion analysis and molecular dynamics simulations disclose the correlation between the structural fluctuations and the change in the stress field around the STZ. The variations in the inclination axes of the STZs alter their percolation mechanism, affect the shear-band dynamics and kinetics, and consequently delay shear failure. These results expand the understanding of the correlation between the atomic-level structure and elementary plastic events in monolithic MGs and thereby pave the way for the design of new ductile metallic alloys. Metallic glasses: seeing the effects of stress Recent insights into the atomic-scale mechanisms underlying the structural failure of glass-like metals provide strategies for the development of novel materials. Metallic glasses have a disordered atomic structure, unlike the crystalline arrangement of conventional metals. They therefore offer greater flexibility in terms of the shapes they can form. However, so-called shear bands that form when the metallic glass is deformed under stress weaken it, leading to structural failure. G.W. from Shanghai University, China, D.Ş. from the Erich Schmid Institute of Materials Science in Leoben, Austria, and co-workers used X-ray diffraction to track changes in atomic structure as they cooled a metallic glass to very low temperatures and correlated these changes with local variations in stress. Understanding this correlation will help design metallic glasses with an improved ability to be deformed without structural failure. Understanding the correlation between atomic-scale structural/elastic fluctuations and local plastic rearrangements (shear transformation zone (STZ)) is essential to the widespread use of metallic glasses (MGs). We report a strategy to control the local stress state and enhance the shear stability of MGs. The enhanced degree of structural/elastic heterogeneities relates to the increased nonaffine thermal strain of the short- and medium-range order. We demonstrate that variations in the stress field around STZ affect their dynamics and percolation process, the progressive formation of shear bands, and, consequently, the macroscopic deformability of MGs. This work paves a new way for designing ductile MGs. [ABSTRACT FROM AUTHOR]