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The main objective of this work was to determine the soil contamination with trace metals within and around the dumpsite of Safi city (Morocco) and to evaluate the potential environmental risk associated. The results showed that the average soil concentrations of trace metals had the following order: Fe > Zn > Cu > Cr > Cd and exceeded the world and the upper continental background concentrations except for Fe. In addition, the concentrations of Zn, Cu, and Cd remained beyond the limit standards given by the WHO/FAO. Geoaccumulation index, enrichment factor, and pollution load index (PLI) indicated that the dumpsite soil is highly contaminated and deteriorated, presenting evidence of high ecological risk proved by the values of the potential ecological risk index (PERI). Correlation analyses revealed a strong relationship between the organic matter & [Fe, Zn, Cr, Cd], calcium carbonates & [Zn, Cr], and Cr & Cu inside the dumpsite soil. Principal component analysis confirmed the temporal and spatial classification of Zone A as the oldest and Zone C as the youngest and indicated that the regrouped trace metals could have the same behavior and or the same origin. The interpolation of trace metals concentrations and PERI revealed a plausible extension outside the landfill, confirmed by PLI values., (© 2023. The Author(s), under exclusive licence to Springer Nature Switzerland AG.)

Municipal solid waste disposed of in illegal dumpsites pollutes the surface and groundwater. However, accurately determining these pollution levels is typically challenging for practitioners and decision-makers in developing countries. The purpose of this study is to use the leachate pollution index (LPI) to assess the contamination potential of uncontrolled dumping sites along the course of the Kulfo River in Arba Minch, Ethiopia. The comprehensive pollution index (CPI) approach was also utilized to assess the suitability of Kulfo River water quality for aquatic species. Leachate samples were collected from four uncontrolled dumping sites along the Kulfo River's course and analyzed for fifteen leachate characteristics necessary to quantify the LPI sub-indices. Water samples were taken from three monitoring stations along the river and examined for aquatic species suitability. When the leachate parameters were compared to the Indian limit for discharge of treated leachate, it was found that dumping sites posed a considerable risk of pollution to adjacent water resources. The overall LPI ranged from 23.34 to 27.35, which is higher than the discharge standard LPI of 5.69, indicating that dumping sites can threaten the surrounding water resources and human health. Based on the rating scale of CPI, at all monitoring stations, the river resulted severely polluted. Finally, appropriate strategies to reduce the pollution and the related mismanagement of solid waste were discussed. Combining LPI and CPI methods can represent a crucial tool for experts and decision-makers in developing countries to evaluate the pollution potential of dumping sites and water resource monitoring., (© 2022. The Author(s), under exclusive licence to Springer Nature Switzerland AG.)

Waste electric and electronic equipment (WEEE) represents a potential secondary source of valuable materials, whose recovery is a growing business activity worldwide. In low-income countries, recycling is carried out under poorly controlled conditions resulting in severe environmental pollution. High concentrations of both metallic and organic pollutants have been confirmed in air, soil, water, and sediments in countries with informal recycling areas. The release of these contaminants into the environment presents a risk to the health of the exposed population that has been widely acknowledged but still needs to be quantified. The aim of this work was to evaluate the relative risk from inhalation associated with the open burning of different kinds of WEEE. The shrinking core model was applied to estimate the concentration of the metals which would be released into the environment during the incineration of different types of WEEE. In addition, the potential generation of dioxins during the same informal practice was estimated, based on the plastic content of the WEEE. The results provided for the first time a comparative analysis of the risk posed from the open burning of WEEE components, proposing a methodology to address the absolute risk assessment to workers from the informal recycling of WEEE.