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12 pags., 8 figs., 8 tabs.-- Section: Letters to the Editor, Observations of IRC +10216 with the Yebes 40 m telescope between 31 and 50 GHz have revealed more than 150 unidentified lines. Some of them can be grouped into a new series of 26 doublets, harmonically related with integer quantum numbers ranging from Jup = 54 to 80. The separation of the doublets increases systematically with J, that is to say, as expected for a linear species in one of its bending modes. The rotational parameters resulting from the fit to these data are B = 290.8844 ± 0.0004 MHz, D = 0.88 ± 0.04 Hz, and q = 0.1463 ± 0.0001 MHz. The rotational constant is very close to that of the ground state of HC9N. Our ab initio calculations show an excellent agreement between these parameters and those predicted for the lowest energy vibrationally excited state, ν19 = 1, of HC9N. This is the first detection, and complete characterization in space, of vibrationally excited HC9N. An energy of 41.5 cm-1 is estimated for the ν19 state. In addition, 17 doublets of HC7N in the ν15 = 1 state, for which laboratory spectroscopy is available, were detected for the first time in IRC +10216. Several doublets of HC5N in its ν11 = 1 state were also observed. The column density ratio between the ground and the lowest excited vibrational states are ≈127, 9.5, and 1.5 for HC5N, HC7N, and HC9N, respectively. We find that these lowest-lying vibrational states are most probably populated via infrared pumping to vibrationally excited states lying at ≈600 cm-1. The lowest vibrationally excited states thus need to be taken into account to precisely determine absolute abundances and abundance ratios for long carbon chains. The abundance ratios N(HC5N)/N(HC7N) and N(HC7N)/N(HC9N) are 2.4 and 7.7, respectively., he Spanish authors thank Ministerio de Ciencia e Innovación for funding support through project AYA2016-75066-C2-1-P. We also thank ERC for funding through grant ERC-2013-Syg-610256-NANOCOSMOS. MA thanks Ministerio de Ciencia e Innovación for Ramón y Cajal grant RyC2014-16277. CB thanks Ministerio de Ciencia e Innovación for Juan de la Cierva grant FJCI-2016-27983. LVP acknowledges support from the Swedish Research Council and from the ERC through the consolidator

5 pags., 3 figs., 1 tab., We present new interferometer molecular observations of R Leo taken at 1.2 mm with the Atacama Large Millimeter Array with an angular resolution up to 0'. 026. These observations permitted us to resolve the innermost envelope of this star, which revealed a complex structure that involves extended continuum emission and molecular emission showing a non-radial gas velocity distribution. This molecular emission displays prominent red-shifted absorptions located immediately in front of the star, which are typical footprints of material infall. This emission also shows lateral gas motions compatible with a torus-like structure., We thank the European Research Council (ERC Grant 610256: NANOCOSMOS) and the Spanish MINECO/MICINN for funding support through grant AYA2016-75066-C-1-P and the ASTROMOL Consolider project CSD2009-00038. MA acknowledges funding support from the Ramón y Cajal program of Spanish MINECO (RyC-2014-16277).

10 pags., 5 figs., 7 tabs., 5 apps., We report on the detection of two series of harmonically related doublets in IRC+10216. From the observed frequencies, the rotational constant of the first series is B = 1380.888 MHz and that of the second series is B = 1381.512 MHz. The two series correspond to two species with a 2Σ electronic ground state. After considering all possible candidates, and based on quantum chemical calculations, the first series is assigned to MgC3N and the second to MgC4H. For the latter species, optical spectroscopy measurements support its identification. Unlike diatomic metal-containing molecules, the line profiles of the two new molecules indicate that they are formed in the outer layers of the envelope, as occurs for MgNC and other polyatomic metal-cyanides. We also confirm the detection of MgCCH that was previously reported from the observation of two doublets. The relative abundance of MgC3N with respect to MgNC is close to one while that of MgC4H relative to MgCCH is about ten. The synthesis of these magnesium cyanides and acetylides in IRC+10216 can be explained in terms of a two-step process initiated by the radiative association of Mg+ with large cyanopolyynes and polyynes followed by the dissociative recombination of the ionic complexes., The Spanish authors thank the Ministerio de Ciencia Innovación y Universidades for funding support from the CONSOLIDER-Ingenio program “ASTROMOL” CSD 2009-00038, AYA2012-32032, AYA2016-75066-C2-1-P. We also thank ERC for funding through grant ERC-2013-Syg610256-NANOCOSMOS. MA thanks the Ministerio de Ciencia Innovación y Universidades for the Ramón y Cajal grant RyC-2014-16277. CB thanks the Ministerio de Ciencia Innovación y Universidades for the Juan de la Cierva grant FJCI-2016-27983. LVP acknowledges support from the Swedish Research Council and from ERC consolidator grant 614