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The effects of heat treatment on the hardness and electrochemical behavior of the Ti6Al4V alloy were studied. Two heat treatments were performed: one below (800 °C) and the other above (1050 °C) its beta transformation temperature (T= 980 ± 20 °C) and cooled using three conditions: water quenching, normalizing, and furnace. A microstructure observed using Optical Microscopy showed dependence on the heat treatment temperature applied; mainly three microstructures were obtained: martensitic, globular, and lamellar. Besides, alpha and beta phases were characterized by X-ray diffraction (XRD) technique. The Berkovich tests were performed to measure the hardness and reduced modulus (E). The Ti6Al4V alloy treated at 1050 °C and air-cooled exhibited hardness values closer to those of the Ti6Al4V as-received alloy. Electrochemical tests were carried out to analyze the electrochemical behavior after 7-day immersion in Hank’s solution at 37 °C and pH 7.40. Open Circuit Potentials (E) showed less negative values for Ti6Al4V and Ti6Al4V alloys, suggesting ennoblement of these materials. Furthermore, these alloys exhibited an outstanding electrochemical behavior compared to the Ti6Al4V as-received alloy by Electrochemical Impedance Spectroscopy (EIS) technique., The authors thank David Pérez-Risco for sharing his experience and useful advice on Berkovich Nano-indenter at the National Metallurgical Research Center (CENIM-CSIC Madrid, Spain), allowing this work to be carried out. Mercedes Paulina Chávez-Díaz thanks the National Science and Technology Council (CONACyT) for a doctoral fellowship to hold a research stay at CENIM-CSIC. This work was supported by the Government of Spain, through the Ministry of Economy and Competitiveness [MAT2015-67750-C3-1]. Elsa Miriam Arce-Estrada and Román Cabrera-Sierra wish to thank the National Research System (SNI) for the distinction of its members and the stipend received.

The directionality of the ductile-brittle transition behavior of two oxide-dispersion-strengthened (ODS) FeCrAl steels with similar chemical compositions, tensile properties, and sub-micrometric grain sizes but different processing routes, and a Zr-particle strengthened FeCrAl steel manufactured by high vacuum melting is discussed. Despite the similarities of the ODS FeCrAl steels, strong differences in the lower and upper shelf energy and the ductile to brittle transition temperature were observed for longitudinal through thickness notched specimens. Although the lower and upper shelf energies of longitudinal surface-notched specimens of ODS FeCrAl steels are similar, a strong difference in the ductile-to-brittle transition temperature is observed. For through-thickness notched and surface-notched specimens taken transversely, the analyzed ODS FeCrAl steels show a similar ductile-to-brittle behavior. In general, the FeCrAl alloy strengthened with Zr-particles presents a more isotropic behavior and a higher ductile-to-brittle transition temperature than the ODS FeCrAl steels. In addition, the upper shelf energy of the FeCrAl steel strengthened with Zr-particles is significantly higher than that of the ODS FeCrAl steels., The authors acknowledge financial support to Spanish Ministerio de Economia y Competitividad (MINECO) in the form of a Coordinate Project (MAT2016-80875-C3-1-R). The authors are grateful for the dilatometer tests by Phase Transformation laboratory. This work contributes to the Joint Programme on Nuclear Materials (JPNM) of the European Energy Research Alliance (EERA).

© 2015, The Minerals, Metals & Materials Society. Coarse-grained Fe-based oxide dispersion-strengthened (ODS) steels are a class of advanced materials for combined cycle gas turbine systems to deal with operating temperatures and pressures of around 1100°C and 15–30 bar in aggressive environments, which would increase biomass energy conversion efficiencies up to 45% and above. This two-part paper reports the possibility of the development of simultaneous corrosion barrier and optimized microstructure in a FeCrAl heat-resistant alloy for energy applications. The first part reports the mechanism of generating a dense, self-healing α-alumina layer by thermal oxidation, during a heat treatment that leads to a coarse-grained microstructure with a potential value for high-temperature creep resistance in a FeCrAl ODS ferritic alloy, which will be described in more detail in the second part., G. Pimentel acknowledges the Spanish Ministerio de Ciencia e Inovación for financial support in the form of PhD research grant (FPI). The authors acknowledge financial support to Ministerio de Economia (MINECO) and Fondo Europeo de Desarrollo Regional (FEDER) in the form of ENE2009-13766-C04-01 project and MAT2013-47460-C5-2-P project.

Mechanically alloyed iron-base oxide dispersion-strengthened (ODS) alloys are the class of advanced materials for application in heat exchangers tubing in which creep and oxidation resistance are paramount. The yttria dispersion in such alloys improves the high-temperature creep and stress rupture life. The strength is further enhanced by the development of a coarse-grained microstructure during recrystallization. Factors controlling the evolution of this desirable microstructure are explored in this work, focusing specifically on PM 2000. The results presented in terms of orientation imaging, transmission electron microscopy, and scanning electron microscopy indicate that the recrystallization process consists of two different stages. Before the coarse grain takes place, the alloy undergoes an extended recovery process followed by abnormal grain growth. The initial microstructure consisted of subgrains (submicrometer sizes) with a strong 〈110〉RD fiber texture (α fiber), which are transformed into coarse grains (mm sizes) with orientations 〈112〉RD. The aim of this study is to describe the mechanisms involved in the intermediate stages of recrystallization process from the submicrometer grain size to the abnormal grain size. © 2014 The Minerals, Metals & Materials Society.

Mechanically alloyed iron-based oxide dispersion-strengthened alloys have the potential for application in heat exchangers for biomass power plants, with operating temperature and pressure at entry of the gas turbine working fluid being around 1,100 °C and 15-30 bar, respectively. The yttria dispersion in such alloys improves the high-temperature creep and stress rupture life. The strength is further enhanced by the development of a coarse-grained microstructure during recrystallization. Factors controlling the evolution of this desirable microstructure are explored in this study, focusing specifically on PM 2000. The results can be interpreted if it is assumed that anything which makes the microstructure heterogeneous stimulates recrystallization. The combination of these results with finite element modelling is used to interpret the role of strain heterogeneity on the development of recrystallized grain structure. In this sense, larger strain gradients lead to more refined and more isotropic grain structures. © 2012 Springer Science+Business Media, LLC.

New carbide free bainitic microstructures are gaining an increasing interest on behalf the scientific and industrial community. The excellent combination of mechanical properties achieved in those microstructures with no need of complex heat treatments or thermomechanical processes represents their main advantage. The strength is mainly achieved by means of the very fine bainitic ferrite plates, consequence of the transformation mechanism, but the parameters contributing to the ductility of those microstructures are still unclear in this type of microstructures, where a soft phase, retained austenite, is imbibed in a very strong matrix of bainitic ferrite. A priori is reasonable to assume that retained austenite will control the levels of ductility achieved. Further enhancement of ductility can be achieved by the transformation of retained austenite into martensite (strain or stress assisted), thus its mechanical stability plays an important role in the final ductility. In this study, by means of X-ray analysis of interrupted compression tests, it is studied the influence that different microstructural aspects of retained austenite may have on its mechanical stability. © 2009 Springer Science+Business Media, LLC.

The Weibull statistic has been widely used to predict the inherent dispersion in fracture strenght of brittle materials,e.g. ceramics fibres. It has also been used to describe the scatteer of the tougheness of steels ata low temperature in the lower part of the transition range, where failure occurs by cleavage.