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The Miocene Climatic Optimum (MCO) represents a global warm period (approximately 17–14.7 Ma) interrupting a long-term period of Cenozoic cooling. To elucidate if bauxitization took place in southeastern European mid-latitude areas during the MCO, we studied a section of undated massive karst bauxite (Crveni Klanac, CK) in central Dalmatia, Croatia, hosted in Upper Cretaceous limestones and overlain by Miocene Sinj Basin lacustrine deposits. Integrated mineralogical, morphological and geochemical analyses indicate the predominant mineral phases of the homogenous bauxite matrix are authigenic, subhedral to euhedral kaolinite and gibbsite. The in-situ mineralization was a consequence of pedogenic processes, indicating the CK bauxites formed autochthonously. In situ U–Pb zircon ages of the lower, middle and upper parts of the CK bauxite are very similar, dominated by Miocene and Oligocene ages, indicating that they all share similar protolith(s). Subsequent high-precision chemical abrasion-isotope dilution-thermal ionization mass spectrometry (CA-ID-TIMS) analyses indicate a maximum depositional age (MDA) for the pre- bauxitic material of 16.9576 ± 0.021 Ma (2σ uncertainty, incorporating decay constant uncertainty). This MDA, a maximum age of autochthonous bauxitization, coincides with the onset of the MCO. Based on currently available geochronological constraints, the maximum timeframe for CK bauxitization was less than ~ 700 ka, which matches the records of the MCO in paleo- mid-latitude Europe. The potential imprint of pre- 17 Ma bauxitization and contribution of older (i.e., Upper Paleogene) bauxite deposits resedimented to the CK profile, as well as degree of potential parautochthonous origin of the CK bauxites, is yet to be investigated. More than simply aligning with regional and local reconstructions of continental climatic conditions during the onset and the early stages of the MCO, the high degree of autochthony of the CK bauxites provide a precise climatic constraint. For in-situ bauxitization to occur in the southeastern parts of mid-latitude continental Europe, paleoclimatic and paleoenvironmental conditions must have had mean annual temperature greater than 17–22 °C and mean annual precipitation of more than 1100–1200 mm.

We perform a multidisciplinary study of biotite porphyroblasts and veinlet infills hosted in Cambrian strata of the hanging walls from the NW-SE-trending Datos, Jarque and Daroca thrusts (Iberian Chains). Stratigraphic and microstructural crosscutting features indicate that a biotite isograd runs parallel to the southeastern transects of the three thrusts. The metamorphic grade reached in the southeastern edge of the Iberian Chains is clearly distinct from both the Cadomian epizonal metamorphism, exclusively recorded in the Ediacaran–basal Cambrian Paracuellos Group, and the Variscan anchizone metamorphism recorded throughout Cambrian–Devonian strata. During post–Variscan negative inversion tectonics, renewed K-metasomatism along the same thrusts led to crystallisation of geochemically similar biotites in parallel fissures and veins. 40Ar/39Ar ages are (i) latest Westphalian–to–Guadalupian (285.82 ± 23.75 Ma) for metamorphic biotite porphyroblasts affected by diffusion loss of Ar, including the Carboniferous–Permian transition within error; and (ii) Early Triassic (246.87 ± 5.36 Ma) for biotite occlusion in post–Variscan veinlets. The Iberian Chains represent the southeastern prolongation of the Cantabrian and West Asturian-Leonese zones. The latter displays a uniform eastward decrease in metamorphic grade, whereas the Iberian Chains exhibits a heterogeneous distribution of low-grade metamorphic conditions (chlorite zone). The local presence of the biotite isograd is linked to the higher tectonic gradients associated with the Daroca, Jarque and Datos thrusts, quite similar to the metamorphic isogrades recognized both in the northeastern edge of the Demanda Massif and the Novellana-Pola de Allande-Degaña Belt of the West Asturian-Leonese Zone. This distribution allows the identification of a broad NW-SE belt of biotite-in isograd-related synkinematic metamorphism, following the western contact of the Narcea Antiform, the Anguiano Thrust and the southeastern edges of the Daroca, Jarque and Datos Thrusts in the Iberian Chains. Based on Variscan structural style and metamorphic grades, the Datos Thrust links with the contact that separates the Cantabrian and West Asturian-Leonese zones of the Iberian Massif., Financial support was provided by projects CGL2013-46169-C2-1-P and CGL2017-87631-P from Spanish MINECO, the Regional Government of Aragón and the European Regional Development Fund (Grupos Consolidados: Geotransfer and Recursos Minerales).