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Different synthetic routes were applied for preparation of some copper(II) carboxylates with 3-hydroxypyridine (3-pyOH). Monomeric and dimeric complex of copper(II) acetate were isolated, Cu(O2CCH3)2(3-pyOH)2, 1, and Cu2(O2CCH3)4(3-pyOH)2, 2, respectively. A covalently linked 2D CuII compounds of general formula Cu(O2CR)2(3-pyOH)2n, were prepared with benzoate (R=C6H5, 3), hexanoate (R=CH3(CH2)4, 4), and heptanoate (R=CH3(CH2)5,5) ligands. The crystal structures of all five compounds were determined by X-ray structure analysis. The compounds were tested for fungicidal activity against two fungal species Trametes versicolor and Antrodia vaillantii. Complete growth retardation for Antrodia vaillantii was noticed for compounds 3, 4, and 5 at concentrations of 5 10-3 mol L-1, 1 10-3 mol L-1, and 5 10-4 mol L-1, while in the case of Trametes versicolor completegrowth retardation was observed for the same three compounds only at the highest tested concentration. Uporabljene so bile različne sintezne poti za pripravo petih bakrovih(II) karboksilatov z 3-hidroksipiridinom. Sintetizirana sta bila monomerni in dimerni kompleks bakrovega(II) acetata, Cu(O2CCH3)2(3-pyOH)2, 1, in Cu2(O2CCH3)4(3-pyOH)2, 2. Pripravljene so bile tudi spojine CuII z dvodimenzionalnimi kovalentnimi povezavami s splosno formulo Cu(O2CR)2(3-pyOH)2n, in naslednjimi karboksilati: benzoatom (R=C6H5)), 3, heksanoatom (R=CH3(CH2)4), 4 in heptanoatom (R=CH3(CH2)5), 5. Kristalne strukture vseh petih spojin so bile določene z rentgensko strukturno analizo. Spojine so bile testirane za fungicidno aktivnost dveh vrst gliv: Trametes versicolor in Antrodia vaillantii. Spojine 3, 4 in 5 s koncentracijo 5 10-3 mol L-1, 1 10-3 mol L-1 in 5 10-4 mol L-1 so povzroeile popoln zastoj rasti glive Antrodia vaillantii. V primeru glive Trametes versicolor pa je bil opažen za iste tri spojine popoln zastoj rasti samo pri najvišji testirani koncentraciji.

Two monomeric and two dimeric copper(II) benzoate and acetate coordination compounds with 2-aminopyridine were synthesized. The crystal structures of benzoate compounds were determined by X-ray diffraction analyses. The monomeric benzoate form ?$Cu(O_2CC_6H_5)_2(2apy)_2$?(2apy=2-aminopyridine) is composed of trans oriented ligands around central copper(II) atom, where benzoates acts as asymmetrical chelates (Cu-O 1.97 and 2.65 L). On the other hand, dimeric form ?$Cu_2(O_2CC_6H_5)_4(apy)_2$? reveals paddle - wheel type structure where 2-aminopyridine acts as axial ligand via pyridine nitrogen atom. All compounds were characterized by standard physico-chemical methods and tested for their fungal mycelial growth retardation activity for wood fungi Tremetes versicolor and Antrodia vaillantii. Sintetizirani sta bili dve enojedrni in dve koordinacijski spojini bakrovega bnezoata in acetata z 2-aminopiridinom. Z rentgensko difrakcijsko analizo je bila določena kristalna struktura obeh benzoatnih spojin. V enojedrni benzoatni obliki ?$Cu(O_2CC_6H_5)_2(2apy)_2(2apy)=2-aminopiridin$?) so koordinirani ligandi v trans položaju okoli osrednjega bakrovega(II) atoma, kjer so benzoati asimetrični kelati (Cu-O 1.97 in 2.65 L). Po drugi strani dvojedrno obliko ?$Cu_2(O_2CC_6H_5)_4(2apy)_2$? predstavlja strukturni tip mlinskega kolesa z 2-aminopiridinom, ki se veže aksialno preko piridinskega dušikovega atoma. Vse spojine so bile karakterizirane s standardnimi fizikalno-kemijskimi metodami in testirane za njihovo zaviralno aktivnost pri rasti micelija lesnih gliv pisane ploskocevke in bele hišne gobe.