1. Efficient and stable CH3NH3PbI3-sensitized ZnO nanorod array solid-state solar cells.
- Author
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Bi D, Boschloo G, Schwarzmüller S, Yang L, Johansson EM, and Hagfeldt A
- Subjects
- Coloring Agents chemistry, Electron Transport, Light, Iodides chemistry, Lead chemistry, Methylamines chemistry, Nanotubes chemistry, Solar Energy, Zinc Oxide chemistry
- Abstract
We report for the first time the use of a perovskite (CH3NH3PbI3) absorber in combination with ZnO nanorod arrays (NRAs) for solar cell applications. The perovskite material has a higher absorption coefficient than molecular dye sensitizers, gives better solar cell stability, and is therefore more suited as a sensitizer for ZnO NRAs. A solar cell efficiency of 5.0% was achieved under 1000 W m(-2) AM 1.5 G illumination for a solar cell with the structure: ZnO NRA/CH3NH3PbI3/spiro-MeOTAD/Ag. Moreover, the solar cell shows a good long-term stability. Using transient photocurrent and photovoltage measurements it was found that the electron transport time and lifetime vary with the ZnO nanorod length, a trend which is similar to that in dye-sensitized solar cells, DSCs, suggesting a similar charge transfer process in ZnO NRA/CH3NH3PbI3 solar cells as in conventional DSCs. Compared to CH3NH3PbI3/TiO2 solar cells, ZnO shows a lower performance due to more recombination losses.
- Published
- 2013
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