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Start Over Author "Yuya Nitta" Publisher royal society of chemistry (rsc)
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1. Selection of two optional covalent bonds by electric stimuli: dual catalytic switching of redox-active copper

Author

Tsutomu Mizuta, Shoko Kume, Kazuyuki Kubo, Yu Kamamoto, and Yuya Nitta

Subjects
chemistry.chemical_classification, 010405 organic chemistry, Inorganic chemistry, Metals and Alloys, Triazole, Alkyne, chemistry.chemical_element, General Chemistry, 010402 general chemistry, 01 natural sciences, Redox, Combinatorial chemistry, Copper, Catalysis, 0104 chemical sciences, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, chemistry.chemical_compound, chemistry, Covalent bond, Electrode, Materials Chemistry, Ceramics and Composites, Electric potential
Abstract

Two types of redox functionality were selected for covalent immobilization on a carbon electrode, using an electric potential as the sole stimulus. A redox-active copper catalyst transformed a terminal alkyne in two ways with and without an oxidation process, to form a triazole or butadiyne.

Published
2016
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