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A high flow rate, low-pressure microfluidic photocatalytic microreactor was created and demonstrated here.

In an effort to scale-up nanomaterial growth over large surface areas, we aim to effectively study the structural non-homogeneities within the arrays of zinc oxide nanowires (ZnO-NWs). The assessment of the lateral gradient of the nanowires' characteristics is presented including their height and surface density. To this end, spectroscopic ellipsometry and the rather recently reported technique of spectral domain attenuated reflectometry are used as two fast, simple and non-invasive characterization methods with further capabilities of scanning over the sample surface. Simple models are proposed by considering ZnO-NWs as the equivalent of thin stratified layers based on the effective medium approach. The methodology not only reveals the presence of gradients, but also enables quantitative analysis for all the samples grown using the hydrothermal method with different growth times ranging from 0.5 h up to 4 h. The gradients are confirmed using scanning electron microscopy (SEM) observations taken as a reference. The results also suggest that the sample orientation during the growth influences the NW growth besides the other parameters already known to affect the growth mechanisms.

In this paper, for the first time, an on-chip optofluidic imaging system is innovated to measure the biophysical signatures of single waterborne bacteria, including both their refractive indices and morphologies (size and shape), based on immersion refractometry. The key features of the proposed optofluidic imaging platform include (1) multiple sites for single-bacterium trapping, which enable parallel measurements to achieve higher throughput, and (2) a chaotic micromixer, which enables efficient refractive index variation of the surrounding medium. In the experiments, the distinctive refractive index of Echerichia coli, Shigella flexneri and Vibrio cholera are measured with a high precision of 5 × 10(-3) RIU. The developed optofluidic imaging system has high potential not only for building up a database of biophysical signatures of waterborne bacteria, but also for developing single-bacterium detection in treated water that is in real-time, label-free and low cost.

International audience; Solar cells based on one-dimensional nanostructures have recently emerged as one of the most promising candidates to achieve high-efficiency solar energy conversion due to their reduced optical reflection, enhanced light absorption, and enhanced carrier collection. In nature, the rainforest, consisting of several stereo layers of vegetation, is the highest solar-energy-using ecosystem. Herein, we gave an imitation of the rainforest configuration in nanostructure-based solar cell design. Novel multilayer nanorainforest solar cells based on p-Si nanopillar array/n-CdS nanoparticles/n-ZnO nanowire array heterostructures were achieved via a highly accessible, reproducible and controllable fabrication process. By choosing materials with appropriate bandgaps, an efficient light absorption and enhanced light harvesting were achieved due to the wide range of the solar spectrum covered. Si nanopillar arrays were introduced as direct conduction pathways for photon-generated charges' efficient collection and transport. The unique strategy using PMMA as a void-filling material to obtain a continuous, uniform and low resistance front electrode has significantly improved the overall light conversion efficiency by two orders of magnitude. These results demonstrate that nanorainforest solar cells, along with waferscale, low-cost and easily controlled processing, open up substantial opportunities for nanostructure photovoltaic devices.