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The combination of Ni-PMA-H2pdc MOF//activated carbon in a hybrid supercapacitor holds great potential for advancements in energy storage technology.

2D Ag2SO4 nanosheets have been delaminated from bulk Ag2S using a two-step combined exfoliation method. Upon blue light irradiation, the 2D Ag2SO4-based sensor exhibits high-performance responses toward low-concentrated NO2 gas at room temperature.

Two-dimensional heterostructures (2D HSs) have emerged as a new class of materials where dissimilar 2D materials are combined to synergise their advantages and alleviate shortcomings. Such a combination of dissimilar components into 2D HSs offers fascinating properties and intriguing functionalities attributed to the newly formed heterointerface of constituent components. Understanding the nature of the surface and the complex heterointerface of HSs at the atomic level is crucial for realising the desired properties, designing innovative 2D HSs, and ultimately unlocking their full potential for practical applications. Therefore, this review provides the recent progress in the field of 2D HSs with a focus on the discussion of the fundamentals and the chemistry of heterointerfaces based on van der Waals (vdW) and covalent interactions. It also explains the challenges associated with the scalable synthesis and introduces possible methodologies to produce large quantities with good control over the heterointerface. Subsequently, it highlights the specialised characterisation techniques to reveal the heterointerface formation, chemistry and nature. Afterwards, we give an overview of the role of 2D HSs in various emerging applications, particularly in high-power batteries, bifunctional catalysts, electronics, and sensors. In the end, we present conclusions with the possible solutions to the associated challenges with the heterointerfaces and potential opportunities that can be adopted for innovative applications.

On-chip optical switches have emerged as a new class of photonic components for high-performance optical communication networks and on-chip interconnects, in which the all-optical configuration without the incorporation of other control-means is highly desired. While two-dimensional (2D) ultrathin materials demonstrate their great potential in developing ultrafast all-optical switches owing to their unique light–matter interaction, such investigations have so far been limited to the fiber optic platform or free space. Here, we realize an all-optical on-chip switch from a silicon waveguide-based asymmetric Mach–Zehnder interferometer (MZI) structure enabled by 2D ultrathin Ga2S3. Upon the visible light excitation at 532 nm, excessive photocarriers in Ga2S3 cause a change of the refractive index and subsequently a phase variation between MZI arms at the 1550 nm operation wavelength, triggering on the optical switch. On the other hand, the switch is off without the visible light stimulation, as the phase variation is recovered due to the ultrafast photo-exciton relaxation behavior of Ga2S3. The Ga2S3-enabled all-optical switch is driven at an extremely small optical power density of 0.12 W cm−2 and exhibits a response and recovery time of 26.3 and 43.5 μs, respectively, which as a combination is superior to those of fiber optic-based all-optical switches enabled by 2D materials. This work may provide a viable approach to develop on-chip all-optical photonic components for practical integrated photonic chips.

The library of true two-dimensional materials is limited since many transition metal compounds are not stratified and can thus not be easily isolated as nanosheets. Here, micron-sized ultrathin rutile TiO2 nanosheets featuring uniform thickness (2 ± 0.5 nm) with dielectric constant (e⊥ = 24) have been synthesized via a liquid metal synthesis strategy.

Facile and scalable synthesis of two-dimensional (2D) non-layered materials is highly desirable for novel applications. Iron compounds including hematite (α-Fe2O3) and iron phosphide (FeP) are an important group of semiconductors but their 2D ultrathin morphology has been rarely reported. Here, we develop a water dissolvable template-based synthesis route to produce free-standing ultrathin iron compounds. Such a method also enables the tunability of morphology from mesoporous nanosheet to meso-macroporous hierarchical nanonet utilizing the aging process, while its corresponding surface active area is reduced simultaneously. Ultrathin hematite is relatively inert to electrochemical hydrogen evolution reaction (HER). However, FeP exhibits excellent catalytic performances with a relatively low overpotential of 117 mV and a Tafel slope of 56 mV dec−1, which is as a whole improved over those of reported free-standing binary transition-metal phosphide nanostructures. This work extends the possibility to produce high-quality 2D non-layered materials, which are expected to exhibit unique properties compared to their bulk counterparts.