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Violet phosphorus quantum dots have been produced for the first time, which are effective fluorescent probes to selectively detect Cu2+. The morphology, microstructure and fluorescence properties have been tuned using synthesis parameters.

A hetero-phase crystal growth method was proposed by introducing a heteroelement to yield large antimony single crystals with high quality.

Violet phosphorene, a recently produced elemental 2D material, is a promising electronic and optoelectronic structure. The work function and band alignment of phosphorene nanoflakes are essential for their heterojunction structure design. The work function of violet phosphorene nanoflakes has been shown to decrease with the increase in layers from 5.16 eV to 4.79 eV and tends to be stable on a gold substrate, which has been confirmed via Kelvin probe force microscopy. The work functions measured on a silicon oxide substrate are much higher due to charge accumulation. The experimental work function of few-layer violet phosphorene is different from the intrinsic work function due to substrate doping, while that of thick violet phosphorene nanoflakes approaches the intrinsic work function value. Various functionals have been adopted for the work function calculation of few-layer violet phosphorene and the values obtained have been compared to the experimental results. The band alignments of different layered violet phosphorene materials calculated using the most accurate functional are demonstrated and compared to those of well-known materials to give a practical route for future applications. The work functions of the violet phosphorene nanoflakes have been shown to decrease due to oxidation, but they significantly improve after annealing in an argon atmosphere.