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The present study reports the performance of a novel PVDF–Cloisite 15A hollow fiber composite membrane for the treatment of effluents containing dyes and salts through a direct contact membrane distillation (DCMD) process. The performance of the membrane was evaluated by varying several important parameters during the DCMD process which included feed properties (type of dyes, dye and salt concentration) and process conditions (feed temperature and flow rate). The experimental results showed that the in-house made membrane was able to achieve stable fluxes and excellent dye rejections (>97%) when tested with feed solutions containing dyes of different classes and molecular weights (MW), except crystal violet (CV) dye. The lower rejection resulting from a CV-containing feed is likely due to its small MW coupled with its high diffusion rate in aqueous solution. With respect to feed concentration, it is found that an increase in salt concentration in the feed solution had a negligible effect on the membrane separation performance. Increasing the dye concentration in the feed however led to lower membrane water flux owing to the deposition of dye particles on the membrane surface which resulted in severe fouling. Meanwhile, increasing the feed temperature and its flow rate could improve the membrane flux without affecting the permeate quality. When tested using a dyeing solution containing 50 ppm acid red and 1.0 M NaCl, the membrane flux was reported to enhance by 200% and 25% on increasing the feed temperature from 50 to 90 °C and the flow rate from 0.010 to 0.023 m s−1, respectively.