Search

Your search keyword '"Jason Tao"' showing total 1 results
Start Over Author "Jason Tao" Publisher royal society of chemistry (rsc)
1 results on '"Jason Tao"'

1. Metal-free intermolecular cyclopropanation between alkenes and iodonium ylides mediated by PhI(OAc)2·Bu4NI

Author

Jason Tao, Carl D. Estrada, and Graham K. Murphy

Subjects
010405 organic chemistry, Cyclopropanation, Stereochemistry, Chemistry, Intermolecular force, Metals and Alloys, General Chemistry, 010402 general chemistry, 01 natural sciences, Medicinal chemistry, Catalysis, 0104 chemical sciences, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, Metal free, Yield (chemistry), Materials Chemistry, Ceramics and Composites
Abstract

A rapid, mild and metal-free intermolecular cyclopropanation between iodonium ylides and alkene-containing substrates mediated by PhI(OAc)2·Bu4NI is reported. Iodonium ylides of cyclic and acyclic 1,3-dicarbonyls were reacted with a variety of mono-, di-, tri- and tetra-substituted alkenes of various structural types to give 29 cyclopropanes in up to 97% yield.

Published
2017
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results